📜二苯二氯硅烷置于ch3Mgbr体系中,用 Not Given 作为反应溶剂,以89%的收率获得产物二甲基二苯基硅烷 参考文献:Electric Moments And Structures Of Organosilicon Compounds. Ii. The Aromatic Carbon-Silicon Bond1,2 标题:Electric Moments And Structures Of Organosilicon Compounds. Ii. The Aromatic Carbon-Silicon Bond1,2 摘要: DOI:10.1021/ja01108A009
专利号:US-8987493-B2 优先权日:2010-05-20 标题 :Process for synthesis of silane dipeptide analogs 发明人:SIEBURTH SCOTT MCNEILL; BO YINGJIAN 权利人:SIEBURTH SCOTT MCNEILL; BO YINGJIAN; Temple University—Of the Commonwealth System of Higher Education 摘要:The invention provides a method of preparing silane dipeptide analogs, comprising the steps of treating a solution of a substituted 1,2-oxasilolane with lithium metal to form a solution of the dilithium salt of a substituted 3-hydroxypropylsilanol, and reacting the solution of the dilithium salt of the substituted 3-hydroxypropylsilanol with a substituted enamine.
专利号:US-9388345-B2 优先权日:2012-07-03 标题:Hydrocarbon synthesis methods, apparatus, and systems 发明人:MCNEFF CLAYTON V; MCNEFF LARRY C; NOWLAN DANIEL THOMAS; YAN BINGWEN; GREUEL PETER G 权利人:SARTEC CORP 摘要:Embodiments of the invention include apparatus and systems for hydrocarbon synthesis and methods regarding the same. In an embodiment, the invention includes a process for creating a hydrocarbon product stream comprising reacting a reaction mixture in the presence of a catalyst inside of a reaction vessel to form a product mixture, the reaction mixture comprising a carbon source and water. The temperature inside the reaction vessel can be between 450 degrees Celsius and 600 degrees Celsius and the pressure inside the reaction vessel can be above supercritical pressure for water. In an embodiment, the invention includes an extrusion reactor system for creating a hydrocarbon product stream. The temperature inside the extrusion reactor housing between 450 degrees Celsius and 600 degrees Celsius. Pressure inside the reaction vessel can be above supercritical pressure for water. Other embodiments are also included herein.
专利号:WO-2023277824-A2 优先权日:2021-07-01 标 题 :Diverse functionalization of hydrosilanes and programmable synthesis of multisubstituted organosilanes enabled by neutral eosin y photocatalysis
专利号:US-2013096335-A1 优先权日:2010-05-20 标题 :Process for synthesis of silane dipeptide analogs
专利号:US-3441538-A 优先权日:1965-08-04 标题 :Boron trifluoride - hydrogen fluoride catalyzed synthesis of poly(aromatic ketone) and poly(aromatic sulfone) polymers 发明人:MARKS BARNARD M 权利人:DU PONT
专利号:US-3442857-A 优先权日:1965-11-10 标题 :Boron trifluoride-hydrogen fluoride catalyzed synthesis of poly(aromatic sulfone) and poly(aromatic ketone) polymers 发明人:THORNTON ROGER L 权利人:DU PONT
参考文献:10.1055/s-0035-1560646 摘要:Xu Z, Xu L, Huang W, Zhang J. Recent Advances in Transition-Metal-Catalyzed Silylations of Arenes with Hydrosilanes: C–X Bond Cleavage or C–H Bond Activation Synchronized with Si–H Bond Activation. Synthesis. 2015 Oct 08;47(23):3645–68. doi: 10.1055/s-0035-1560646. 参考文献:10.1007/s10800-024-02180-2 摘要:Silina YE, Altmeyer MO, Lee J, Kim YJ, Zolotukhina EV, Koch M. Novel approach for rapid electrochemical profiling of Escherichia coli cell-free supernatant. J Appl Electrochem. 2024 Aug 10;55(2):499–508. doi: 10.1007/s10800-024-02180-2. 参考文献:10.2116/analsci.17.545 摘要:Nakao H, Hayashi H, Okita K. Spectroelectrochemical characterization of Si-bridged diphenylamines: influence of Si-bridging upon electronic structures of diphenylamines. Anal Sci. 2001 Apr;17(4):545–9. doi: 10.2116/analsci.17.545.