CAS: 12672-51-4; Cobalt Hydroxide

该化合物是工业和研究应用中常用的一种无机化合物,因其多用途化学特性而常见于工业和研究应用中;它看起来像粉红色至玫瑰红固体,在水中无法溶解;钴氢的主要优点在于它作为生产钴氧化物和其他钴化合物的前体的作用,这些化合物在电池电极,催化剂和颜料中至关重要;其稳定结构和高回活性使其适合电化学应用,包括镍镉和锂离子电池等能源储存系统;此外,它作为涂层和陶瓷中的一种有效添加剂,以提高材料性能;由于它的潜在毒性,建议进行适当的处理.

结构式图片

合成工艺路线路线简述

    专利信息


    专利号:US-2015037240-A1
    优先权日:2012-03-12
    标 题 :Methods of preparing catalysts for the chirally selective synthesis of single-walled carbon nanotubes
    发明人:CHEN YUAN
    权利人:UNIV NANYANG TECH
    摘要:Methods of preparing a sulfur-containing catalyst for the chirally selective synthesis of single-walled carbon nanotubes are presented. Sulfur-containing catalysts for the chirally selective synthesis of single-walled carbon nanotubes, the catalysts comprising sulfur-doped transition metal as active phase on a support, and methods of forming single-walled carbon nanotubes having a selected chirality using the catalysts are also presented.

    专利号:US-5955051-A
    优先权日:1996-08-02
    标 题 :Synthesis of lithium nickel cobalt dioxide
    发明人:LI WU; CURRIE JOHN CARLETON; WOLSTENHOLME JACK
    权利人:WESTAIM TECHNOLOGIES INC
    摘要:A single calcination stage process for the synthesis of homogeneous crystalline lithium nickel cobalt dioxide from either a mechanical mixture of nickel and cobalt oxides, hydroxide or oxyhydroxide or a chemical precipitation of a homogeneous nickel cobalt hydroxide or cobalt nickel cobalt oxyhydroxide is provided. The reactants are calcined in the presence of lithium hydroxide and an alkali metal hydroxide under predetermined oxygen partial pressure and temperature conditions. The products of the process are characterized in having a lithium to transition metal ratio closely approximating to the desired theoretical value.

    专利号:WO-2005085390-A1
    优先权日:2004-03-09
    标 题:Cobalt catalyst for the synthesis of fischer-tropsch, catalyst support, processes for the preparation of support and catalyst and the use of the catalyst
    发明人:DOS SANTOS ANA CARLOTA BELIZAR; PEREIRA ANTONIO TELHADO; SOUSA-AGUIAR EDUARDO FALABELLA; MORAES JORGE LUIZ; DE OLIVEIRA KENSLEY ALVES; SUGAYA MARCOS DE FREITAS; SCHMAL MARTIN; MONTEIRO ROBSON DE SOUZA; VICENTINI VALERIA PERFEITO
    权利人:CBMM SA; OXITENO SA IND E COMERCIO; PETROLEO BRASILEIRO SA; DOS SANTOS ANA CARLOTA BELIZAR; PEREIRA ANTONIO TELHADO; SOUSA-AGUIAR EDUARDO FALABELLA; MORAES JORGE LUIZ; DE OLIVEIRA KENSLEY ALVES; SUGAYA MARCOS DE FREITAS; SCHMAL MARTIN; MONTEIRO ROBSON DE SOUZA; VICENTINI VALERIA PERFEITO
    摘要:The present invention is related to a cobalt catalyst supported on high-surface area niobium pentoxide for Fischer-Tropsch synthesis, the support of this catalyst which is a niobium pentoxide (Nb2O5) with a BET surface area in the range of 30 to 160 m2.g-1, the process for the preparation of the high-surface area support of niobium pentoxide by calcination of a hydrated niobium oxide or by synthesis from either organic or inorganic niobium precursors, a process for the preparation of said catalyst, and the use of the catalyst for the Fischer-Tropsch synthesis to obtain hydrocarbons with carbon atoms equal or higher than five containing specially linear paraffins in the diesel fuel range, and without a significant formation of light hydrocarbons, olefins, aromatics and oxygenated compounds.

    专利号:US-7538061-B2
    优先权日:2001-05-18
    标题 :One-step production of 1,3-propanediol from ethylene oxide and syngas with a cobalt-iron catalyst
    发明人:KNIFTON JOHN FREDERICK; JAMES TALMADGE GAIL; SLAUGH LYNN HENRY; WEIDER PAUL RICHARD; ALLEN KEVIN DALE; POWELL JOSEPH BROUN
    权利人:SHELL OIL CO
    摘要:Disclosed is a new catalyst composition comprising a bimetallic Co—Fe catalyst, optionally complexed with a ligand selected from a N-heterocycle, phosphine, or porphorine ligand, that provides a lower cost alternative for the one step synthesis of 1,3-propanediol (1,3-PDO) from ethylene oxide and synthesis gas. For example, a catalyst containing cobalt carbonyl: iron carbonyl with no ligand, or a catalyst containing a cobalt carbonyl: octaethylporphine iron acetate provide moderate yields of 1,3-PDO in a one step synthesis under mild conditions.

    专利号:US-6903044-B2
    优先权日:2001-05-18
    标题:One-step production of 1,3-propanediol from ethylene oxide and syngas with a catalyst with a N-heterocyclic ligand
    发明人:KNIFTON JOHN FREDERICK; JAMES TALMADGE GAIL; ALLEN KEVIN DALE; WEIDER PAUL RICHARD; POWELL JOSEPH BROUN; SLAUGH LYNN HENRY; WILLIAMS TIMOTHY
    权利人:SHELL OIL CO
    摘要:Disclosed is a new catalyst composition comprising a bimetallic Co—Ru catalyst complexed with a N-heterocylcic ligand that is effective, economical, and provides improvements in oxidative stability in the one step synthesis of 1,3-propanediol (1,3-PDO) from ethylene oxide and synthesis gas. For example, cobalt-ruthenium-2,2′-bipyrimidine, 2,2′-dipyridyl, or 2,4,6-tripridyl-s-triazine catalyst precursors in cyclic ether solvents, such as 1,3-dioxolane, 1,4-dioxolane, 1,4-dioxane, and 2-ethyl-2-methyl-1,3-dioxolane, provide good yields of 1,3-PDO in a one step synthesis.

    专利号:US-8568686-B2
    优先权日:2004-10-18
    标 题 :Synthesis of thin films and materials utilizing a gaseous catalyst
    发明人:MORSE DANIEL E; SCHWENZER BIRGIT; GOMM JOHN R; ROTH KRISTIAN M; HEIKEN BRANDON; BRUTCHEY RICHARD
    权利人:MORSE DANIEL E; SCHWENZER BIRGIT; GOMM JOHN R; ROTH KRISTIAN M; HEIKEN BRANDON; BRUTCHEY RICHARD; UNIV CALIFORNIA
    摘要:A method for the fabrication of nanostructured semiconducting, photoconductive, photovoltaic, optoelectronic and electrical battery thin films and materials at low temperature, with no molecular template and no organic contaminants. High-quality metal oxide semiconductor, photovoltaic and optoelectronic materials can be fabricated with nanometer-scale dimensions and high dopant densities through the use of low-temperature biologically inspired synthesis routes, without the use of any biological or biochemical templates.
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    合成参考文献


    摘要:Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013.
    摘要:ACGIH - Documentation of the TLVs and BEIs, 7th Ed. Cincinnati: ACGIH Worldwide, 2020.
    摘要:L29: ATSDR - Agency for Toxic Substances and Disease Registry (2004). Toxicological profile for cobalt. U.S. Public Health Service in collaboration with U.S. Environmental Protection Agency (EPA).
    摘要:L30: Wikipedia. Cobalt. Last Updated 21 March 2009.
    摘要:L134: ATSDR - Agency for Toxic Substances and Disease Registry (2001). Minimal Risk Levels (MRLs) for Hazardous Substances. U.S. Public Health Service in collaboration with U.S. Environmental Protection Agency (EPA). http://www.atsdr.cdc.gov/mrls/
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