CAS: 694-53-1; Phenylsilane

相似化合物

766-08-5 104013-25-4 7072-01-7

上下游产品

CAS号98-13-5 苯基三氯硅烷 | CAS号6157-41-1 2-hydroxy-5-[(5... | CAS号16853-85-3 氢化铝锂 | CAS号780-69-8 苯基三乙氧基硅烷 | CAS号75-16-1 甲基溴化镁 | CAS号4206-75-1 氯苯基硅烷 | CAS号917-54-4 甲基锂 | CAS号775-12-2 二苯基硅烷 | CAS号81956-87-8 (η(5)-C5Me5)2HfH2 | CAS号27484-20-4 phenyl(phenylsi... | CAS号10581-00-7 tribromo(phenyl... | CAS号10581-02-9 tributoxy(pheny... | CAS号4957-14-6 二对甲苯基甲烷 | CAS号139732-72-2 phenylsilyl cation | CAS号4206-75-1 氯苯基硅烷 | CAS号368-47-8 苯基三氟硅烷 | CAS号824-90-8 1-phenyl-1-butene | CAS号1007-03-0 环丙基苯基碳酸酯 | CAS号1425941-73-6 (cyclopropyl(ph... | CAS号1425941-74-7 (PhCH(C3H5)O)2SiHPh

苯基三甲氧基硅烷置于六甲基磷酰三胺,Sodium Tetrahydroborate,溴乙烷,四正辛基溴化铵体系中,用 氘代苯 作为反应溶剂,化学反应 24.0H,以49%的收率获得产物苯硅烷
参考文献:氢硅烷的合成通过路易斯碱催化还原的烷氧基硅烷的用nabh 4 †
标题:氢硅烷的合成通过路易斯碱催化还原的烷氧基硅烷的用nabh 4 †
摘要:通过在六甲基磷酸三酰胺(hmpa)作为路易斯碱催化剂的存在下,用bh 3还原烷氧基硅烷来合成氢硅烷.该反应也可通过使用廉价且易于处理的氢化物源nabh 4来实现,该氢化物源与etbr作为牺牲试剂反应,就地形成bh 3.
DOI:10.1039/c9Cc01961H

专利信息

专利号:US-7651968-B2
优先权日:2005-12-12
标 题:Shaped body comprising a microporous material and at least one silicon-containing binding agent method for production and use thereof as catalyst in particular in a method for continuous synthesis of methylamines
发明人：BOSCH MARCO; EBERHARDT JAN; ROETTGER RODERICH
权利人:BASF SE
摘要:A process for producing a shaped body comprising a microporous material and at least one silicon-comprising binder, which comprises the stepsn (I) preparation of a mixture comprising the microporous material, the binder and a lubricant, (II) mixing and densification of the mixture, (III) shaping of the densified mixture to give a shaped body and (IV) calcination of the shaped body,n nwherein a silicone resin having a softening point of ≧30° C. is used as binder,n nshaped bodies which can be produced by this process, their use as catalyst, in particular in organic synthesis and very particularly preferably in a process for preparing methylamines.

专利号:US-2009005600-A1
优先权日:2005-12-12
标 题:Shaped Body Comprising a Microporous Material and at Least One Silicon-Containing Binding Agent Method for Production and Use Thereof as Catalyst in Particular in a Method for Continuous Synthesis of Methylamines

专利号:US-4139403-A
优先权日:1977-08-19
标题:Dinitroalkyl and fluorodinitroalkyl silicon compounds
发明人：BAUM KURT; LERDAL DUANE A; HORN JERALD S
权利人:US NAVY
摘要:Energetic silicon compounds of the general formulae ##STR1## The gem dinitro compounds are prepared from alkyl bromide silanes by sod nitrite displacement and oxidative nitration. The compounds are then fluorinated. To prepare the polysiloxanes, phenyl blocking groups are used during synthesis of the fluoro dinitro moiety and are then replaced with bromine and the monomer is hydrolyzed.

专利号:US-2009270279-A1
优先权日:2005-05-04
标题 :Materials and Methods for the Photodirected Synthesis of Oligonucleotide Arrays

专利号:CA-1197522-A
优先权日:1982-06-14
标 题 :Synthesis of phenylacetic acid esters

专利号:CN-109503645-A
优先权日:2018-11-19
标题 :A kind of chiral geminal disilyl alkane compound containing four silicon-hydrogen bonds and its synthesis method and application