CAS: 40663-68-1; 4-(Allyloxy)Benzaldehyde

该化合物是有机化合物,其特点是甲醛功能组和苯环上的甲氧代代替代物都有,该化合物一般是一种无色的黄色液体,具有独特的芳香味;其分子结构具有苯并二甲丁胺(Benzalthyde mothy)特征,其位置与乙酰氧组(-O-CH2-CH=CH2)相对应,这种结构影响其再活动性和特性,使其在有机合成中成为有用的中间体,特别是在生产各种药品和农用化学品方面;该化合物一般在乙醇和醚等有机溶剂中溶解,但水溶解性有限;此外,该化合物的分子结构可能具有中度毒性,需要适当的处理和安全防范;其再活动可归因于甲醛和甲酰组的存在,允许各种化学转化,包括核毒剂添加反应和聚合物.

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上下游产品

CAS号123-08-0 4-羟基苯甲醛; 对羟基苯甲醛 | CAS号106-95-6 烯丙基溴 | CAS号109-64-8 1,3-二溴丙烷 | CAS号3256-45-9 4-(2-Propen-1-Y... | CAS号74323-90-3 para-(allyloxy)... | CAS号107-05-1 氯丙烯 | CAS号36844-51-6 4-Allyloxybenzo... | CAS号90-02-8 水杨醛 | CAS号16215-47-7 4-Allyoxystyrene | CAS号106456-81-9 5 10 15 20-TETR... | CAS号123-08-0 4-羟基苯甲醛; 对羟基苯甲醛 | CAS号5736-85-6 4-丙氧基苯甲醛 | CAS号71771-90-9 R(-)-去甲胺 | CAS号10035-16-2 苯并呋喃-5-甲醛 | CAS号32078-38-9 1-(chloromethyl... | CAS号33148-47-9 4-(烯丙氧基)苯甲腈 | CAS号35750-24-4 4-(烯丙氧基)苯甲酸甲酯 | CAS号136433-45-9 4-prop-2-enoxy-... | CAS号27914-60-9 4-(烯丙氧基)苯甲酸

合成工艺路线路线简述

    📜(E)-1-(4-Hydroxyphenyl)Propene置于氧气,Potassium Carbonate体系中,用 二甲基亚砜,丙酮 作为反应溶剂,20.0 °C,200.0 Kpa 条件下,反应 28.0H,反应生成 4-烯丙氧基苯甲醛
    参考文献:Expanding The Regioselective Enzymatic Repertoire: Oxidative Mono-Cleavage Of Dialkenes Catalyzed By Trametes Hirsuta
    标题:Expanding The Regioselective Enzymatic Repertoire: Oxidative Mono-Cleavage Of Dialkenes Catalyzed By Trametes Hirsuta
    摘要:首次报告了利用来自毛头菌的无细胞酶制备,成功实现了双烯的生物催化区域选择性氧化单裂解,且以分子氧为反应物.所选反应在制备规模上进行,获得了高至优异的转化率和化学选择性.
    DOI:10.1039/c2Cc17572J

    海关参考信息

    专利信息


    专利号:US-5861532-A
    优先权日:1997-03-04
    标 题:Solid-phase synthesis of N-alkyl amides
    发明人:BROWN EDWARD G; NUSS JOHN M
    权利人:CHIRON CORP
    摘要:Methods for solid phase synthesis of N-alkyl amides comprise reductive amination of carbonyl compounds using a reducing agent and an amine-containing linker bound to a solid support. The methods afford high yields of linker-bound, monoalkylated amines, and subsequent coupling with acid derivatives provide derivatized N-substituted amides in excellent yields after cleavage from the solid-phase. Compositions useful in solid phase synthesis are also described.

    专利号:US-6528642-B1
    优先权日:1997-08-29
    标题:Mono-and di-derivatives of cyclodextrins, synthesis thereof and purification and use thereof in support
    发明人:DUVAL RAPHAEL; LEVEQUE HUBERT
    权利人:INST FRANCAIS DU PETROLE; CHIRALSEP SARL
    摘要:Mono- and di-derivatives of cyclodextrins are completely defined, also a method for their synthesis and purification, functionalised cyclodextrins obtained from these derivatives, and the synthesis of supports comprising these cyclodextrin derivatives. Use of the supports for the preparation or separation of enantiomers, for asymmetric synthesis, for catalysis, for the preparation or separation of geometrical isomers or positional isomers, or for the preparation or separation of organic molecules with a hydrophobic nature is also described.

    专利号:WO-2014073003-A1
    优先权日:2012-11-09
    标题:Single-step process for the preparation of aryl olefins
    发明人:BORATE HANUMANT BAPURAO; GAIKWAD SUPRIYA HANUMANT; KUDALE ANANDA SHAHAJI; CHAVAN SUBHASH PRATAPRAO; PHARANDE SHRIKANT GANPAT; WAGH VITTHAL DATTATRAYA; SAWANT VIKRAM SHAHAJI
    权利人:COUNCIL SCIENT IND RES
    摘要:The present invention relates to the single-step process for the synthesis of aryl olefin compounds of Formula (1) by reacting aryl aldehydes with alkyl aldehydes in presence of malononitrile and acid or base or salt, optionally in presence of solvent.

    专利号:US-6042723-A
    优先权日:1997-08-29
    标 题:Mono- and di-derivatives of cyclodextrins, synthesis thereof and purification and use thereof in a support

    专利号:US-9423395-B2
    优先权日:2013-01-14
    标 题:Fluorescent cell cycle probe having M-phase specificity
    发明人:CHANG YOUNG-TAE; ZHAI DUANTING; LEE SUNG-CHAN; YUN SEONG-WOOK; JEONG YUN-MI; KANG NAM-YOUNG; PARK SUNG-JIN
    权利人:NAT UNIV SINGAPORE; AGENCY SCIENCE TECH & RES
    摘要:The present invention is directed to a novel family of fluorophores based on the BODIPY scaffold, and methods for their synthesis. The BODIPY-based fluorophores disclosed herein are used for the selective visualization of cells that exist in the M-phase of the cell cycle. The present invention further relates to methods for the image-based monitoring of mitotic progression in live cells.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Chessum, N.; Couty, S.; Jones, K., Science of Synthesis, (2009) 48, 318.
    摘要:Chessum, N.; Couty, S.; Jones, K., Science of Synthesis, (2009) 48, 321.
    摘要:Leung, M.-k.; Chou, C.-M.; Luh, T.-Y., Science of Synthesis Knowledge Updates, (2018) 2, 410.
    摘要:Leung, M.-k.; Chou, C.-M.; Luh, T.-Y., Science of Synthesis Knowledge Updates, (2018) 2, 414.
    摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
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