CAS: 6476-36-4; Triisopropylphosphine

上下游产品

2-iodo-propane di-isopropylphosphine isopropylmagnesium bromide dithi°Carboxy-triisopropyl-phosphonium betaine5-phosphanylidene)-eth-(E)-ylidene]-(2,2,2-trifluoro-1-trifluoromethyl-ethyl)-amine[2-Phenyl-2-(triisopropyl-λ5-phosphanylidene)-eth-(E)-ylidene]-(2,2,2-trifluoro-1-trifluoromethyl-ethyl)-amine phosphoniumbromidTriisopropyl(pentafluorphenyl)methylphosphoniumbromid trimethylphosphane diisopropylmethylphosphine

📜异丙基溴化镁置于三氯化磷体系中,化学反应生成 三异丙基膦
参考文献:苯硫酸铜锌和第一种硒酸铜锌和碲酸铜配合物的合成及晶体结构
标题:苯硫酸铜锌和第一种硒酸铜锌和碲酸铜配合物的合成及晶体结构
摘要:五铜锌苯基硫属元素络合物 [(Ipr3Pcu)3(Znme2)2(Sph)3] (1),[(Ipr3Pcu)2(Znph)4(Sph)6] (2),[(Ipr3Pcu)2(Znet)4 (Sph)6] (3),[(Ipr3Pcu)3(Znet)(Seph)4] (4) 和 [(Ipr3Pcu)3Cu(Ipr3Pzn)(Teph)6] (5) 是由膦反应合成的稳定的苯基硫属元素铜配合物与 Znr2 (R = Me,Et,Ph) 有和没有额外的硫属元素醇.通过单晶x射线结构分析和核磁共振光谱对新型混合金属化合物进行了表征.图 4 和图 5 分别是具有 Zn-Se-Cu 或 Zn-Te-Cu 键的化合物的第一个例子.
DOI:10.1002/zaac.201600426

专利信息

专利号:US-6504041-B2
优先权日:1996-11-15
标题 :Synthesis of ruthenium or osmium metathesis catalysts
发明人：GRUBBS ROBERT H; BELDERRAIN TOMAS R; BROWN SETH N; WILHELM THOMAS E
权利人:CALIFORNIA INST OF TECHN
摘要:The present invention relates to the synthesis of highly active ruthenium and osmium carbene metathesis catalyst in good yield from readily available starting materials. The catalysts that may be synthesized are of the general formula n wherein: n M is ruthenium or osmium; n X and X 1 are independently any anionic ligand; n L and L 1 are any neutral electron donor ligand; and, n R and R 1 are each hydrogen or one of the following substituent groups: C 2 -C 20 alkenyl, C 2 -C 20 alkynyl, C 1 -C 20 alkyl, aryl, C 1 -C 20 carboxylate, C 1 -C 20 alkoxy, C 2 -C 20 alkenyloxy, C 2 -C 20 alkynyloxy, aryloxy, C 2 -C 20 alkoxycarbonyl, C 1 -C 20 alkylthio, C 1 -C 20 alkylsulfonyl and C 1 -C 20 alkylsulfinyl. Optionally, the substituent group may be substituted with one or more groups selected from C 1 -C 5 alkyl, halogen, C 1 -C 5 alkoxy, and aryl. When the substitute aryl group is phenyl, it may be further substituted with one or more groups selected from a halogen, a C 1 -C 5 alkyl, or a C 1 -C 5 alkoxy. Specific synthetic protocols for vinyl alkylidene catalysts wherein R is hydrogen and R 1 is —CHCR 12 R 13 and non-vinyl alkylidene catalysts are also disclosed. In addition to the ease of synthesis (typically a one-step synthesis), the reactions generally may be run at or above room temperature and the resulting products usually may be used without extensive post synthesis purification.

专利号:US-7102023-B2
优先权日:1999-11-24
标 题:Protecting groups useful in the synthesis of polysaccharides, natural products, and combinatorial libraries
发明人：BUCHWALD STEPHEN L; PLANTE OBADIAH J; SEEBERGER PETER H
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:One aspect of the present invention relates to optionally substituted halogenated benzyl halides and the like. These compounds are useful as halogenated benzyl ether-based protecting groups for a variety of functional groups. Another aspect of the present invention relates to use of said protecting groups in an orthogonal protecting group strategy for the synthesis of complex molecules that comprise a number of suitable functional groups. Another aspect of the present invention relates to saccharides bearing various arrays of protecting groups of the present invention. Another aspect of the present invention relates to a method of synthesizing an oligosaccharide or glycoconjugate, comprising the steps of: using a saccharide bearing at least one protecting group of the present invention to glycosylate a second molecule to give a product comprising said saccharide; and removing a protecting group of the present invention from said product.

专利号:US-6613910-B2
优先权日:2001-04-02
标题 :One-pot synthesis of group 8 transition metal carbene complexes useful as olefin metathesis catalysts
发明人：GRUBBS ROBERT H; MORGAN JOHN P; BENITEZ DIEGO; LOUIE JANIS
权利人:CALIFORNIA INST OF TECHN
摘要:The invention provides a novel method for synthesizing transition metal carbene complexes useful as olefin metathesis catalysts. The method is a convenient one-pot synthesis in which transition metal carbenes are prepared in high yield from readily available starting materials via a dihydrogen complex containing two different anionic ligands, preferably a phosphine and a heteroatom-stabilized carbene. The invention additionally provides a method for synthesizing precursors to carbene ligands useful, inter alia, in the aforementioned one-pot synthesis. The precursors are in the form of trichloromethyl adducts of the formula L 1 -CCl 3 , where L 1 is a heteroatom-stabilized carbene ligand, and are prepared by contacting an unsaturated, ionized analog of L-CCl 3 with a non-nucleophilic base in the presence of chloroform.

专利号:US-10173993-B2
优先权日:2015-12-09
标题 :Process for the synthesis of sulfones and sulfonamides
发明人：VON WOLFF NIKLAS; CHAR JOËLLE; CANTAT THIBAULT
权利人:COMMISSARIAT ENERGIE ATOMIQUE
摘要:A one pot single step process is described for the synthesis of a compound, including a labeled compound, containing a sulfonyl functional group comprising the step of mixing together a silane, an SO 2 source, an electrophilic compound, an activating compound and optionally a metal catalyst. A process for producing tracers from a labeled sulfonyl containing compound prepared by the described process is also included.

专利号:US-5789530-A
优先权日:1996-12-20
标 题:Catalyzed synthesis of aramid from carbon monoxide, aromatic dichlorides, and diamines
发明人：SEN AYUSMAN; KIM JANG SUB
权利人:PENN STATE RES FOUND
摘要:The synthesis of an aramid by the catalyzed reaction of carbon monoxide, an aromatic dichloride, such as 1,4-dichlorobenzene, and a diamine, such as 1,4-diaminobenzene, is disclosed. The reaction may be catalyzed by palladium (II) and palladium (0)-containing catalysts with chelating trialkyl phosphines, such as bis(diisopropylphosphino)-propane.

专利号:US-7034096-B2
优先权日:2002-02-19
标题:Ring-expansion of cyclic olefins metathesis reactions with an acyclic diene
发明人：CHOI TAE-LIM; LEE CHOON WOO; KIM HYUNJIN M; GRUBBS ROBERT H
权利人:CALIFORNIA INST OF TECHN
摘要:This invention relates generally to synthetic procedures that include the step of ring-opening metathesis of cyclic olefins and reaction with an acyclic diene co-reactant to produce olefin macrocycles by ring expansion, or alternatively. The ring expansion of the cyclic olefin is provided by three types of sequential olefin metathesis (ring-opening, cross, and ring-closing olefin metathesis). More particularly, the invention pertains to synthesis of olefin macrocycles via olefin metathesis reactions using a Group 8 transition metal complex as the metathesis catalyst. Macrocycles provided herein have a variety of uses in the pharmaceutical, biomedical, organic synthesis and chemical industries, such as the production of crown ethers that are useful as metal complexing species.