CAS: 2038-44-0; N'1,N'2-Dihydroxyoxalimidoyl Dichloride

上下游产品

CAS号557-30-2 乙二肟 | CAS号56366-92-8 3-amino-N-hydro... | CAS号4732-58-5 N-(1-chloro-2-n... | CAS号143608-04-2 N-[1,2-bis(dode... | CAS号5728-20-1 3,4-二氯-1,2,5-噻二唑 | CAS号2580-79-2 二氨基乙二醛肟 | CAS号6667-11-4 3,3'-Biisoxazol... | CAS号4331-98-0 Cyanogen,di-N-oxide | CAS号4732-61-0 N-(1,2-diazido-...

乙二肟置于n-氯代丁二酰亚胺体系中,用 N,N-二甲基甲酰胺 用作溶剂,化学反应 10.0H,以70%的收率获得二氯乙二肟
参考文献:氯呋喃和溴呋喃的合成及合成应用.
标题:氯呋喃和溴呋喃的合成及合成应用.
摘要:呋喃喃类化合物在医药和农业化学中是潜在有用的杂芳族单元.然而,由于其合成方法的不发达,基于呋喃喃类化合物的应用受到了阻碍.在这里,我们报告了一种新的合成方法,用于合成氯代和溴代呋喃.起始原料是二氯呋喃和二溴呋喃,并将取代基以模块方式直接引入到呋喃环中.合成的一氟代呋喃并用作安装第二个取代基的底物,以制备进一步的官能化的呋喃喃.
Doi:10.1021/acs.Joc.0C00326

专利信息

专利号:US-11434209-B2
优先权日:2018-08-21
标 题 :Method for synthesis of TKX-50 using insensitive intermediate
发明人：KWON KUK TAE; LEE WOONG HEE; SHIM JEONG SUB; LEE SO JUNG
权利人:AGENCY DEFENSE DEV
摘要:The present disclosure relates to a method for synthesis of TKX-50 using an insensitive intermediate, and more specifically, to a method of manufacturing TKX-50 which includes: preparing DCG as a starting material; forming a THP-DAG intermediate from the DCG; and synthesizing TKX-50 through the THP-DAG intermediate.

专利号:US-2024043406-A1
优先权日:2020-12-18
标题 :Method for sequential one-pot synthesis of tkx-50
发明人：DELAGE ARTHUR; ECK GENEVIÈVE; ALAIME THIBAUD; LACEMON FRÉDÉRICK; KLAPOTKE THOMAS; STIERSTORFER JORG; BOLTER MARC
权利人:EURENCO FRANCE
摘要:The present invention relates to a sequential one-pot synthesis of TKX-50, suitable for larger-scale production, during which an acetyl halide is used during the cyclization of diazidoglyoxime so as to obtain 1,1′-diacetyl-5,5′-bistetrazole, which is then hydrolyzed to 5,5′-bistetrazole-1,1′-diolate, to which compound a hydroxylammonium salt is subsequently added.

专利号:US-4539405-A
优先权日:1984-04-16
标题:Synthesis of 1,4-dinitrofurazano(3,4-b)piperazine
发明人：WILLER RODNEY L
权利人:US NAVY
摘要:The novel explosive compound, 1,4-dinitrofurazano[3,4-b]piperazine, is prepared by the reaction of 2,3-dioximinopiperazine with a base, followed by the nitration of the intermediate furazano[3,4-b]piperazine. The nitrated compound has a density, detonation pressure, detonation velocity and Isp similar to RDX while being highly insensitive.

专利号:RU-2027713-C1
优先权日:1992-09-07
标题 :Morpholinoglyoxime as an intermediate product in the synthesis of 3-morpholino-4-chloro -1,2,5-thiadiazole, and a method of its synthesis

专利号:WO-2020040448-A1
优先权日:2018-08-21
标题 :Method for synthesis of tkx-50 using insensitive intermediate

专利号:EP-4263527-A1
优先权日:2020-12-18
标题 :Method for sequential one-pot synthesis of tkx-50