CAS: 90-44-8; Anthracen-9(10H)-One

• 英文名称Anthracen-9(10H)-One
• 中文名称蒽酮
• IUPAC名称anthracen-9(10H)-one
• 其它别名蔥酮; Anthracen-9(10H)-One
• CAS编号90-44-8
• MFCD编号:MFCD00001187
• EINECS号:201-994-0
• FDA UNII编号:FP0FJ7K744
• 分子式:C14H10O
• 分子量:194.23
• 产品CID: 1937412
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• 产品信息参考;;;;
• InChIKey: RJGDLRCDCYRQOQ-UHFFFAOYSA-N
• InChI=1S/C14H10O/c15-14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-8H,9H2…
• 计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数0.0

物理性质

• 熔点154-157 °C
• 沸点721 °C at 760 mmHg
• 闪点150.3°C
• 密度450kg/m3
• PSA:17.07
• LogP:2.8218
• 折射率1.5500 (估算)
• 蒸汽压0.0000183 [mmHg]
• 溶解性Insoluble
• 敏感性光敏感
• 外观形态黄色粉末
• 储存条件2-8°C
• 产品应用该品用于有机合成,用糖和动物体液中淀粉的比色测定.
• 性质描述该品为无色针状结晶体.熔点为155°C,溶于大多数有机溶剂和热氢氧化钠溶液,不溶于水.无荧光,所出现的荧光是由蒽酚所致.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  水生慢性毒性 类别3
  严重眼刺激 类别2A
• 警示词Warning(警告)
• 危险描述H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H336 |可能引起嗜睡或头晕.
  H412 |对水生生物有害并具有长期持续影响.
• 防范说明P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501
• UN编号NONH for all modes of transport
• 危险品标志Xi,Xn
• 安全声明26-36
• 危险类别码36/37/38-20/21/22
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 Anthrone 主要起始原料 2-Benzylbenzoic Acid
• 612-35-1 = 90-44-8
  反应条件:1.1 Reagents: Diphosphoryl Chloride1.2 Reagents: Water
  标题:Intramolecular Acylation Of Aryl- And Aroyl-Aliphatic Acids By The Action Of Pyrophosphoryl Chloride And Phosphorus Oxychloride
  作者:El-Sayrafi,Sami; Rayyan,Saleh
  参考文献:Molecules [online Computer File] 日期:2001 卷标:6(3) 页码:279-286]
  
  67673-27-2 = 90-44-8
  反应条件:1.1 Reagents: Water Solvents: Water
  标题:Another Pathway Of The Reaction Of Thionyl Chloride With Active Methylene Compounds. Reaction Of Anthrone With Thionyl Chloride
  作者:Oka,Kitaro; Hara,Shoji
  参考文献:Journal Of Organic Chemistry 日期:1978 卷标:43(23) 页码:4533-5]
  
  84-65-1 = 90-44-8
  反应条件:1.1 Reagents: Tin Solvents: Acetic Acid; Rt -> Reflux1.2 Reagents: Hydrochloric Acid; 2 H,Reflux; 2 H,Reflux
  标题:Selective Recognition And Sensing Of Biologically Important Phosphates Using Triptycene-Based Anion Receptors
  作者:Kassir,Ahmad F.; Lupp,Daniel; Grabowski,Jakub; Granda,Jaroslaw M.; Jurczak,Janusz
  参考文献:Chemrxiv 日期:2022 卷标:1 页码:1-97]
  
  84-65-1 = 90-44-8
  反应条件:1.1 Reagents: Sodium Hydroxide,Dithionite Solvents: Water
  标题:Preparation Of Anthrone
  参考文献:Japan]
  
  613-31-0 = 90-44-8
  反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide Catalysts: 1,3,5-Benzenetricarboxylic Acid,Iron(3+) Salt (1:1) Solvents: Acetonitrile; 27 H,70 °C; 70 °C -> Rt
  标题:Metal Organic Frameworks As Efficient Heterogeneous Catalysts For The Oxidation Of Benzylic Compounds With T-Butyl Hydroperoxide
  作者:Dhakshinamoorthy,Amarajothi; Alvaro,Mercedes; Garcia,Hermenegildo
  参考文献:Journal Of Catalysis 日期:2009 卷标:267(1) 页码:1-4]
  
  92560-84-4 = 90-44-8
  反应条件:1.1 Reagents: Hydrogen Peroxide,Pyridinium Fluorochromate Solvents: Acetone,Water
  标题:Oxidative Deprotection Of Oximes Using Pyridinium Fluorochromate And Hydrogen Peroxide
  作者:Ganguly,Nemai C.; Sukai,Arun K.; De,Sripada; De,Prithwiraj
  参考文献:Synthetic Communications 日期:2001 卷标:31(10) 页码:1607-1612]
  
  612-35-1 = 90-44-8
  反应条件:1.1 Catalysts: Nafion H Solvents: 1,3-Dichlorobenzene
  标题:Catalysis By Solid Superacids. Part 33. Nafion-H Catalyzed Intramolecular Friedel-Crafts Acylation. Formation Of Cyclic Ketones And Related Heterocycles
  作者:Olah,George A.; Mathew,Thomas; Farnia,Morteza; Prakash,G. K. Surya
  参考文献:Synlett 日期:1999 卷标:(7) 页码:1067-1068]
  
  613-31-0 = 90-44-8
  反应条件:1.1 Reagents: Alumina Catalysts: Manganese Oxide (Mno2) (Nano); 150 - 240 S,105 °C
  标题:Efficient Oxidation Of Arylmethylene Compounds Using Nano-Mno2
  作者:Nammalwar,Baskar; Fortenberry,Chelsea; Bunce,Richard A.; Lageshetty,Sathish Kumar; Ausman,Kevin D.
  参考文献:Tetrahedron Letters 日期:2013 卷标:54(15) 页码:2010-2013]
  
  612-35-1 = 90-44-8
  反应条件:1.1 Catalysts: Boron,Trifluoro(2,2,2-Trifluoroethanol-Ko)-,(T-4)-,Compd. With 2,2,2-Trifluor... Solvents: Dichloromethane; Rt
  标题:Bf3.2Cf3Ch2Oh (Bf3.2Tfe),An Efficient Superacidic Catalyst For Some Organic Synthetic Transformations
  作者:Prakash,G. K. Surya; Mathew,Thomas; Marinez,Eric R.; Esteves,Pierre M.; Rasul,Golam; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2006 卷标:71(10) 页码:3952-3958]
  
  = 90-44-8
  反应条件:1.1 Reagents: Potassium Hydride,18-Crown-6 Solvents: 1,4-Dioxane1.2 Reagents: Methanol
  标题:Model Studies Directed Towards The Synthesis Of The Oxetane D-Ring Of Paclitaxel: Assessment Of The Oxyanion-Assisted Retro-Diels-Alder Reaction As A Means For Generating Oxete
  作者:Banwell,Martin G.; Clark,George R.; Hockless,David C. R.; Pallich,Susanne
  参考文献:Australian Journal Of Chemistry 日期:2001 卷标:54(11) 页码:691-704]
  
  611-63-2 = 90-44-8
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: Silica,(Sp-4-1)-Bis[ethyl (2E)-2-(Phenylmethylene)Hydrazinecarbodithioato-Kn2,Ks′1]Nick... Solvents: Acetonitrile,Water; 95 Min,Rt
  标题:Selective Oxidation Of Thiols And Alcohols By Physically Encapsulated Nickel Schiff-Base Complex Prepared Via Sol-Gel Method As Nano-Catalyst
  作者:Eshtiagh-Hosseini,Hossein; Tabari,Taymaz; Takjoo,Reza; Eshghi,Hossein
  参考文献:Synthesis And Reactivity In Inorganic 日期:2013 卷标:43(3) 页码:264-272]
  
  613-31-0 = 90-44-8
  反应条件:1.1 Reagents: Sodium Hypochlorite Catalysts: Cobalt Diacetate,Tempo Solvents: Dichloromethane; 6 H,Ph 8.3,0 - 5 °C
  标题:Direct Benzylic Oxidation With Sodium Hypochlorite Using A New Efficient Catalytic System: Tempo/co(Oac)2
  作者:Jin,Can; Zhang,Li; Su,Weike
  参考文献:Synlett 日期:2011 卷标:(10) 页码:1435-1438]
  
  613-31-0 = 90-44-8
  反应条件:1.1 Reagents: Oxygen Catalysts: Manganese Oxide (Mno2) Solvents: O-Xylene; 9 H,Reflux
  标题:Wool Supported Manganese Dioxide Nano-Scale Dispersion: A Biopolymer Based Catalyst For The Aerobic Oxidation Of Organic Compounds
  作者:Shaabani,Ahmad; Hezarkhani,Zeinab; Badali,Elham
  参考文献:Rsc Advances 日期:2015 卷标:5(76) 页码:61759-61767]
  
  611-63-2 = 90-44-8
  反应条件:1.1 Catalysts: Cesium Carbonate,Palladium Oxide (Pdo) (Intercalated With Mesoporous Silica); 8 H,80 °C
  标题:Palladium Oxide Nanoparticles Intercalated Mesoporous Silica For Solvent Free Acceptorless Dehydrogenation Reactions Of Alcohols
  作者:Samanta,Partha Kumar; Ray,Shounak; Das,Trisha; Gage,Samuel H.; Nandi,Mahasweta; Et Al
  参考文献:Microporous And Mesoporous Materials 日期:2019 卷标:284 页码:186-197]
  
  132556-02-6 = 90-44-8
  反应条件:1.1 Reagents: Permanganic Acid (Hmno4),Potassium Salt (1:1),Water Catalysts: Silica; 15 Min,Rt1.2 Solvents: Cyclohexane
  标题:Wet Silica-Supported Permanganate For The Cleavage Of Semicarbazones And Phenylhydrazones Under Solvent-Free Conditions
  作者:Hajipour,Abdol R.; Adibi,Hadi; Ruoho,Arnold E.
  参考文献:Journal Of Organic Chemistry 日期:2003 卷标:68(11) 页码:4553-4555]
  
  613-31-0 = 90-44-8
  反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide,Oxygen Catalysts: 2257484-14-1 Solvents: Water; 4 H,Rt
  标题:Cu(I)-Based Metal-Organic Frameworks As Efficient And Recyclable Heterogeneous Catalysts For Aqueous-Medium C-H Oxidation
  作者:Gao,Kuan; Huang,Chao; Yang,Yisen; Li,Hong; Wu,Jie; Et Al
  参考文献:Crystal Growth & Design 日期:2019 卷标:19(2) 页码:976-982]
  
  529-86-2 = 90-44-8
  反应条件:1.1 Reagents: Sodium Hypochlorite (Dowex 1X8-200 Supported) Solvents: Acetone; 2 H,Reflux
  标题:Sodium Hypochlorite-Dowex 1X8-200: A Convenient Oxidizing Reagent
  作者:Hashemi,Mahmoodi; Mohammad; Ahmadibeni,Yousef
  参考文献:Iranian Journal Of Chemistry & Chemical Engineering 日期:2002 卷标:21(2) 页码:71-73

海关参考信息

• 2912110000-甲醛
  2912210000-苯甲醛
  2914190090-其他无环酮
  2914399090-其他芳香酮
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

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