CAS: 492-21-7; 9H-Xanthene-9-Thione

该化合物是一个含硫的环环环化合物,其特点是其氧气骨干,在中9位置有一个硫碳基功能组,这种结构具有独特的光物理和电子特性,在有机合成和材料科学中具有宝贵价值;该化合物具有很强的吸收和排放特性,适合于在荧光染料,传感器和光电子材料中应用;其二氯酮混合物还能够增强循环和聚合反应的再活动性;具有高热稳定性和金枪鱼可溶性,9H-Xanthene-9-thione作为设计高级功能材料的多用途中间体.建议谨慎处理,因为有可能对光和空气敏感.

结构式图片

MSDS等安全信息

    合成工艺路线路线简述

      📜Alkaline Earth Salt Of/the/ Methylsulfuric Acid 反应生成 9-噻吨酮
      参考文献:Schoenberg Et Al.,Chemische Berichte,1929,Vol. 62,P. 2561
      标题:Schoenberg Et Al.,Chemische Berichte,1929,Vol. 62,P. 2561

      海关参考信息

      专利信息


      专利号:US-4443310-A
      优先权日:1981-03-12
      标题:Photoinitiated synthesis of mercaptans
      发明人:ARRETZ EMMANUEL; LANDOUSSY CLAUDE; MIRASSOU ALFRED; OLLIVIER JEAN
      权利人:ELF AQUITAINE
      摘要:Improvement in the photoinitiated synthesis of mercaptans, in which an ethylenic compound is treated with hydrogen sulphide, preferably under pressure, in the presence of ultraviolet radiation and a photoinitiator involves the use of a xanthenic compound, possibly substituted, as the initiator. Preferably, the xanthenic compounds is employed in conjunction with an organic compound of an element of Group V A of the Periodic Classification of the Elements.

      专利号:US-4267344-A
      优先权日:1972-09-22
      标 题:N-Substituted N-carboxyanhydrides of α-amino acids and their application in the preparation of peptides
      发明人:HALSTROM JOHN B; KOVACS KAROLY G
      权利人:PROTEINKEMISK INST TILKNYTTET
      摘要:N-Substituted N-carboxyanhydrides of α-amino acids, useful in peptide syntheses, and peptide synthesis process using such compounds, are disclosed. The N-substituent is penta(lower alkoxy)benzyl, or optionally substituted 9-xanthyl, 9-thioxanthyl or 9-selenoxanthyl.

      专利号:CN-114957037-A
      优先权日:2022-06-09
      标题 :A method for the synthesis of β-aminocarbonyl compounds by light-induced homolytic decarboxylation of oxalyl oxime esters and addition of activated alkenes

      专利号:CA-1162510-A
      优先权日:1981-03-12
      标题:Photoinitiated synthesis of mercaptans

      专利号:DE-60754-T1
      优先权日:1981-03-12
      标 题 :PHOTO-INDUCED SYNTHESIS OF THE MERCAPTANE.

      专利号:FR-2521990-A2
      优先权日:1982-02-22
      标 题 :IMPROVEMENT TO THE PHOTOINITIATED SYNTHESIS OF MERCAPTANS

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      品牌试剂参考报价(招募中)

      📌 第三方产品分析报告

      ✅ COA系统入驻 | 共享模式

      合成参考文献


      摘要:Gao, W.-C.; Tian, J., Science of Synthesis Knowledge Updates, (2020) 3, 324.
      摘要:Mlostoń, G.; Heimgartner, H., Science of Synthesis Knowledge Updates, (2014) 2, 381.
      摘要:Mlostoń, G.; Heimgartner, H., Science of Synthesis Knowledge Updates, (2014) 2, 397.
      参考文献:10.1007/bf00195443
      摘要:Vermeir M, Boens N. Determination of the partition of the tetramisole derivative (±)-5,6-dihydro-6-phenyl-2-n-propyl-imidazo[2,1-b]thiazole into liposomal membranes by fluorescence quenching of the membrane probe 8-(2-anthryl)-octanoic acid. European Biophysics Journal. 1992 Mar;21(1):47–56. doi: 10.1007/bf00195443.
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