CAS: 19139-31-2; Dihexyl Fumarate

该化合物是一种有机化合物,分类为氟酸酯,其结构特征包括用两种六氟基乙基酯进行蒸发的硫酸脊椎,在室温下一般是无色的,不显色的黄色液体,具有低挥发性,粘度相对较低,这种化合物在有机溶剂中具有溶解性,在各种应用中都十分有用,包括作为聚合物配方中的增塑剂和有机合成中的潜在中间体.二丙基氟酸酯具有中度的分子重量,在标准条件下一般稳定,尽管在水或酸性或基本条件下可进行水解.其化学特性包括能够参与聚合反应,这可能导致形成具有理想机械和热性的共同聚合物.安全数据表明,与许多化学物质一样,它应该谨慎处理,因为它在与皮肤或眼睛接触时可能会引起刺激.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

(3-Hexyloxycarbonyl)Acrylic Acid 15420-81-2

合成工艺路线路线简述

    📜正己醇置于4-二甲氨基吡啶,盐酸-N-乙基-N'-(3-二甲氨基丙基)碳二亚胺,三乙胺体系中,用 二氯甲烷 用作溶剂,20.0~55.0 °C,101.33 Kpa 条件下,反应 25.0H,反应生成(2E)-2-丁烯二酸二己酯
    参考文献:通过固态[4 + 4]热环加成反应和分子动力学模拟显示的2,3,9,10-四取代并五苯衍生物的面对面包装
    标题:通过固态[4 + 4]热环加成反应和分子动力学模拟显示的2,3,9,10-四取代并五苯衍生物的面对面包装
    摘要:合成了2,3,9,10取代的并五苯四酯和并五苯二酯-二腈.这些并五苯衍生物经历了不寻常的固态[4 + 4]热二聚,具有非常好的效率和完全的立体选择性.该观察结果表明,该并五苯衍生物系列采用的π-π堆积几何结构在固态中具有很大的相互重叠.这一观点已通过分子动力学模拟得到证实.
    Doi:10.1021/acs.Joc.6B00526

    海关参考信息

    专利信息


    专利号:US-5629394-A
    优先权日:1992-12-17
    标 题 :Direct synthesis by living cationic polymerization of nitrogen-containing polymers
    发明人:CHERADAME HERVE M; CHEN FRANK J; STANAT JON E R; NGUYEN HUNG A; TABAR BEHROOZ R
    权利人:EXXON CHEMICAL PATENTS INC
    摘要:A method is provided for the direct synthesis by living cationic polymerization of novel polymeric materials functionalized with desirable nitrogen-containing functional groups such as terminal azido, cyano, carbonylamino, cyanato, thiocyanato or thiocarbonylamino groups. Polymerization and functionalization occur in a substantially simultaneous manner. All necessary reactants for the functionalization are present when polymerization is initiated. The nitrogen-containing functional group is provided as a part of a molecule having a release moiety which is preferably resonance stabilized or a tertiary alkyl type and which acts to aid the nitrogen-containing species in functioning as a leaving group.

    专利号:US-10450525-B2
    优先权日:2014-08-27
    标题:Process for alaknolamide synthesis
    发明人:SUEN YAT FAN; LIU JOANNE; SIMARD FRANCOIS; LEUNG YUEN TING ANITA
    权利人:CHEVRON ORONITE CO
    摘要:The present invention is directed to a process of making alkanolamides wherein the “agingâ€? time is reduced and the diethanol amide to ester ratio in the finished product is increased. Further provided is an additive composition comprising an alkanolamide which contains a reduced amount of DEA and BHEP.

    专利号:US-4486581-A
    优先权日:1979-12-28
    标题 :Use of fumaric acid polymers as antiscalants
    发明人:WALINSKY STANLEY W
    权利人:PFIZER
    摘要:Pumaric acid polymers may be used to control or inhibit scaling in boilers, desalination plants, steam generators, cooling equipment and the like. A novel process for their synthesis employs a mono or dialkyl ester of fumaric acid as a starting material.

    专利号:US-4533709-A
    优先权日:1979-12-28
    标题:Use of fumaric acid polymers as antiscalants
    发明人:WALINSKY STANLEY W
    权利人:PFIZER
    摘要:Fumaric acid polymers may be used to control or inhibit scaling in boilers, desalination plants, steam generators, cooling equipment and the like. A novel process for their synthesis employs a mono or dialkyl ester of fumaric acid as a starting material.

    专利号:CN-119039166-A
    优先权日:2024-08-21
    标题 :A kind of large sterically hindered aspartame polyurea resin and synthesis method

    专利号:US-5444135-A
    优先权日:1992-12-17
    标 题:Direct synthesis by living cationic polymerization of nitrogen-containing polymers

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