CAS: 873-51-8; Dichlorophenylborane

该化合物是有机有机体化合物,其特征是存在附于一个子原子的苯基组,该化合物又被联结到两个氯原子上.该化合物一般是淡黄色液体的无色物质,以其活性闻名,特别是在水分存在的情况下,它可以水解形成苯丙酸.它用于有机合成,特别是形成碳-boron联结,在各种化学反应(包括交叉组合反应)中很有价值.该化合物具有中度毒性,应谨慎处理,因为它会刺激皮肤,眼睛和呼吸系统.此外,在冷干燥的地方储存二氯化苯并呋喃,远离湿气和不相兼容的物质,以保持其稳定性并防止其不想要的反应.

结构式图片

相似化合物

104013-25-4 860585-01-9 402-27-7

物理性质

MSDS等安全信息

欧盟法规

ECHA物质C&L通报

上下游产品

triphenylboroxine bis(s-butyloxy)phenyl borane diphenylboronchloride diethyl phenylboronate(ethyloxy)chloro-phenylborane (n-butyloxy)chloro-phenylborane chloro-phenoxy-phenyl-borane

合成工艺路线路线简述

  • 768-32-1 = 873-51-8
    反应条件:1.1 Reagents: Boron Trichloride
    标题:Arylhaloboranes
    作者:Haubold,Wolfgang; Et Al
    参考文献:Journal Of Organometallic Chemistry 日期:1986 卷标:315(1) 页码:1-8]

    768-32-1 = 873-51-8
    反应条件:1.1 Reagents: Boron Trichloride Solvents: Dichloromethane
    标题:Borylation Of Arylsilanes. I. A General,Easy,And Selective Access To Phenyldihaloboranes
    作者:Kaufmann,Dieter
    参考文献:Chemische Berichte 日期:1987 卷标:120(5) 页码:853-4]

    = 873-51-8
    反应条件:1.1 Reagents: Methyl Iodide,Aluminum Solvents: Benzene
    标题:Synthesis Of Organoboranes
    作者:Muetterties,E. L.
    参考文献:Journal Of The American Chemical Society 日期:1960 卷标:82 页码:4163-6]

    = 873-51-8
    反应条件:1.1 Reagents: Aluminum,Aluminum Chloride
    标题:Synthesis Of Aryl Dichloroboranes
    作者:Muetterties,E. L.
    参考文献:Journal Of The American Chemical Society 日期:1959 卷标:81]

    = 873-51-8
    反应条件:1.1 Reagents: Boron Trichloride
    标题:Phenylboron Dichloride
    作者:Miyaura,Norio
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1]

    31044-59-4 = 873-51-8
    反应条件:1.1 Reagents: Boron Trichloride Catalysts: Iron Chloride (Fecl3) Solvents: Dichloromethane
    标题:Organoboranes. 55. Improved Procedure For The Conversion Of Representative Achiral And Chiral Alkyl-,(E)-1-Alkenyl And (Z)-1-Alkenyl-,And Arylboronates Into The Corresponding Organyldichloroboranes
    作者:Brown,Herbert C.; Et Al
    参考文献:Organometallics 日期:1992 卷标:11(9) 页码:3094-7]

    100-34-5 = 873-51-8
    反应条件:1.1 Reagents: Cytidylyl-(3′->5′)-Uridine,Mercuric Chloride2.1 Reagents: Boron Trichloride
    标题:Phenylmercury(Ii) Chloride
    作者:Khanna,Rajinder N.; Et Al
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]

    = 873-51-8
    反应条件:1.1 -2.1 Reagents: Boron Trichloride
    标题:Phenylmercury(Ii) Chloride
    作者:Khanna,Rajinder N.; Et Al
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-3]

    1534-67-4 = 873-51-8 + 941-78-6
    反应条件:1.1 Reagents: Boron Trichloride Solvents: Dichloromethane; 2 - 4 °C; 24 H,22 °C
    标题:The Preparation Of Pentafluorophenyldihaloboranes From Pentafluorophenylmercurials C6F5Hgr And Bx3: The Dramatic Dependence Of The Reaction Direction On The Ligand R
    作者:Bardin,Vadim V.; Et Al
    参考文献:Monatshefte Fuer Chemie 日期:2019 卷标:150(8) 页码:1523-1531]

    768-32-1 = 873-51-8
    反应条件:1.1 Reagents: Boron Trichloride Solvents: Dichloromethane; 15 Min,-78 °C; 1 H,-78 °C; 12 H,-78 °C -> Rt
    标题:Regioselective Reductive Opening Of Benzylidene Acetals With Dichlorophenylborane/triethylsilane: Previously Unreported Side Reactions And How To Prevent Them
    作者:Henault,Jerome; Et Al
    参考文献:Journal Of Organic Chemistry 日期:2022 卷标:87(2) 页码:963-973]

    = 873-51-8 [标题:Reaction Conditions
    标题:Product Subclass 7: Hydroxyboranes
    作者:Miyaura,N.
    参考文献:Science Of Synthesis 日期:2004 卷标:6 页码:257-300]

    = 873-51-8
    反应条件:1.1 Reagents: Boron Tribromide Solvents: Benzene; 4 H,Reflux
    标题:The Preparation Of Pentafluorophenyldihaloboranes From Pentafluorophenylmercurials C6F5Hgr And Bx3: The Dramatic Dependence Of The Reaction Direction On The Ligand R
    作者:Bardin,Vadim V.; Et Al
    参考文献:Monatshefte Fuer Chemie 日期:2019 卷标:150(8) 页码:1523-1531]

    = 873-51-8
    反应条件:1.1 Reagents: Boron Trichloride
    标题:Phenylmercury(Ii) Chloride
    作者:Khanna,Rajinder N.; Et Al
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]

    = 873-51-8
    反应条件:1.1 Reagents: Boron Trichloride Solvents: Chlorobenzene; 0.5 H,Rt
    标题:The Preparation Of Pentafluorophenyldihaloboranes From Pentafluorophenylmercurials C6F5Hgr And Bx3: The Dramatic Dependence Of The Reaction Direction On The Ligand R
    作者:Bardin,Vadim V.; Et Al
    参考文献:Monatshefte Fuer Chemie 日期:2019 卷标:150(8) 页码:1523-1531]

    = 873-51-8
    反应条件:1.1 Reagents: Mercuric Chloride2.1 Reagents: Boron Trichloride
    标题:Phenylmercury(Ii) Chloride
    作者:Khanna,Rajinder N.; Et Al
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-3]

    = 873-51-8
    反应条件:1.1 Reagents: Mercuric Chloride2.1 Reagents: Boron Trichloride
    标题:Phenylmercury(Ii) Chloride
    作者:Khanna,Rajinder N.; Et Al
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]

    = 873-51-8
    反应条件:1.1 Reagents: Boron Trichloride
    标题:Phenylboron Dichloride
    作者:Miyaura,Norio
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1]

    100-34-5 = 873-51-8
    反应条件:1.1 Reagents: Mercuric Chloride,Hydrochloric Acid1.2 Catalysts: Copper2.1 Reagents: Boron Trichloride
    标题:Phenylmercury(Ii) Chloride
    作者:Khanna,Rajinder N.; Et Al
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-3]

    = 873-51-8
    反应条件:1.1 -2.1 Reagents: Boron Trichloride
    标题:Phenylmercury(Ii) Chloride
    作者:Khanna,Rajinder N.; Et Al
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-3]

    = 873-51-8
    反应条件:1.1 100 °C2.1 Reagents: Boron Trichloride
    标题:Phenylmercury(Ii) Chloride
    作者:Khanna,Rajinder N.; Et Al
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]

    618-41-7 = 873-51-8
    反应条件:1.1 Reagents: Mercuric Chloride2.1 Reagents: Boron Trichloride
    标题:Phenylmercury(Ii) Chloride
    作者:Khanna,Rajinder N.; Et Al
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-3]

    618-41-7 = 873-51-8
    反应条件:1.1 Reagents: Mercuric Chloride2.1 Reagents: Boron Trichloride
    标题:Phenylmercury(Ii) Chloride
    作者:Khanna,Rajinder N.; Et Al
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]

    3262-89-3 = 873-51-8
    反应条件:1.1 Reagents: Aluminum Chloride Solvents: Octane
    标题:Boron Compounds. 71. Novel Organoboron-Oxygen-Haloaluminum Compounds From Triorganoboroxins With Aluminum Trihalides
    作者:Koester,Roland; Et Al
    参考文献:Chemische Berichte 日期:1986 卷标:119(4) 页码:1301-14]

    = 873-51-8 + 1135-99-5
    反应条件:1.1 Catalysts: Boron Trichloride
    标题:Boron Trichloride
    作者:Miyaura,Norio
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]

    879-05-0 + 1192-89-8 = 873-51-8 + 941-78-6
    反应条件:1.1 Solvents: Diethyl Ether,Tetrahydrofuran; 3 H,Reflux2.1 Reagents: Boron Trichloride Solvents: Dichloromethane; 2 - 4 °C; 24 H,22 °C
    标题:The Preparation Of Pentafluorophenyldihaloboranes From Pentafluorophenylmercurials C6F5Hgr And Bx3: The Dramatic Dependence Of The Reaction Direction On The Ligand R
    作者:Bardin,Vadim V.; Et Al
    参考文献:Monatshefte Fuer Chemie 日期:2019 卷标:150(8) 页码:1523-1531]

    = 873-51-8 + 941-78-6
    反应条件:1.1 Reagents: Mercury Dibromide Solvents: Diethyl Ether; 4 H,Reflux2.1 Solvents: Diethyl Ether,Tetrahydrofuran; 3 H,Reflux3.1 Reagents: Boron Trichloride Solvents: Dichloromethane; 2 - 4 °C; 24 H,22 °C
    标题:The Preparation Of Pentafluorophenyldihaloboranes From Pentafluorophenylmercurials C6F5Hgr And Bx3: The Dramatic Dependence Of The Reaction Direction On The Ligand R
    作者:Bardin,Vadim V.; Et Al
    参考文献:Monatshefte Fuer Chemie 日期:2019 卷标:150(8) 页码:1523-1531
二苯基汞置于三氯化硼体系中,化学反应生成 二氯苯酚溴酯
参考文献:Michaelis; Becker,Chemische Berichte,1880,Vol. 13,P. 59,61
标题:Michaelis; Becker,Chemische Berichte,1880,Vol. 13,P. 59,61

海关参考信息

专利信息


专利号:US-9938312-B2
优先权日:2011-03-25
标题 :Compounds and methods for chemical and chemo-enzymatic synthesis of complex glycans
发明人：BOONS GEERT-JAN; WANG ZHEN
权利人:BOONS GEERT JAN; WANG ZHEN; UNIV GEORGIA
摘要:The present invention provides chemical and chemo-enzymatic methods for the synthesis of a wide array of complex asymmetric multi-antennary glycans.

专利号:US-8937188-B2
优先权日:2009-04-29
标 题:Process for the preparation of lasofoxifene tartrate
发明人：KHAN MUBEEN AHMED; TRIVEDI NIKHIL RASIKLAL; KANDASAMY NAGAN NIRMALAN; PATIL DAYAGHAN GANGADHAR; PANDEY VIPIN KUMAR; SINHA SUKUMAR
权利人:KHAN MUBEEN AHMED; TRIVEDI NIKHIL RASIKLAL; KANDASAMY NAGAN NIRMALAN; PATIL DAYAGHAN GANGADHAR; PANDEY VIPIN KUMAR; SINHA SUKUMAR; GLENMARK GENERICS LTD
摘要:A solid crystalline form of 1-(2-[4-(6-methoxy-3,4-dihydronaphthalene-1-y) phenoxy]ethyl)pyrrolidine, and a preparing process thereof are provided. The aforesaid compound is a key intermediate in the synthesis of lasofoxifene. A process for preparing lasofoxifene, a process for purifying lasofoxifene tartrate, and a crystalline form of lasofoxifene tartrate are also provided.

专利号:US-10336784-B2
优先权日:2016-03-08
标 题 :Methods for modular synthesis of N-glycans and arrays thereof
发明人：WONG CHI-HUEY; WU CHUNG-YI; SHIVATARE SACHIN S
权利人:ACADEMIA SINICA
摘要:The present disclosure relates to novel modular methods for generating a diversity of N-glycans of high mannose, hybrid and complex types. The present disclosure also relates to exemplary arrays of the synthesized N-glycans spotted onto aluminium oxide coated slides. These arrays can be used to detect and analyze binding interactions between the synthesized N-glycans and glycan binding molecules, such as HIV-1 neutralizing antibodies. The present disclosure also relates to methods for identifying agents that bind to various types of molecules on the arrays and to defining the structural elements of the molecules on the arrays that bind to those agents. The arrays and methods provided herein may be used for general epitope identification, drug discovery and as analytical tools. The present disclosure also provides useful glycans and epitope determinants that are useful in detecting, diagnosing, recurrence monitoring and preventing pathological diseases such as HIV.

专利号:US-9644073-B2
优先权日:2012-12-14
标 题 :Method for the synthesis of a chlorine-free, pre-ceramic polymer for the production of ceramic molded bodies
发明人：GRABE NORMAN; ROTHMANN MICHAEL
权利人:BJS CERAM GMBH
摘要:A method for producing a polysilane includes a disproportionation reaction of a methylchlorodisilane mixture to form chlorine-containing oligosilane, a substitution reaction of the chlorine atoms contained in the oligosilane by the reaction with a primary amine and a cross-linking reaction of the oligosilanes using a chain former to form polysilanes. The obtained polysilanes are infusible and are very suitable for being spun to form green fibers and processed to form silicon carbide fibers and fiber composites. The method is characterized in that it can be carried out cost-effectively and quickly and with very high yields.

专利号:US-2024229131-A1
优先权日:2022-12-22
标 题 :Transition-metal catalyst compositions and methods for sequencing by synthesis
发明人：MARIANI ANGELICA; BEECH TIMOTHY; FRANCAIS ANTOINE; PANIGRAHI ADYASHA; HATTINGH KATHRYN; CRESSINA ELENA
权利人:ILLUMINA INC
摘要:The present application relates to compositions and methods for sequencing by synthesis. A blocking group of a nucleotide may be removed by a transition metal catalyst, the transition metal catalyst activated by a non-reducing ligand and a reducing agent.

专利号:US-2024247311-A1
优先权日:2022-12-22
标题 :Palladium catalyst compositions and methods for sequencing by synthesis
发明人：PEDROSO CASSIO; PANIGRAHI ADYASHA; MARIANI ANGELICA; CARVER ADAM; HOURS RAPHAËLLE; CHANDRACHUD PREETI; FRANCAIS ANTOINE; APSUNDE TUSHAR; HATTINGH KATHRYN; BEECH TIMOTHY; SOLIS DANIEL; LAWRENCE ELLIOT J
权利人:ILLUMINA INC
摘要:The present application relates to palladium catalyst composition and uses in sequencing by synthesis. In particular, the Pd catalyst composition comprises one or more macrocycles (e.g., cyclodextrin or analogs thereof) as additives for improving thermal or oxidative stability of the active Pd(0) species.

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合成参考文献


摘要:Davies, G. H. M.; Wisniewski, S. R., Science of Synthesis Knowledge Updates, (2021) 2, 114.
摘要:Davies, G. H. M.; Wisniewski, S. R., Science of Synthesis Knowledge Updates, (2021) 2, 164.
摘要:Bubnov, Yu. N.; Kolomnikova, G. D., Science of Synthesis Knowledge Updates, (2012) 3, 257.
摘要:Davies, G. H. M.; Wisniewski, S. R., Science of Synthesis Knowledge Updates, (2021) 2, 158.
摘要:Davies, G. H. M.; Wisniewski, S. R., Science of Synthesis Knowledge Updates, (2021) 2, 165.
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