CAS: 84-11-7; Phenanthrene-9,10-Dione

• 英文名称Phenanthrene-9,10-Dione
• 中文名称菲醌
• IUPAC名称phenanthrene-9,10-dione
• 其它别名菲-9,10-二酮
• CAS编号84-11-7
• MFCD编号:MFCD00001163
• EINECS号:201-515-5
• FDA UNII编号:42L7BZ8H74
• 分子式:C14H8O2
• 分子量:208.22
• 产品CID: 2369392
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• InChIKey: YYVYAPXYZVYDHN-UHFFFAOYSA-N
• InChI=1S/C14H8O2/c15-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14(13)16/h1-8H…
• 计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数0.0

物理性质

• 熔点209-212°C
• 沸点360°C at 760 mmHg
• 闪点241°C
• 密度350kg/m3
• PSA:34.14
• LogP:2.7326
• 折射率1.5681 (估算)
• 蒸汽压8.5X10-7 mm Hg at 25 °C (est)
• 溶解性7.5Mg/l
• 外观形态橙棕色粉末
• 储存条件存储低于 +30°C.
• 产品应用菲醌用于有机合成,可用来生产苯绕蒽酮.菲醌具有抑菌能力,用于拌种可防止谷物黑穗病,棉花苗期病,还可作为纸浆防腐剂.经氢氧化钠处理后可制得多效能的植物生长调节剂整形素.
• 性质描述橙黄色针状结晶.熔点208.5-210°C,沸点360°C以上.升华.相对密度1.405.不溶于水,微溶于乙醇,苯,醋酸乙酯,溶于乙醚和热醋酸,在浓硫酸中溶解并呈现暗绿色.升华得橙红色片状体.与亚硫酸钠作用生成不稳定的亚硫酸氢盐.经进一步氧化,可得联苯二甲酸.还原成菲氢醌.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  水生急性毒性 类别1
  严重眼刺激 类别2A
• 警示词Warning(警告)
• 危险描述H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H400 |对水生生物毒性极大.
• 防范说明P264-P273-P280-P391-P501
• 危险等级9
• UN编号3077.0
• 危险品标志Xi
• 包装等级Ⅲ
• 安全声明26-36-24/25-22
• 危险类别码36/37/38
• WGK Germany3.0

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 Phenanthrenequinone 主要起始原料 Phenanthrene
• 1210-05-5 = 84-11-7
  反应条件:1.1 Reagents: 1,8-Diazabicyclo[5.4.0]Undec-7-Ene Solvents: Tert-Butanol; 24 H,60 °C1.2 Reagents: Oxygen
  标题:Thiazol-2-Ylidene Catalysis In Intramolecular Crossed Aldehyde-Ketone Benzoin Reactions
  作者:Enders,Dieter; Niemeier,Oliver
  参考文献:Synlett 日期:2004 卷标:(12) 页码:2111-2114]
  
  604-84-2 = 84-11-7
  反应条件:1.1 Reagents: Sodium Periodate Solvents: Dichloromethane,Water; 10 Min,Rt
  标题:1-Methyl-1,4-Cyclohexadiene As A Traceless Reducing Agent For The Synthesis Of Catechols And Hydroquinones
  作者:Baschieri,Andrea; Amorati,Riccardo; Valgimigli,Luca; Sambri,Letizia
  参考文献:Journal Of Organic Chemistry 日期:2019 卷标:84(21) 页码:13655-13664]
  
  484-17-3 = 84-11-7
  反应条件:1.1 Reagents: Sodium Bicarbonate,Potassium Peroxymonosulfate Sulfate (2Khso5.Khso4.K2So4) Solvents: Acetone,Dichloromethane,Water
  标题:The Formation Of Orthoquinones In The Dimethyldioxirane Oxidation Of Phenols
  作者:Crandall,Jack K.; Zucco,Martine; Kirsch,R. Scott; Coppert,David M.
  参考文献:Tetrahedron Letters 日期:1991 卷标:32(40) 页码:5441-4]
  
  85-01-8 = 84-11-7
  反应条件:1.1 Reagents: Pyridine,2,6-Dichloro-,1-Oxide Catalysts: (Oc-6-12)-Dichloro[5,10,15,20-Tetrakis(2,6-Dichlorophenyl)-21H,23H-Porphinato(2-... Solvents: Dichloromethane; 12 H,40 °C
  标题:Dichlororuthenium(Iv) Complex Of Meso-Tetrakis(2,6-Dichlorophenyl)Porphyrin: Active And Robust Catalyst For Highly Selective Oxidation Of Arenes,Unsaturated Steroids,And Electron-Deficient Alkenes By Using 2,6-Dichloropyridine N-Oxide
  作者:Zhang,Jun-Long; Che,Chi-Ming
  参考文献:Chemistry - A European Journal 日期:2005 卷标:11(13) 页码:3899-3914]
  
  5807-64-7 = 84-11-7
  反应条件:1.1 Reagents: Butyllithium,Hexamethylditin Solvents: Tetrahydrofuran; 15 Min,0 °C1.2 Solvents: Tetrahydrofuran; 5 H,-78 °C1.3 Reagents: Water; Ph 7.0
  标题:Stanna-Brook Rearrangement Of Carboxylic Acid Derivatives. Synthetic Utility And Mechanistic Studies
  作者:Paleo,M. Rita; Calaza,M. Isabel; Grana,Paula; Sardina,F. Javier
  参考文献:Organic Letters 日期:2004 卷标:6(6) 页码:1061-1063]
  
  85-01-8 = 84-11-7
  反应条件:1.1 Reagents: 1-Hexadecanaminium,N,N,N-Trimethyl-,(T-4)-Bromotrioxochromate(1-) (1:1) Solvents: Dichloromethane; 72 Min,Reflux
  标题:Cetyltrimethylammonium Bromochromate. A New And Efficient Oxidant For Organic Substrates
  作者:Ghammamy,Shahriar; Eimanieh,Hossein; Mohammady,Mohammad Kazem
  参考文献:Synthetic Communications 日期:2007 卷标:37(4) 页码:599-605]
  
  85-01-8 = 84-11-7
  反应条件:1.1 Reagents: 1-Butanaminium,N,N,N-Tributyl-,(T-4)-Fluorotrioxochromate(1-) Solvents: Dichloromethane; 45 Min,Rt
  标题:Tetrabutylammonium Fluorochromate(Vi) (Tbafc). A Mild And Efficient Reagent For Oxidation Of Organic Substrates
  作者:Ghammami,Shahriare; Sajadi,Seyed Abolfazl Seyed
  参考文献:Journal Of The Serbian Chemical Society 日期:2005 卷标:70(11) 页码:1243-1248]
  
  85-01-8 = 84-11-7
  反应条件:1.1 Reagents: Methanaminium,N,N,N-Trimethyl-,(T-4)-Fluorotrioxochromate(1-) (1:1) Solvents: Dichloromethane; 45 Min,Rt
  标题:Tetramethylammonium Fluorochromate(Vi): A New And Efficient Oxidant For Organic Substrates
  作者:Mahjoub,Ali Reza; Ghammami,Shahriare; Kassaee,Mohammad Zaman
  参考文献:Tetrahedron Letters 日期:2003 卷标:44(24) 页码:4555-4557]
  
  484-17-3 = 84-11-7
  反应条件:1.1 Reagents: Potassium Carbonate,Sodium Sulfate,Potassium Peroxymonosulfate Sulfate (2Khso5.Khso4.K2So4) Solvents: Ethyl Acetate; 24 H,Rt1.2 Catalysts: Tetrabutylammonium Hydrogen Sulfate,Benzenesulfonic Acid,2-Iodo-5-Methyl-,Sodium Salt (1:1) Solvents: Ethyl Acetate; 3 H,40 °C
  标题:Ibs-Catalyzed Regioselective Oxidation Of Phenols To 1,2-Quinones With Oxone
  作者:Uyanik,Muhammet; Mutsuga,Tatsuya; Ishihara,Kazuaki
  参考文献:Molecules 日期:2012 卷标:17 页码:8604-8616]
  
  85-01-8 = 84-11-7
  反应条件:1.1 Reagents: Chromate(1-),Chlorotrioxo-,(T-4)-,Hydrogen,Compd. With N,N-Dipropyl-1-Propan... Solvents: Dichloromethane; Rt; 350 Min,Rt
  标题:The Two New Tripropylammonium Halochromates,(C3H7)3Nh[cro3X],(X = F,Cl),Reagents For Oxidation Of Alcohols On Alumina
  作者:Ghammamy,Shahriar; Sharifnezhad,Zahra; Aghbolagh,Zahra Shokri; Sahebalzamani,Hajar
  参考文献:Advances In Applied Science Research 日期:2010 卷标:1(2) 页码:119-123]
  
  85-01-8 = 84-11-7
  反应条件:1.1 Reagents: Chromate(1-),Chlorotrioxo-,(T-4)-,Hydrogen,Compd. With N,N-Dimethylmethanami... Solvents: Dichloromethane; Rt; 8 H,Rt
  标题:Heterogeneous Oxidation Of Organic Substrates By Using Two Trimethylammonium Halochromates On Alumina,(Ch3)3Nh[cro3X],(X=f,Cl)
  作者:Ghammamy,Shahriare; Moghimi,Ali; Nezhad,Zahra Sharif; Aghbolagh,Zahra Shokri; Behbahani,Golam Rezaei
  参考文献:Chemica Sinica 日期:2010 卷标:1(1) 页码:106-110]
  
  85-01-8 = 84-11-7
  反应条件:1.1 Reagents: Acetic Acid,Ceric Sulfate Catalysts: Iridium Trichloride; 3 H,100 °C
  标题:Liquid-Phase And Solventless Oxidation Of Cyclohexane,Benzene,And Other Hydrocarbons By Cerium(Iv) Catalyzed By Iridium(Iii) In Acidic Medium
  作者:Tandon,Praveen K.; Srivastava,Manish; Singh,Santosh B.; Srivastava,Nidhi
  参考文献:Synthetic Communications 日期:2008 卷标:38(18) 页码:3183-3192

海关参考信息

• 2902600000-乙苯
  2912110000-甲醛
  2912120000-乙醛
  2912210000-苯甲醛
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

专利信息

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• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管