CAS: 7099-88-9; 2-(4-Chlorophenyl)-2-Oxoacetic Acid

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CAS号34966-48-8 4-氯苯甲酰甲酸乙酯 | CAS号4254-20-0 1,2-双(4-氯苯基)-2-羟基乙酮 | CAS号3457-46-3 4,4'-二氯苯偶酰 | CAS号74-11-3 对氯苯甲酸 | CAS号85-56-3 2-(4-氯苯甲酰)苯甲酸 | CAS号6212-33-5 DL-对氯苯甘氨酸 | CAS号6265-91-4 2-(4-氯苯基)苯并噻唑 | CAS号104132-79-8 Benzeneacetyl c... | CAS号1019-85-8 2-(4-氯苯基)苯并咪唑 | CAS号104-88-1 对氯苯甲醛

📜对氯苯乙酮置于selenium(Iv) Oxide体系中,用 吡啶 作为反应溶剂,化学反应 18.0H,反应生成 (4-氯苯基)乙醛酸
参考文献:A Palladium-Catalyzed 4Czipn-Mediated Decarboxylative Acylation Reaction Of O-Methyl Ketoximes With α-Keto Acids Under Visible Light
标题:A Palladium-Catalyzed 4Czipn-Mediated Decarboxylative Acylation Reaction Of O-Methyl Ketoximes With α-Keto Acids Under Visible Light
摘要:这项工作介绍了一种钯催化的氧肟醚导向的正选择性苯甲酰化反应,使用苯甲酰甲酸作为酰基来源,钯催化剂和4Czipn作为共催化剂,在光照下进行.得到了多种非对称苯甲酮衍生物,收率在中等到非常好之间.初步的机制研究表明,反应通过自由基途径进行.
DOI:10.3390/molecules27061980

专利信息

专利号:US-2021323987-A1
优先权日:2018-08-20
标题:Methods for the Synthesis of Heteroatom Containing Polycyclic Aromatic Hydrocarbons
发明人：GARG NEIL K; DARZI EVAN R; BARBER JOYANN S; SUSICK ROBERT; CHARI JASON; SPENCE KATIE
权利人:UNIV CALIFORNIA
摘要:Methods for the synthesis of polycyclic aromatic hydrocarbons and synthesis platforms for performing such syntheses are provided. Methods and platforms are provided that allow for the synthesis of aza-polycyclic aromatic hydrocarbons by an expedient ring assembly. Methods and platforms allow for a modular approach to synthesis that provide multiple new C—C bonds in sequential pericyclic reactions, thus giving access to compounds with multiple axes of substitution.

专利号:CN-108017635-A
优先权日:2018-02-02
标 题 :A kind of method of continuous reaction synthesis aryl benzoquinazinone compound