CAS: 4433-30-1; 1-Phenylundecan-1-One

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📜正癸烯置于[pd(Ipr)(Cin)Cl],Potassium Carbonate体系中,用 四氢呋喃 作为反应溶剂,化学反应 30.0H,反应生成 十一苯酮
参考文献:钯/ Nhc(nhc = N-杂环碳烯)-通过选择性n-C键断裂催化的酰胺的b-烷基铃木交叉偶联
标题:钯/ Nhc(nhc = N-杂环碳烯)-通过选择性n-C键断裂催化的酰胺的b-烷基铃木交叉偶联
摘要:据报道,通过n-C(o)裂解,钯-Nhc(nhc = N-杂环卡宾)具有高度化学选择性,催化b-Sp 3-烷基试剂与活化酰胺之间的直接交叉偶联.钯-Nhc预催化剂可促进酰胺的化学选择性烷基化,这是通过使用强有机金属试剂无法实现的.各种酰胺,包括直接和位点选择性的n,N-Di-Boc活化后具有挑战性的伯酰胺,都与此方法兼容.顺序c(sp 2)-c(sp 2)/ C(sp 2)-c(sp 3)证明了这种温和协议的潜力)交叉偶联,该偶联使用源自共同伯酰胺键的di-Boc酰胺.该方法在b-烷基-Suzuki交叉偶联中提供了空气和水分稳定,轮廓分明且高反应性的pd-Nhc预催化剂的罕见实例.
DOI:10.1021/acs.Orglett.8B02911

专利信息

专利号:US-7517828-B2
优先权日:2003-04-25
标 题 :Chiral broensted acid catalyst for asymmetric synthesis and method of asymmetric synthesis with the catalyst
发明人：AKIYAMA TAKAHIKO
权利人:TOAGOSEI CO LTD
摘要:A compound usable as an asymmetric synthesis catalyst which can be easily synthesized without using any metal such as a lanthanoid group element; a method of asymmetric synthesis with the compound; and a chiral compound obtained by the asymmetric synthesis method. A Broensted acid is used as a catalyst in asymmetric synthesis, the chiral Broensted acid being represented by formula (1) below or formula (3) below. The asymmetric synthesis method employs the catalyst. Asymmetric synthesis with the catalyst gives a chiral compound.

专利号:US-2006276329-A1
优先权日:2003-04-25
标题:Asymmetric synthesis catalyst based on chiral brsnsted acid and method of asymmetric synthesis with the catalyst

专利号:EP-1623971-A1
优先权日:2003-04-25
标 题:Asymmetric-synthesis catalyst based on chiral broensted acid and method of asymmetric synthesis with the catalyst