CAS: 153766-81-5; Potassium Trifluoro(Phenyl)Borate

该化合物是一种有机体化合物,其特征是存在一个附于一个与三个氟原子相连的共聚物原子的联苯集团,该化合物一般是白色的,白色以外的固体,以其稳定性和溶解于极地溶剂中而闻名,在有机合成中经常使用,特别是在相互交织的反应中,例如铃木-米亚乌拉反应中,它作为形成碳-碳联系的共聚物来源.三氟乙酸盐会增强该化合物的再活性,使它成为制药和农用化学剂开发中的宝贵再生剂.此外,与其它碳溶剂相比,三氟乙酸钾被认为毒性较低,因此在实验室环境中是一种更安全的替代品.其独特的特性和再活性特征使其在现代合成化学中成为一个重要的工具.

结构式图片

相似化合物

98-80-6 215527-70-1 216434-82-1

欧盟法规

C&L通报

合成工艺路线路线简述

    📜二苯基汞 以 水 用作溶剂,化学反应生成苯基三氟硼酸钾
    参考文献:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: B: B-Verb.9,5.1.4,Page 161-166
    标题:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: B: B-Verb.9,5.1.4,Page 161-166

    海关参考信息

    专利信息


    专利号:US-9650355-B2
    优先权日:2013-01-31
    标 题 :Method for preparation of justicidin a derivatives of arylnaphthalene lignan structure
    发明人:HAM JUNGYEOB; KIM TAE JUNG; KWON HAK CHEOL; JEONG KYU HYUK; SONG JUNGHO; CHUNG BONG CHUL
    权利人:KOREA INST SCI & TECH
    摘要:The present disclosure relates to a novel method for preparing an arylnaphthalene lignan compound. In synthesis of arylnaphthalene lignan compounds and derivatives according to the present disclosure, a naphthalene backbone may be constructed first and an aryl group may be introduced at the final stage. Through this, various kinds of derivatives that could not be prepared from the existing methods can be synthesized effectively. Further, the synthesis method according to the present disclosure is appropriate for large-scale production.

    专利号:WO-2012173572-A1
    优先权日:2011-06-10
    标 题 :Stereoselective synthesis of highly substituted enamides
    发明人:PARK CHEOL-MIN; LIU YU
    权利人:UNIV NANYANG TECH; PARK CHEOL-MIN; LIU YU
    摘要:The disclosure provides new methods for the oxidative Heck cross-coupling reaction with electron-rich alkenes such as substituted β-amidoacrylate and other related substituted enamides. Previously, functionalization of enamides under Heck conditions has been limited to those with unsubstituted vinyl groups. By tuning the reaction parameters that allow for the balance between stability and reactivity of the reactants, the oxidative Heck cross-coupling reaction now provides highly substituted enamides in good to excellent yields. (II) (III) (I)·

    专利号:US-7119212-B2
    优先权日:2004-03-30
    标 题 :Process for the preparation of tolterodine and intermediates thereof
    发明人:COLOMBO LINO; ROSSI ROBERTO; ALLEGRINI PIETRO; CASTALDI GRAZIANO
    权利人:DIPHARMA SPA
    摘要:A process for the preparation of 6-methyl-4-(R)-phenyl-chroman-2-one and 6-methyl-4-(S)-phenyl-chroman-2-one, intermediates for the synthesis of tolterodine and its (S) enantiomer, by reaction of 6-methyl-coumarin with phenylboronic acids, esters and derivatives thereof, in the presence of chiral catalysts.

    专利号:CN-119019314-B
    优先权日:2024-09-26
    标 题:Synthesis of Abediterol Precursors

    专利号:CN-119264033-A
    优先权日:2024-09-26
    标 题 :Synthesis method of oxygen-18 substituted Abediterol precursor

    专利号:CN-108203440-B
    优先权日:2016-12-19
    标题 :Solvent-free twin-screw extrusion continuous synthesis process of potassium aryl trifluoroborate

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Black, D. A.; Fagnou, K., Science of Synthesis, (2010) 45, 571.
    摘要:Davies, G. H. M.; Wisniewski, S. R., Science of Synthesis Knowledge Updates, (2021) 2, 175.
    摘要:Davies, G. H. M.; Wisniewski, S. R., Science of Synthesis Knowledge Updates, (2021) 2, 198.
    摘要:Davies, G. H. M.; Wisniewski, S. R., Science of Synthesis Knowledge Updates, (2021) 2, 159.
    摘要:Joule, J. A., Science of Synthesis Knowledge Updates, (2010) 2, 319.
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