CAS: 1461-25-2; Tetrabutyltin

该化合物是有机锡化合物,其特征为四丁基锡化合物,其四丁基锡组附在锡原子上,在室内温度下对黄黄色液体无色,具有较高的沸点和低挥发性.四丁基锡以其疏水性闻名,使其在水中无法溶解,但在有机溶剂中可溶解.这种化合物主要用作海洋油漆以及各种工业应用中的生物杀灭剂和防污剂,包括聚氯乙烯生产中的稳定剂.然而,必须指出,四丁基锡对水生生物有毒,并造成环境风险,导致监管审查.其化学结构允许丁基锡可能释放丁基化合物,从而进一步增加其毒性.鉴于这些特性,处理四丁基锡需要谨慎,应当采取适当的安全措施,以减少接触和环境影响.

结构式图片

MSDS等安全信息

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号24850-33-7 烯丙基三丁基锡 | CAS号7486-35-3 三丁基乙烯基锡 | CAS号595-90-4 四苯基锡 | CAS号56-35-9 三丁基氧化锡 | CAS号683-18-1 二丁基二氯化锡 | CAS号144-55-8 碳酸氢钠 | CAS号78443-73-9 2,4-dichloro-6-... | CAS号109-72-8 正丁基锂 | CAS号89727-03-7 tributyl-[1-(me... | CAS号487-89-8 3-吲哚甲醛 | CAS号111735-91-2 4-butyl-1H-indo... | CAS号544-40-1 二丁基硫醚 | CAS号16892-65-2 2,2,4,4,6,6-hex... | CAS号563-25-7 二丁基二氟锡 | CAS号1983-10-4 三正丁基氟化锡 | CAS号37920-25-5 4-丁基苯乙酮 | CAS号72679-69-7 2-butyl-isonico... | CAS号142730-56-1 4-butylpyridine... | CAS号629-45-8 二丁基二硫醚

合成工艺路线路线简述

    📜二正丁基氧化锡置于正丁基锂体系中,用 四氢呋喃 用作溶剂,以80%的收率获得四丁基锡
    参考文献:有机锂试剂裂解锡氧键和锡硫键
    标题:有机锂试剂裂解锡氧键和锡硫键
    摘要:
    Doi:10.1016/s0022-328X(00)86348-2

    海关参考信息

    专利信息


    专利号:US-5705659-A
    优先权日:1994-09-30
    标 题 :Intermediates for the synthesis of 16-phenoxy-prostatrienoic acid derivatives and a preparing method thereof
    发明人:PARK HOKOON; JUNG SUN HO; LEE YONG SUP; NAM KI HONG
    权利人:KOREA INST SCI & TECH
    摘要:Intermediate compounds represented as formula (I) useful for the synthesis of 16-phenoxy-prostatrienoic acid derivatives and a preparing method thereof are disclosed. ##STR1## wherein R is tetrahydropyranyl, tetrahydrofuranyl, 2-ethoxyethyl, t-butyldimethylsilyl, triisopropylsilyl or triethylsilyl group; R 1 and R 2 are independently hydrogen or ester-forming group; P is hydrogen, trimethylsilyl or tri-n-butyltin; and wavy line means epi-stereoisomeric mixture.

    专利号:US-2014255328-A1
    优先权日:2013-03-11
    标 题:Hydrothermal Synthesis of Zinc Phlogopite
    发明人:MCGUIRE MEAGHAN CLARK; BULL IVOR; JOHNSON GEOFFREY MARK
    权利人:BASF SE
    摘要:This invention relates to a synthetically derived zinc phlogopite platelets, of superior platelet diameter, effect pigments comprising such synthetically derived platelets and methods of forming said substrates. More specifically the disclosure describes an improved hydrothermal synthesis of zinc phlogopite suitable as a platelets for interference pigments, barrier and flame retardant applications.

    专利号:US-4584354-A
    优先权日:1981-04-17
    标 题:Graft copolymers and the method of their preparation
    发明人:HUDECEK SLAVKO; HUDECKOVA IVANA; CEFELIN PAVEL
    权利人:CESKOSLOVENSKA AKADEMIE VED OF
    摘要:Graft copolymers are formed having a backbone formed by monomeric units, selected from the group of vinyl monomers comprising acrylates, methacrylates, acrylamide, styrene and N-vinyl-2-phyrrolidone, and side branches formed by 10-80 wt. % of oligourethanes based on aliphatic, aromatic and alkylaromatic diisocyanates and low-molecular-weight diols with 2-4 carbon atoms in the molecule. The graft copolymers are prepared in two steps: the first step consists in the synthesis of oligourethane with the terminal unsaturated group; the second step is the radical copolymerization of this oligourethane with the above vinyl monomers.

    专利号:US-2024383928-A1
    优先权日:2021-07-30
    标 题:Production of diorganotin dihalides
    发明人:VINCENT ROBERT; ZIMMERMANN JARROD C
    权利人:MERCK PATENT GMBH
    摘要:The disclosed and claimed subject matter relates to the safe and efficient synthesis of diorganotin dihalide compounds of the formula R2SnX2 that as-synthesized are free of tetraalkyltin (R4Sn), trialkyltin halide (R3SnX) and monoalkyltin trihalide (RSnX3) species and of methods for their synthesis and use.

    专利号:US-4360688-A
    优先权日:1981-05-21
    标题 :Precursors and synthesis of d1-(methyl)-16,16-(dimethyl)-11-alpha, 15-alpha, beta-dihydroxy-9-oxo-2,13,-trans, trans-prostadienoates
    发明人:FLOYD JR MIDDLETON B
    权利人:AMERICAN CYANAMID CO
    摘要:Novel compounds are disclosed of the classes: ##STR1## wherein the subscript n is an integer from 3-5, inclusive, R 1 is hydrogen or R 2 ; R 2 and R 3 consist essentially of C 1 -C 6 alkyl and R 2 may be the same as or different from R 3 , and wherein Aryl consists essentially of phenyl and phenyl substituted with halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, and trifluoromethyl; n (b) derivatives of furan having the formula ##STR2## wherein R 4 consists essentially of hydrogen and C 1 -C 6 alkyl, and W is either carbonyl or carbinol; and n (c) cyclopentenonyl compounds having the formulas ##STR3## wherein R 5 consists essentially of hydrogen and C 1 -C 6 alkyl, P 1 is hydrogen or a protective group, Y is either ##STR4## A new process is disclosed for preparing 1-(methyl)-16,16-(dimethyl)-11-alpha-15-alpha-dihydroxy-9-oxo-2,13,trans, trans-prostadienoate, and congeners thereof, including racemic mixtures.

    专利号:US-6215010-B1
    优先权日:2000-08-02
    标题 :Synthesis of organotin oxides
    发明人:GROSSMAN RICHARD F
    权利人:HAMMOND GROUP INC
    摘要:Organotin oxides are synthesized by reacting powdered tin metal with an alcohol at elevated temperatures on the order of about 200-400° C. Dialkyltin oxides are produced in quantitative yields according to the method.

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
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