苄基乙基醚置于mortierella Isabellina Nrrl 1757体系中,用60%的收率获得产物乙醇 参考文献:Removal Of O-And N-Benzyl Groups By Fungal Biotransformation 标题:Removal Of O-And N-Benzyl Groups By Fungal Biotransformation 摘要: DOI:10.1016/s0040-4039(00)82354-0
专利号:WO-2025062384-A2 优先权日:2023-09-23 标题 :A method for synthesis of metal halide perovskite (cspbbr3) nano/microcrystals 发明人:M A GOKUL; RAHMAN ATIKUR 权利人:INDIAN INSTITUTE OF SCIENCE EDUCATION AND RES PUNE IISER PUNE 摘要:The present invention relates to metal halide perovskite (CsPbBr3) nano/microcrystals. Specifically, the present invention relates to a method for the synthesis of metal halide perovskite (CsPbBr3) nano/microcrystals. The present invention uses an easy, scalable low temperature growth of metal halide nanoparticles like CsPbBr3. The method uses a clever play on the solubility and ion exchange mechanism to precipitate nano and microcrystals of metal halide perovskites. The synthesis resulted in stable perovskite crystals with high photo- luminescence, ultralow dark current and control over their morphology. The combination of ultralow dark current, high responsivity, exceptional detectivity, and broad-band photon detection capabilities makes these crystals an excellent choice for upcoming sensors and detector technologies.
专利号:US-11866398-B2 优先权日:2018-05-15 标 题:Total synthesis of prostaglandin J natural products by stereoretentive metathesis 发明人:LI JIAMING; CHEN XU; AHMED TONIA S; STOLTZ BRIAN M; GRUBBS ROBERT H 权利人:CALIFORNIA INST OF TECHN 摘要:This invention relates generally to the synthesis of Δ12-Prostaglandin J product using stereoretentive ruthenium olefin metathesis catalysts supported by dithiolate ligands. Δ12-Prostaglandin J products were generated with excellent selectivity (>99% Z) and in moderate to high/good yields (47% to 80% yield; 58% to 80% yield).
专利号:WO-2021260722-A1 优先权日:2020-06-21 标 题:Design, synthesis of novel oxyindole inhibitors of denv rna dependent rna polymerase 发明人:GUNDLA RAMBABU; ASTHANA SHAILENDRA; BHATTACHARYYA SANKAR; MADDIPATI VENKATANARAYANA CHOWDARY; MITTAL LOVIKA; KAUR JASKARAN; RAWAT YOGITA 权利人:TRANSLATIONAL HEALTH SCIENCE AND TECH INSTITUTE; GANDHI INSTITUTE OF TECH AND MANAGEMENT 摘要:The present invention is drawn to novel compounds of formula I, II and III, including any conformational isomeric form, salts and solvates for inhibition of DENV RNA dependent and RNA polymerase. The present invention also discloses a process of synthesis of the compounds, compositions comprising the said compounds and use of the compounds and treatment comprising the compounds of the present invention.
专利号:US-9763452-B2 优先权日:2012-06-11 标 题 :Synthesis of MOFs 发明人:MORRIS RUSSELL EDWARD; WHEATLEY PAUL STEWART; WARRENDER STEWART; DUNCAN MORVEN 权利人:UNIV COURT UNIV ST ANDREWS; UNIVERISTY COURT OF THE UNIV OF ST ANDREWS 摘要:The present invention relates to the synthesis of a variety of metal organic frameworks (MOFs) using low temperature and solvents which are considered to be not particularly harmful to the environment. There is also provided novel MOFs which may be made by the desired processes.
专利号:EP-4092127-A1 优先权日:2021-05-18 标题:Enzyme-catalytic method for the direct stereoselective synthesis of gamma-(acyloxy) carboxylic acids 发明人:PARVE JAAN; KUDRJASHOVA MARINA; GATHERGOOD NICHOLAS; PARVE OMAR 权利人:TALLINN UNIV OF TECHNOLOGY 摘要:The present invention is a method for the stereoselective straightforward synthesis of gamma-acyloxy carboxylic acids of novel structure starting from racemic gamma-hydroxy carboxylic acid salts that are obtained by alkaline hydrolysis of the racemic gamma-lactones. The salt is acylated by enzyme catalysis in an organic solvent containing an acyl donor and an immobilised lipase, on stirring at room temperature (ca 20 °C) until reaching the conversion rate required. After that, the reaction mixture is acidified and extracted and the product treated with catalytic amount of para-toluenesulfonic acid in toluene during the time required for the relactonisation of the unreacted salt enantiomer. Thereafter, the target gamma-acyloxy carboxylic acid formed from one enantiomer of the starting compound and relactonised gamma-lactone formed from the other, unreacted enantiomer of the starting compound are isolated using a routine separation method, such as distillation, extraction with NaHCO3 water solution followed by acidification or column chromatography.
专利号:WO-2025015696-A1 优先权日:2023-07-17 标题:β-CYC-ASSISTED SYNTHESIS OF IN-V GROUP QUANTUM DOT, AND SYNTHESIS METHOD THEREFOR AND USE THEREOF 发明人:LI GUOQIANG; LIANG JIEHUI; WANG JUNKUN; GUO JIANSEN; LIU PEIXIN 权利人:UNIV SOUTH CHINA TECH 摘要:Provided are β-cyc-assisted synthesis of an In-V group quantum dot, and a synthesis method therefor and the use thereof. The method for β-cyc-assisted synthesis of an In-V group quantum dot comprises: preparing a β-cyc-containing precursor solution of an In source and a V group element source, and subjecting it to a hydrothermal reaction; extracting a stock solution after the hydrothermal reaction by using an organic solvent; removing β-cyc from the stock solution, washing same with water and then extracting same; and heating and concentrating same to obtain a high-concentration In-V group quantum dot solution. With regard to the β-cyc-assisted synthesis of an In-V group quantum dot, the In-V group quantum dot synthesized with the assistance of β-cyc is prepared by using the method for β-cyc-assisted synthesis of an In-V group quantum dot. The use of β-cyc-assisted synthesis of an In-V group quantum dot is the use of the β-cyc-assisted synthesis of an In-V group quantum dot in the field of photovoltaics, and the field of photovoltaics comprises solar cells, photoelectrochemical hydrogen production and photoelectric detectors. Compared with traditional synthesis methods, this synthesis method has the advantages of green and environmentally friendly raw materials, a simple and safe process, a simple and convenient device, efficient and economic synthesis, and being low cost.
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