CAS: 58109-40-3; Diphenyliodonium Hexafluorophosphate

该化合物是一种有机碘化合物,其独特结构包括一种配有六氟磷酸阴离子的二苯并呋喃,该化合物一般是白色至光黄色固体,以其稳定性和溶性在极地有机溶剂中的稳定性和溶性而著称,由于它能够在接触光时产生反应性物种,因此是各种聚合过程的光导动力,特别是在紫外线可保证系统中;六氟磷酸盐的阴离子有助于化合物的离子特性,并提高其在有机介质中的溶性;二苯并二苯并二氟磷酸与其他碘盐相比,其毒性较低,因此在某些应用中成为首选,其反应性和稳定性使其在材料科学和光化学领域具有价值,用于先进材料的合成和涂层.

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合成工艺路线路线简述

    📜二苯基碘鎓高氯酸盐,六氟磷酸钾置于potassium Perchlorate体系中,用 丁酮 作为反应溶剂,化学反应 1.0H,以resulting In 4 Parts Of A Solid的收率获得产物二苯基碘六氟磷酸盐
    参考文献:Method For Making Diaryliodonium Polyhalometalloid Salts
    标题:Method For Making Diaryliodonium Polyhalometalloid Salts
    摘要:本发明提供了一种制备特定二芳基碘化铵光引发剂的方法,该方法基于首先形成二芳基碘酸铵,该二芳基碘酸铵是从二芳基碘酸氢根的前体中形成的.然后将二芳基碘酸铵与一个反离子源(例如碱金属六氟族金属盐)反应,以产生所需的二芳基碘化铵盐,该盐可以用作光引发剂.本发明所述方法制备的碘化铵光引发剂可以用于促进各种阳离子聚合的有机材料的固化,例如环氧树脂.

    专利信息


    专利号:US-8192590-B1
    优先权日:2008-04-14
    标 题:Microwave-assisted formation of sulfonium photoacid generators
    发明人：BELFIELD KEVIN D; YANEZ CICERON O
    权利人:BELFIELD KEVIN D; YANEZ CICERON O; UNIV CENTRAL FLORIDA RES FOUND
    摘要:Efficient method for preparing sulfonium photoacid generators (PAGs) by microwave-assisted reaction of diarylsufides in the presence of alkylaryliodonium salts. Microwave-assisted synthesis of the PAGs is significantly faster, reducing reaction time with less energy consumption. Reaction times using the microwave-assisted synthesis are in a range of from 90 to 420 faster than conventional thermal conditions. The photoacid quantum yields of several salts prepared by the microwave reaction were measured; the photoacid quantum yields of new sulfonium PAGs were in a range from 0.01 to 0.4 times greater than yields from conventional synthesis. Incorporating a nitro group in the structures of the sulfonium salts increased photoacid quantum yield, induced intersystem crossing and increased the efficiency of photoacid generation compounds.

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    主要参考文献

    [参考文献]: Carolyn K Dong, Et Al. Type Ii Nadh Dehydrogenase Of The Respiratory Chain Of Plasmodium Falciparum And Its Inhibitors. Bioorg Med Chem Lett. 2009 Feb 1;19(3):972-5.
    [参考文献]: E Hatanaka, Et Al. Serum Amyloid A Induces Reactive Oxygen Species (Ros) Production And Proliferation Of Fibroblast. Clin Exp Immunol. 2011 Mar;163(3):362-7.
    [参考文献]: Hasan Erbil Abaci, Et Al. Unforeseen Decreases In Dissolved Oxygen Levels Affect Tube Formation Kinetics In Collagen Gels. Am J Physiol Cell Physiol. 2011 Aug;301(2):C431-40.
    [参考文献]: Hyun-Ja Nam, Et Al. Co-Treatment With Hepatocyte Growth Factor And Tgf-Beta1 Enhances Migration Of Hacat Cells Through Nadph Oxidase-Dependent Ros Generation. Exp Mol Med. 2010 Apr 30;42(4):270-9.
    [参考文献]: Li Qian, Et Al. Nadph Oxidase Inhibitor Dpi Is Neuroprotective At Femtomolar Concentrations Through Inhibition Of Microglia Over-Activation. Parkinsonism Relat Disord. 2007:13 Suppl 3:S316-20.

    合成参考文献


    摘要:Chen, P.; Liu, G.; Engle, K. M.; Yu, J.-Q., Science of Synthesis Knowledge Updates, (2013) 2, 67.
    摘要:Jackowski, O.; Perez-Luna, A., Science of Synthesis Knowledge Updates, (2022) 3, 83.
    摘要:Spivey, A. C.; Tseng, C.-C., Science of Synthesis Knowledge Updates, (2010) 1, 18.
    摘要:Sharma, U.; Kumar, R.; Gupta, S. S.; Chandra, D., Science of Synthesis Knowledge Updates, (2022) 2, 232.
    摘要:Sharma, U.; Kumar, R.; Gupta, S. S.; Chandra, D., Science of Synthesis Knowledge Updates, (2022) 2, 371.
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