- ⚠️危险化学品目录 类别: 毒害品和感染性物品
- 英文名称Dioxabenzofos
- 中文名称蔬果磷
- IUPAC名称2-methoxy-4H-benzo[d][1,3,2]dioxaphosphinine 2-sulfide
- 其它别名Phosphorothioicacid, O-methyl ester, cyclic O,O-ester with o-hydroxybenzyl alcohol (7CI); Phosphorothioic acid, cyclic O,O-(methylene-o-phenylene) O-methyl ester (8CI); Benzyl alcohol, o-hydroxy-, cyclic O,O-ester with O-methyl phosphorothioate(8CI); 2-Methoxy-4H-1,3,2-benzodioxaphorphorin-2-sulfide; 2-Methoxy-4H-1,3,2-benzodioxaphospholin-2-sulfide; 2-Methoxy-4H-1,3,2-benzodioxaphosphorin-2-sulfide; Dioxabenzofos; Dioxabenzophos; Fenfosphorin; Saligenin cyclic methylphosphorothionate; Salithion
- CAS编号3811-49-2
- MFCD编号:MFCD00210363
- EINECS号:223-292-3
- FDA UNII编号:6ZWK96BZW6
- 分子式:C8H9O3PS分子量:216.19
- 产品CID: 1392344
- 产品分类化学农药原药 → 杀虫剂 → 有机磷杀虫剂

物理性质
- 熔点55-56°C (methanol )
- 沸点approximate 274°C
- 闪点119.8 °C
- 密度1.37±0.1 g/cm3(预测)
- PSA:69.59
- LogP:3.1171
- 折射率1.59
- 蒸汽压0.00907 mmHg at 25 °C
- 溶解性58Mg/l(30 °c)
- 外观形态固体-粉末
- 储存条件0-6°C
- 产品应用水杨硫磷(3811-49-2)的用途:水杨硫磷是一种广谱,高效,低残留有机磷杀虫剂,它有杀卵伤用,有触杀和胃毒作用,并且能快速杀死虫害.用于防治水稻螟虫,稻瘿蚊,稻飞虱等害虫.水杨硫磷还可用于棉花抗性棉铃虫,果树卷叶虫,红铃虫,柑橘介壳虫,蔬菜菜青虫及地下害虫药效显著. 蔬果磷还主要对棉花后期棉铃虫,柑桔介壳虫及蔬菜的多类害虫药效显著.用于防治柑橘凤蝶,卷叶蛾,袋蛾,菜青虫,桃食心虫,蚜虫,甘蓝夜蛾.以25g/hL剂量能有效地防治水果,水稻,蔬菜和经济作物上的许多害虫,对抗对硫磷的棉铃虫有特效.
- 性质描述水杨硫磷(3811-49-2)的理化性质:纯品为无色至淡蓝色结晶固体,熔点55.5~56°C,25°C时的蒸气压为0.627Pa.工业品为淡黄色结晶,熔点52~55°C,300下溶于水58mg/L;可溶于丙酮,苯,乙醇和乙醚,适量溶于甲苯,二甲苯,甲基戊酮和环丙酮.对弱酸或碱稳定.毒性:急性口服LD50雌大白鼠为180mg/kg,雄大白鼠为125 mg/kg,雄小白鼠为94mg/kg,雌小白鼠为128mg/kg.急性经皮LD50雄大白鼠为400mg/kg,雌大白鼠为590mg/kg,小白鼠>1250mg/kg.小白鼠皮下注射LD50为81.6mg/kg.鲤鱼TLm(48小时)20mg/L.LC50(48小时)鲤鱼为3.55mg/L,金鱼为2.8mg/L.水蚤LC50(3・小时)为0.75mg/L.
欧盟法规
统一分类与标签压力设备指令-第1组危险流体ECHA物质工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单上下游产品
salicylic alcohol O-methyl-O-(4-nitrophenyl) phosphor°Chloridothioate salicylaldehyde 2-chloro-4H-1,3,2-benzodioxaphosphorin 2-sulfidesalioxon 📜水杨醇 反应生成 蔬果磷
参考文献:Okamoto,Itiro;Morisima,Yasuo
标题:Okamoto,Itiro;Morisima,Yasuo
海关参考信息
- 2902300000-甲苯
2905110000-甲醇
2906210000-苄醇
2907121100-间甲酚 - 💡 提示:海关信息按照顺序优先匹配,如需确认的海关信息,请参考相关资料。
- 详情请参考:📖 海关编码查询和海关进出口税则
专利信息
专利号:WO-2025056767-A1
优先权日:2023-09-15
标题 :Process for the preparation of enantiomerically enriched aliphatic amines
发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
权利人:SYNGENTA CROP PROTECTION AG
摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.
专利号:US-2007232495-A1
优先权日:2006-03-24
标题:Compositions and methods to add value to plant products, increasing the commercial quality, resistance to external factors and polyphenol content thereof
发明人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
权利人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
摘要:The invention is related to compositions and methods that naturally protect plant tissues against ultraviolet radiation and temperature, thus giving protection against sunburn to plants, plant parts, fruits and/or flowers during their development. The invention is also related to compositions and methods to naturally improve the color of plants, plant parts, fruits and/or flowers by inducing the natural synthesis of flavonoids and anthocyanins present in plants. Likewise, the present invention is directed to improving the nutritional value of plants, plant parts, fruits and/or flowers by increasing the normal levels of polyphenolic compounds, especially flavonoids, present therein. Additionally, the present invention is related to compositions and methods that give more resistance to plants, plant parts, fruits and/or flowers against pathogens as bacteria and fungi. Finally, the present invention is related to plants, plant parts, fruits, flowers and/or propagating material treated with the compositions described in the present document.
专利号:WO-2021074309-A1
优先权日:2019-10-16
标 题:1-(3-quinolyl)-3,4-dihydroisoquinoline derivatives as fungicides for combating specific phytopathogens
发明人:WEISS MATTHIAS; QUARANTA LAURA; BOU HAMDAN FARHAN; MAHAJAN ATUL; WILLIAMS SIMON; KILARU JAGADEESH; SEN INDIRA; BIERI STEPHANE; DIGGELMANN MARTIN
权利人:SYNGENTA CROP PROTECTION AG
摘要:1-(3-quinolyl)-3,4-dihydroisoquinoline derivatives of formula (I) as well as a method of combating, preventing or controlling the phytopathogens Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale), which comprises applying to the phytopathogen, to the locus of the phytopathogen, or to a plant susceptible to attack by the phytopathogen, or to propagation material thereof, a fungicidally effective amount of a 1-(3-quinolyl)-3,4-dihydroisoquinoline derivative of formula (I). The present description discloses the synthesis of exemplary compounds, formulation examples, relevant biological data (antifungal activity against Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale) when spayed on plants), as well as comparative data against three prior art compounds (e.g. pages 52 to 85; formulation examples; examples A1 to A3; table E; compounds E.01 to E.187; biological examples). Exemplary compounds are e.g.: 5-bromo-1-(8-fluoro-3-quinolyl)spiro[4H-isoquinoline-3,1'- cyclopropane] (example A1) 5-bromo-1-(8-fluoro-3-quinolyl)-3,3-dimethyl-4H-isoquinoline (example A2) 1-(8-fluoro-3-quinolyl)-3,3-dimethyl-4H-isoquinoline-5-carbonitrile (example A3)
专利号:WO-2021074311-A1
优先权日:2019-10-16
标题:1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives as fungicides for combating specific phytopathogens
发明人:WEISS MATTHIAS; QUARANTA LAURA; BOU HAMDAN FARHAN; MAHAJAN ATUL; WILLIAMS SIMON; KILARU JAGADEESH; BIERI STEPHANE; DIGGELMANN MARTIN
权利人:SYNGENTA CROP PROTECTION AG
摘要:1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives of formula (I) as well as a method of combating, preventing or controlling the phytopathogens Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale), which comprises applying to the phytopathogen, to the locus of the phytopathogen, or to a plant susceptible to attack by the phytopathogen, or to propagation material thereof, a fungicidally effective amount of a 1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives of formula (I). The present description discloses the synthesis of exemplary compounds, formulation examples, relevant biological data (antifungal activity against Mycosphaerella graminicola, Monographella nivalis, Fusarium culmorum and/or Gibberella zeae when spayed on plants) (e.g. pages 47 to 55; examples A1 and A2; compounds E.01 to E.17; table E). An exemplary compounds is e.g.: 3-(5-bromo-3,3-dimethyl-2,4-dihydro-1 H-isoquinolin-1-yl)-8-fluoro- quinoline (example A1)
专利号:US-8937089-B2
优先权日:2004-07-01
标 题:Synergistic mixtures of anthranilamide invertebrate pest control agents
发明人:ANNAN ISAAC BILLY; FLEXNER JOHN LINDSEY; PORTILLO HECTOR EDUARDO; LAHM GEORGE PHILIP; SELBY THOMAS PAUL; STEVENSON THOMAS MARTIN
权利人:ANNAN ISAAC BILLY; FLEXNER JOHN LINDSEY; PORTILLO HECTOR EDUARDO; LAHM GEORGE PHILIP; SELBY THOMAS PAUL; STEVENSON THOMAS MARTIN; DU PONT
摘要:Disclosed are mixtures and compositions for controlling invertebrate pests relating to combinations comprising (a) 3-bromo-N-[4-chloro-2-methyl-6-[(methylamino)carbonyl]phenyl]-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxamide, and its N-oxides, and suitable salts thereof n n n n n n n n n n n n andn na component (b) wherein the component (b) is at least one compound or agent selected from neonicotinoids, cholinesterase inhibitors, sodium channel modulators, chitin synthesis inhibitors, ecdysone agonists, lipid biosynthesis inhibitors, macrocyclic lactones, GABA-regulated chloride channel blockers, juvenile hormone mimics, ryanodine receptor ligands, octopamine receptor ligands, mitochondrial electron transport inhibitors, nereistoxin analogs, pyridalyl, flonicamid, pymetrozine, dieldrin, metaflumizone, biological agents, and suitable salts of the foregoing.n n n n n n Also disclosed are methods for controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a mixture or composition of the invention.
专利号:EP-1771070-B1
优先权日:2004-07-26
标题:Mixtures of anthranilamide invertebrate pest control agents
发明人:ANNAN ISAAC BILLY; HUGHES KENNETH ANDREW; LAHM GEORGE PHILIP; SELBY THOMAS PAUL; STEVENSON THOMAS MARTIN
权利人:DU PONT
摘要:Disclosed are mixtures and compositions for controlling invertebrate pests relating to combinations comprising (a) 3-bromo-N-[4-cyano-2-methyl-6Â[(methylamino)carbonyl]phenyl]-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxamide, an N-oxide, or a salt thereof, Formula (1) and (b) at least one invertebrate pest control agent selected from neonicotinoids, cholinesterase inhibitors, sodium channel modulators, chitin synthesis inhibitors, ecdysone agonists, lipid biosynthesis inhibitors, macrocyclic lactones, GABA-regulated chloride channel blockers, juvenile hormone mimics, ryanodine receptor ligands, octopamine receptor ligands, mitochondrial electron transport inhibitors, nereistoxin analogs, pyridalyl, flonicamid, pymetrozine, dieldrin, metaflumizone, biological agents, and salts of the foregoing. Also disclosed are methods for controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a mixture or composition of the invention.