CAS: 69851-61-2; N,N'-1,3-Propanediylbis[3,5-Bis(1,1-Dimethylethyl)-4-Hydroxybenzenepropanamide]

相似化合物

23128-74-7 70331-94-1 20170-32-5

上下游产品

Trimethylenediamine methyl 3-(4-hydroxy-3,5-di-tert-butyl)phenylpropanoate

📜1,3-丙二胺,3-(3,5-二叔丁基-4-羟基苯基)丙酸甲酯置于n-甲基吡咯烷酮体系中,化学反应生成 抗氧剂 Irganox-1019
参考文献:Process For Preparing Organic Esters And Amides And Catalyst System
标题:Process For Preparing Organic Esters And Amides And Catalyst System
摘要:揭示了一种通过将(a)(取代-4-羟基苯基)烷酸酯的5至60摩尔%过量与(b)(i)具有一个或多个羟基的c.Sub.4-C.Sub.20脂肪醇或硫醚醇或(II)公式为(r"').Sub.2N(Ch.Sub.2).Sub.Nr""的胺反应而制备有机酯和酰胺的方法,其中r"'为氢,C.Sub.1-7烷基,C.Sub.5-12环烷基或c.Sub.6-12芳基,前提是一个r"'为氢,而r""为氢或n(R"').Sub.2,其中r"'如上所定义,在存在基本无机化合物和极性无水有机化合物的催化剂系统的情况下.该方法提供了所需产品更高的产量,更短的反应时间,并减少了不良副产物的反应生成.

专利信息

专利号:US-2009318592-A1
优先权日:2005-10-11
标 题 :Process for the Synthesis of Amine Ethers
发明人：FREY MARKUS; BROENNIMANN VALERIE
权利人:CIBA GEIGY CORP
摘要:The present invention relates to novel processes for the preparation of a sterically hindered amine ether by reacting a corresponding sterically hindered amine oxide with a ketone or an aldehyde with at least one reactive H in the presence of a peroxydisulphate. Products obtained by this process may be hydrogenated. The compounds made by these processes are particularly effective in the stabilization of polymer compositions against harmful effects of light, oxygen and/or heat and as flame-retardants for polymers.

专利号:US-2007191516-A1
优先权日:2004-03-15
标题 :Process for the synthesis of amine ethers
发明人：FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS
权利人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS
摘要:A process for the preparation of a sterically hindered amine ether which comprises reacting a corresponding sterically hindered aminoxide with a C 5 -C 18 alk-1-ene in the presence of an organic hydroperoxide and optionally hydrogenating the resulting product as well as the product mixtures obtained therewith and their use as stabilizers and flame retardants.

专利号:US-7402675-B2
优先权日:2000-05-26
标题 :Process for the synthesis of amine ethers from secondary amino oxides
发明人：HAFNER ANDREAS; KIRNER HANS JUERG; SCHWARZENBACH FRANZ; VAN DER SCHAAF PAUL ADRIAAN; NESVADBA PETER
权利人:CIBA SC HOLDING AG
摘要:An amine ether of formula A n nwherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L;n E′ is C 1 -C 36 alkyl; C 3 -C 18 alkenyl; C 2 -C 18 alkinyl; C 5 -C 18 cycloalkyl; C 5 -C 18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C 2 -C 7 alkyl or C 3 -C 7 alkenyl substituted by halogen; C 7 -C 15 aralkyl or C 7 -C 15 aralkyl substituted by C 1 -C 4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C 4 -C 18 alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR 21 or C(O)—R 22 ; or T′ is C 5 -C 12 cycloalkyl; C 5 -C 12 cycloalkyl which is interrupted by at least one O or —NR 18 —; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR 18 —; or T′ is —C(G 1 )(G 2 )-T″; or C 1 -C 18 alkyl or C 5 -C 12 cycloalkyl substituted by n n n n n n n n n n n n T″ is hydrogen, halogen, NO 2 , cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; n or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G 1 and G 2 , an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, n are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E 1 -H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. n n n n n The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.

专利号:US-5629394-A
优先权日:1992-12-17
标 题 :Direct synthesis by living cationic polymerization of nitrogen-containing polymers
发明人：CHERADAME HERVE M; CHEN FRANK J; STANAT JON E R; NGUYEN HUNG A; TABAR BEHROOZ R
权利人:EXXON CHEMICAL PATENTS INC
摘要:A method is provided for the direct synthesis by living cationic polymerization of novel polymeric materials functionalized with desirable nitrogen-containing functional groups such as terminal azido, cyano, carbonylamino, cyanato, thiocyanato or thiocarbonylamino groups. Polymerization and functionalization occur in a substantially simultaneous manner. All necessary reactants for the functionalization are present when polymerization is initiated. The nitrogen-containing functional group is provided as a part of a molecule having a release moiety which is preferably resonance stabilized or a tertiary alkyl type and which acts to aid the nitrogen-containing species in functioning as a leaving group.

专利号:US-6417363-B1
优先权日:1997-12-04
标题 :Heterocyclyl ligand containing ruthenium and osmium catalysts
发明人：VAN DER SCHAAF PAUL ADRIAAN; MUEHLEBACH ANDREAS; HAFNER ANDREAS; KOLLY ROMAN
权利人:CIBA SC HOLDING AG
摘要:Penta- and hexa-coordinated, bridged ruthenium and osmium catalysts of the formulawherein Me is ruthenium or osmium; L1 and L2 are neutral ligands having electron donor properties;X is an anionic ligand; Y is oxygen or sulphur; A is a direct bond, C1-C4alkylene or C2-C4alkylidene;Z is a direct bond, oxygen, sulphur or the groupswherein R1 and R2 are hydrogen or hydrocarbon radicals; their preparation and their us in the synthesis of polymers, in the ring-closure metathesis of diolefins, in the cross metathesis of olefins and in the isomerisation of olefins are disclosed.

专利号:US-6077805-A
优先权日:1997-03-06
标题:Hexacoordinated ruthenium or osmium carbene catalysts
发明人：VAN DER SCHAAF PAUL ADRIAAN; HAFNER ANDREAS; MUEHLEBACH ANDREAS
权利人:CIBA SC HOLDING AG
摘要:Hexacoordinated ruthenium and osmium catalysts of the formulae in which M and M' independently of one another are ruthenium or osmium; X, X', Y and Y' independently of one another are anionic ligands, or X and Y and X' and Y' in each case together are bis-anionic ligands L1 and L1' independently of one another are tertiary phosphine; L2 and L3 independently of one another are a monodentate ligand, or L2 and L3 together are bidentate, neutral electron donor ligands; L4 is tetradentate, neutral electron donor ligand; L5 is a bidentate, neutral electron donor ligand; and T and T' indepedently of one another are H or organic substituents, are useful for the synthesis of custom-tailored polymers and for the ring-closing metathesis of olefins.