CAS: 79769-48-5; 11-Bromoundecyltrichlorosilane

该化合物是一种硅化合物,其特点是存在一个长的碳氢化合物链,具体地说是一个不二极类的化合物,在第11个碳位置上被溴原子所取代.该化合物还有一个三氯硅功能组,表明三个氯原子被捆绑在硅原子上.这些功能组的存在表明,该化合物可能具有独特的特性,如由于长的烷基链链而具有疏水性,而三氯硅酸可以促进与各种子元素的反应,使其在地表改造和粘合应用中有用.此外,溴原子也可以作为反应场所,用于进一步的化学转化.

英文名称11-Bromoundecyltrichlorosilane
中文名称11-溴十-基三氯硅烷
IUPAC名称11-bromoundecyl(trichloro)silane
其它别名(11-Bromoundecyl)trichlorosilane; 1-Bromo-11-(trichlorosilyl)undecane; 1-Bromo-11-undecyl trichlorosilane
CAS编号79769-48-5
MFCD编号:MFCD00270977
EINECS号:842-231-7
分子式:C11H22BrCl3Si
分子量:368.64
产品CID: 1791604
产品分类化学试剂 → 硅烷试剂

相似结构搜索
InChIKey: LLNQRNOPJAFMFQ-UHFFFAOYSA-N
InChI=1S/C11H22BrCl3Si/c12-10-8-6-4-2-1-3-5-7-9-11-16(13,14)15/h1-11H2…
计算化学: 氢键受体数0.0氢键供体数0.0可旋转键数10.0

MSDS等安全信息

GHS象形图
GHS符号GHS05;
注释: Corrosion
危险类别金属腐蚀物类别1
皮肤腐蚀类别1B
严重眼损伤类别1
警示词Danger(危险)
危险描述H290 |可能对金属造成腐蚀.
H314 |造成严重皮肤灼伤和眼损伤.
H318 |造成严重眼损伤.
防范说明P280-P305+P351+P338-P310-P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501-P234-P390-P404
UN编号2987
危险品标志C
安全声明26-36/37/39-45
危险类别码34-36/37/38

欧盟法规

C&L通报

上下游产品

1-undecen-11-ylbromide 4-(11-tris(2-trimethylsilylethyl)silylundecyloxy)benzoic acid benzyl 4-(11-tris(2-trimethylsilylethyl)silylundecyloxy)benzoate 78H110O10Si4C78H110O10Si4

合成工艺路线路线简述

7766-50-9 = 79769-48-5
反应条件:1.1 Reagents: Trichlorosilane Catalysts: Platinum Solvents: Xylene; 1 H,Rt; 24 H,Rt
标题:Synthesis And Coordinative Layer-By-Layer Deposition Of Pyridine-Functionalized Gold Nanoparticles And Tetralactam Macrocycles On Silicon Substrates
作者:Traulsen,Christoph H.-H.; Et Al
参考文献:Langmuir 日期:2013 卷标:29(46) 页码:14284-14292]

7766-50-9 = 79769-48-5
反应条件:1.1 Reagents: Trichlorosilane Catalysts: Chloroplatinic Acid Solvents: Isopropanol; 24 H,60 °C
标题:A New Bio-Active Surface For Protein Immobilization Via Copper-Free 'Click' Between Azido Sam And Alkynyl Fischer Carbene Complex
作者:Sawoo,Sudeshna; Et Al
参考文献:Chemical Communications (Cambridge 日期:2008 卷标:(45) 页码:5957-5959]

109-76-2 = 79769-48-5
反应条件:1.1 Reagents: Ruthenate(2-),Pentachloro-,Potassium (1:2) Solvents: Methanol,Water; 48 H,Reflux1.2 Reagents: Hydrochloric Acid Solvents: Water2.1 Reagents: (4-Pyridinylmethyl)Lithium (Reaction Product With Alkylsilyl Functionalized Quartz Surface And Rut...) Solvents: Ethanol,Water; 30 Min,Rt; 72 H,Reflux
标题:Synthesis And Bonding Of Trans-Dichlorobis(1,3-Diaminopropane)Ruthenium(Iii) Chloride To A Self Assembled Monolayer And Its Effect On Conducting Polymer Sheet Conductivity
作者:Kariuki,Peter N.; Et Al
参考文献:Inorganica Chimica Acta 日期:2012 卷标:383 页码:320-326]

79769-48-5 = 79769-48-5
反应条件:1.1 Reagents: (4-Pyridinylmethyl)Lithium (Reaction Product With Alkylsilyl Functionalized Quartz Surface And Rut...) Solvents: Ethanol,Water; 30 Min,Rt; 72 H,Reflux
标题:Synthesis And Bonding Of Trans-Dichlorobis(1,3-Diaminopropane)Ruthenium(Iii) Chloride To A Self Assembled Monolayer And Its Effect On Conducting Polymer Sheet Conductivity
作者:Kariuki,Peter N.; Et Al
参考文献:Inorganica Chimica Acta 日期:2012 卷标:383 页码:320-326]

7766-50-9 = 79769-48-5
反应条件:1.1 Reagents: Trichlorosilane Catalysts: Dichloro[(2,3,5,6-η)-3A,4,7,7A-Tetrahydro-4,7-Methano-1H-Indene]Platinum; 10 - 16 H,40 °C
标题:Maleimido-Terminated Self-Assembled Monolayers
作者:Wang,Yayun; Et Al
参考文献:Chemistry - A European Journal 日期:2005 卷标:11(13) 页码:3968-3978]

112-43-6 = 79769-48-5
反应条件:1.1 Reagents: Pyridine,Phosphorus Tribromide Solvents: Toluene; 2 H,-10 - -5 °C; 2 H,100 °C2.1 Reagents: Trichlorosilane Catalysts: Dichloro[(2,3,5,6-η)-3A,4,7,7A-Tetrahydro-4,7-Methano-1H-Indene]Platinum; 10 - 16 H,40 °C
标题:Maleimido-Terminated Self-Assembled Monolayers
作者:Wang,Yayun; Et Al
参考文献:Chemistry - A European Journal 日期:2005 卷标:11(13) 页码:3968-3978

11-溴-1-十一烯置于dihydrogen Hexachloroplatinate,三氯硅烷体系中,用四氢呋喃作为反应溶剂,以79%的收率获得产物11-溴代十一烷基三氯硅烷
参考文献:连接在无机基材表面的单层 C60:组装和结构
标题:连接在无机基材表面的单层 C60:组装和结构
摘要:我们设计了一种新方法,通过(吡啶基)[sub N]-Oso[sub 4]-C[sub 60] 配位络合物将富勒烯 C[sub 60] 连接到硅表面单层化学吸附在基材上.(Pyridyl)[sub N]-Oso[sub 4]-C[sub 60] 单层复合物的结构与衬底的 Sio[sub X] 表面相连,与轮廓和面内结构完全一致由高分辨率 X 射线晶体学确定.虽然轮廓结构已通过 X 射线干涉测量法推导出并被 X 射线全息术证明是独一无二的,但面内/面外结构只是一个模型,与相关 I(Q) 中的六个更强的反射一致[sub Xy],Q[sub Z]) 衍射数据.6 参考,3 无花果.
DOI:10.1021/ja00063A075

海关参考信息

2903399020-溴甲烷
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-2023192731-A1
优先权日:2020-05-29
标题 :Process for the stepwise synthesis of silahydrocarbons
发明人：AUNER NORBERT; STURM ALEXANDER G; SANTOWSKI TOBIAS; FELDER THORSTEN
权利人:MOMENTIVE PERFORMANCE MAT INC
摘要:The invention relates to a process for the stepwise synthesis of silahydrocarbons bearing up to four different organyl substituents at the silicon atom, wherein the process includes at least one step a) of producing a bifunctional hydridochlorosilane by a redistribution reaction, selective chlorination of hydridosilanes with an ether/HCl reagent, or by selective chlorination of hydridosilanes with SiCl 4 , at least one step b) of submitting a bifunctional hydridochloromonosilane to a hydrosilylation reaction, at least one step c) of hydrogenation of a chloromonosilane, and a step d) in which a silahydrocarbon compound is obtained in a hydrosilylation reaction.

专利号:US-9895673-B2
优先权日:2015-12-01
标题:Functionalized surfaces and preparation thereof
发明人：PECK BILL JAMES; INDERMUHLE PIERRE; MARSH EUGENE P; FERNANDEZ ANDRES; STERN DAVID
权利人:TWIST BIOSCIENCE CORP
摘要:Compositions, devices, methods and systems are provided for differential functionalization of a surface of a structure to support biopolymer synthesis. Provided herein are processes which include use of lamps, lasers, and/or microcontact printing to add functional groups to surfaces for the efficient and uniform synthesis of oligonucleic acids.

专利号:US-10183955-B2
优先权日:2015-07-21
标题:Molecules for isolation of polyribosomes, ribosomes, uses and kits thereof
发明人：CLAMER MASSIMILIANO; VIERO GABRIELLA; GUELLA GRAZIANO; QUATTRONE ALESSANDRO
权利人:IMMAGINA BIOTECHNOLOGY S R L
摘要:Molecules of general Formula (I): able to bind to native polyribosomes engaged in active protein synthesis. The disclosure relates also to the use of the molecules of general Formula (I) for isolating at least one active ribosome from a biological sample, and for ribosome profiling, as well as kits for isolating at least one active ribosome from a biological sample.

专利号:EP-3915995-A1
优先权日:2020-05-29
标题:Process for the stepwise synthesis of silahydrocarbons

其他信息查阅

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合成参考文献

参考文献:10.1007/978-1-4419-9647-3_5
摘要:Spruell JM. Heterogeneous Catalysis of a Copper-Coated Atomic Force Microscopy Tip for Direct-Write Click Chemistry. 2011. In: The Power of Click Chemistry for Molecular Machines and Surface Patterning.