CAS: 94278-27-0; Ethyl 3-((Furan-2-Ylmethyl)Thio)Propanoate

化学文摘社编号942778-270,该化学文摘社称丙酸和乙醇为有机化合物化合物,其成分为酯类3-[2-furanyl-27-0],其成分为酯类功能,其特性为酯类3-[2-furanyl-27-0],其成分为酯类功能组,其成分来自丙酸和乙醇,其结构中存在呋喃环,有助于其独特的化学特性,包括在不同条件下潜在的回活动性和稳定性.该化合物的结构特征可能允许进行各种修改,从而导致衍生物具有特定药物或农业化学应用的特性.

英文名称Ethyl 3-((Furan-2-Ylmethyl)Thio)Propanoate
中文名称3-((呋喃-2-基甲基)硫代)丙酸乙酯
IUPAC名称ethyl 3-((furan-2-ylmethyl)thio)propanoate
其它别名3-(糠基硫代)丙酸乙酯; Ethyl 3-Furfurylthio Propionate
CAS编号94278-27-0
MFCD编号:MFCD00051819
EINECS号:304-716-7
FDA UNII编号:E9G0NGH9PL
分子式:C10H14O3S
分子量:214.29
产品CID: 1992554
产品分类有机原料→分子砌块→芳杂环类化合物→呋喃类化合物

相似结构搜索
InChIKey: ZKCVVCLCYIXCOD-UHFFFAOYSA-N
InChI=1S/C10H14O3S/c1-2-12-10(11)5-7-14-8-9-4-3-6-13-9/h3-4,6H,2,5,7-8H2,1H3…
计算化学: 氢键受体数4.0氢键供体数0.0可旋转键数6.0

相似化合物

58066-86-7 59020-85-8 94278-26-9

MSDS等安全信息

GHS象形图
GHS符号GHS07;
注释: Exclamation mark
危险类别皮肤腐蚀/刺激类别2
严重眼刺激类别2
警示词Warning(警告)
危险描述H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
防范说明P264-P280-P302+P352-P305+P351+P338-P362+P364
UN编号NONH for all modes of transport
安全声明24/25
WGK Germany3

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

Ethyl 3-bromopropionate 2-thiolomethyl-furan

合成工艺路线路线简述

3-溴丙酸乙酯,糠基硫醇置于sodium Ethanolate体系中,化学反应生成 3-糠硫基丙酸乙酯
参考文献:Regio-And Stereocontrol In The Intramolecular Nitrile Oxide Cycloaddition To 2-Furylthiol-And 2-Furylmethanethiol Derivatives.
标题:Regio-And Stereocontrol In The Intramolecular Nitrile Oxide Cycloaddition To 2-Furylthiol-And 2-Furylmethanethiol Derivatives.
摘要:A Series Of 2-Furyl And 2-Furylmethyl Substituted Nitrosulphides With A Proper Chain Length Were Prepared And Showed To Undergo A Totally Regiocontrolled Intramolecular Furan-Nitrile Oxide Cycloaddition To Give Cis-Fused Products In High Yield. Insertion Of A Stereocenter On The Cycloaddends Did Not Allow Satisfactory Control Of The Absolute Stereochemistry Of The Reaction. Enantiomerically Enriched Products (E.E. Less-Than-Or-Equal-To 95%) Were Obtained By A Kinetic Resolution Process Involving Oxidation Of The Sulphide Cycloadducts To The Corresponding Sulphoxides.
DOI:10.1016/s0040-4020(01)80910-8