CAS: 128055-74-3; 2,2',7,7'-Tetrabromo-9,9'-Spirobifluorene

相似化合物

171408-76-7 171408-84-7 67665-47-8

上下游产品

CAS号159-66-0 9,9'-螺二芴 | CAS号171408-84-7 2,7-二溴-9,9-螺二芴 | CAS号67665-44-5 9-(2-phenylphen... | CAS号2113-51-1 2-碘联苯 | CAS号90-41-5 2-氨基联苯 | CAS号486-25-9 9-芴酮 | CAS号2052-07-5 邻溴联苯 | CAS号622011-44-3 9,9'-spirobi[fl...

2-碘联苯置于盐酸,Iron(III) Chloride,溴,Magnesium,溶剂黄146体系中,用 乙醚,水 用作溶剂,化学反应 37.5H,反应生成2,2',7,7'-四溴-9,9'-螺二芴
参考文献:容易合成具有硅芴核的空穴传输材料,用于高效介观的ch 3 Nh 3 Pbi 3钙钛矿太阳能电池†
标题:容易合成具有硅芴核的空穴传输材料,用于高效介观的ch 3 Nh 3 Pbi 3钙钛矿太阳能电池†
摘要:一种新型的富电子小分子4,4'-(5,5-二己基-5 H-二苯并[ B,D ]甲硅油-3,7-二基)双(n,N-双(4-甲氧基苯基)苯硅烷基苯胺(s101)含有硅芴作为具有芳基胺侧基的核,已通过一条短而有效的途径合成.当将s101作为空穴传输材料(htm)结合到ch 3 Nh 3 Pbi 3钙钛矿太阳能电池中时,短路光电流密度(j Sc)为18.9 Ma Cm-2,开路电压(v oc))为0.92 V,填充系数(ff)为0.65,有助于使总功率转换效率(pce)达到约11%,这与使用最新技术的htm 2,2'获得的pce相当获得了7,7'-四(n,N'-二-对甲氧基苯胺)-9,9'-螺二芴(spiro-Ometad)(η= 12.3%).因此,S101是一种很有前途的htm,由于其可比的性能以及更简单,更便宜的合成路线,它有可能取代昂贵的spiro-Ometad.
Doi:10.1039/c6Ta01776B

专利信息

专利号:US-5026894-A
优先权日:1990-03-12
标题 :Compound for use in the synthesis of semiconducting polymers with perpendicularly arranged cores and method of synthesizing said compound
发明人：TOUR JAMES M; WU RUILIAN; SCHUMM JEFFRY S
权利人:UNIV SOUTH CAROLINA
摘要:The stereochemical structure necessary for preparation of perpendicularly arranged cores is provided by a compound of the formula ##STR1## This compound can be synthesized by the reaction of ##STR2## with bromine in the presence of FeCl 3 .

专利号:CN-114539240-B
优先权日:2022-01-05
标 题:Synthesis of 3D non-fullerene receptor small molecule and application of 3D non-fullerene receptor small molecule in ternary organic solar cell

专利号:CN-114539240-A
优先权日:2022-01-05
标 题:Synthesis of a 3D non-fullerene acceptor small molecule and its application in ternary organic solar cells

专利号:US-8410185-B2
优先权日:2007-06-28
标题:Porous polymeric materials for hydrogen storage
发明人：YU LUPING; LIU DI-JIA; YUAN SHENGWEN; YANG JUNBING
权利人:YU LUPING; LIU DI-JIA; YUAN SHENGWEN; YANG JUNBING; UCHICAGO ARGONNE LLC
摘要:A porous polymer, poly-9,9′-spirobifluorene and its derivatives for storage of H 2 are prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO 2 /steam oxidation and supercritical water treatment.

专利号:US-12252584-B2
优先权日:2021-03-02
标题:Poly(aryl ether) based polymers and associated methods
发明人：SWAGER TIMOTHY MANNING; LIU RICHARD; GUO SHENG
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:Compositions and methods related to the synthesis and application of poly(aryl ether)s are generally described.

专利号:US-11891481-B2
优先权日:2021-03-02
标 题:Poly(aryl ether) based polymers and associated gas separation membranes
发明人：SWAGER TIMOTHY MANNING; SMITH ZACHARY; BENEDETTI FRANCESCO MARIA; GUO SHENG
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:Compositions and methods related to the synthesis and application of poly(aryl ether)s are generally described.