CAS: 1515-80-6; Methyl Sorbate

相似化合物

110-44-1 17102-64-6 689-89-4

上下游产品

methanol hexa-2,4-dienoyl chloride diethyl ether sodium methylate3-methylheptanedioic acid 3-propylpentanedioic acid methyl (2E,4E)-6-bromo-2,4-hexadienoate methyl (E)-4-oxo-2-butenoate

📜山梨酸置于氯化亚砜体系中,用 甲醇 用作溶剂,化学反应 3.0H,以95%的收率获得山梨酸甲酯
参考文献:Hemicalide的c1-c28区域具有合成功能的相对立体化学分配†
标题:Hemicalide的c1-c28区域具有合成功能的相对立体化学分配†
摘要:通过合成有效的细胞毒性海洋聚酮化合物hemicalide的模型c1-C28片段的两个候选非对映异构体,可以实现c1-C15和c16-C26之间的相对构型分配.通过与天然产物的详细NMR比较,这两个1,6相关立体簇之间的相对立体化学被阐明为13,18-Syn,而不是先前提出的13,18-反式.概述了使用高级c1-C28酮片段22的灵活和模块化策略,以阐明其余的立体化学特征并实现总合成.
Doi:10.1039/c8Cc00933C

专利信息

专利号:US-6258323-B1
优先权日:1998-11-16
标题:Apparatus and method used in multiple, simultaneous synthesis of general compounds
发明人：HORMANN ROBERT EUGENE; GILBERT DARYL EUGENE; SIOMA EDWARD MICHAEL
权利人:ROHM & HAAS
摘要:The apparatus and method of the present invention provides for conducting simultaneous multiple synthesis of general compounds, which often takes place under varied uneven conditions requiring heating, cooling, agitation, reagent/solvent additions to the reactor contents at each reaction vessel location, supply and maintenance of inert atmosphere and means to facilitate the reflux of the reactor contents. Thus, it becomes necessary to monitor and control the reaction conditions during the simultaneous multiple synthesis of general compounds. The apparatus allows the user to connect various independently controlling and conveying means to each reaction vessel through multiple ports provided on a stopper mounted on each reaction vessel. The apparatus of the present invention permits user to readily access the reaction vessels without interrupting the reactions occurring in the adjacent reaction vessels. The unique geometry and shape of the stopper allows positioning of multiple ports, while still providing the stopper with a compact size. As a result, a large array of reaction vessels can be accommodated in the device of the present invention without significantly increasing the overall size of the apparatus. Some of the general compounds that can be readily synthesized by the apparatus and the method of the present invention include inorganic compounds as well as organic compounds, such as oligomers, polymers, agricultural chemicals, drugs, peptides and oligonucleotides.

专利号:US-9573116-B2
优先权日:2013-12-30
标题 :Synthesis of ZSM-58 crystals with improved diffusivity for use in gas separations
发明人：JOHNSON IVY D; BEUTEL TILMAN W; RAVIKOVITCH PETER I; DECKMAN HARRY W; JOHNSON JACK W; BEECKMAN JEAN W; FASSBENDER NATALIE A; HRYCENKO NADYA A; SMILEY RANDOLPH J
权利人:JOHNSON IVY D; BEUTEL TILMAN W; RAVIKOVITCH PETER I; DECKMAN HARRY W; JOHNSON JACK W; BEECKMAN JEAN W; FASSBENDER NATALIE A; HRYCENKO NADYA A; SMILEY RANDOLPH J; EXXONMOBIL RES & ENG CO
摘要:Methods are provided for synthesizing ZSM-58 crystals with an improved morphology and/or an improved size distribution. By controlling the conditions during synthesis of the ZSM-58 crystals, crystals of a useful size with a narrow size distribution can be generated. Steaming the H-form DDR framework type crystals at a temperature from 426±° C. to 1100±° C. for a time period from about 30 minutes to about 48 hours can attain one or more of the following properties: a CH4 diffusivity of no more than 95% of the CH4 diffusivity of the unsteamed H-form DDR framework type crystals; an N2 BET surface area from 85% to 110% of the surface area of unsteamed H-form DDR framework type crystals; and an equilibrium CO2 sorption capacity from 80% to 105% of the equilibrium CO2 sorption capacity of unsteamed H-form DDR framework type crystals.

专利号:US-2025223247-A1
优先权日:2022-05-03
标 题:Process for the hydrogenation of unsaturated esters
发明人：GRAINGER DAMIAN; VAJARIA KRISHA
权利人:JOHNSON MATTHEY PLC
摘要:Some embodiments relate to a process for the hydrogenation of ester-containing substrates. More specifically, the embodiments relate to a process for the reduction of α,β-γ,δunsaturated containing esters and β,γ unsaturated containing esters of Formula (I) to produce an alcohol of Formula (II). The process of the embodiments uses a base, the conjugate acid of the base has a pKa of from 4 to 15. The process of the embodiments finds use in the synthesis of organic molecules.

专利号:US-9108940-B2
优先权日:2010-08-19
标题:Conversion of 5-(chloromethyl)-2-furaldehyde into 5-methyl-2-furoic acid and derivatives thereof
发明人：MIKOCHIK PETER; CAHANA AVIAD
权利人:MIKOCHIK PETER; CAHANA AVIAD; XF TECHNOLOGIES INC
摘要:The present invention concerns the synthesis of 5-methyl-2-furoic acid, including ester, amide, and thioester derivatives of such from 5-(chloromethyl)-2-furaldehyde (CMF). The molecules so prepared are useful as intermediates for pharmaceutical, food, and fragrance molecules; as well as fuel or fuel additives.

专利号:EP-3089941-A1
优先权日:2013-12-30
标题 :Synthesis of zsm-58 crystals with improved diffusivity for use in gas separations

专利号:US-2015182947-A1
优先权日:2013-12-30
标题:Synthesis of zsm-58 crystals with improved diffusivity for use in gas separations