📜二苯基磷酸乙酯置于碘,Magnesium体系中,用 二氯甲烷 作为反应溶剂,化学反应生成 二苯基甲氧基膦 参考文献:Reduktion Der O-Alkylsalze Von Phosphinoxiden,Phosphonaten Und Phosphoniten 标题:Reduktion Der O-Alkylsalze Von Phosphinoxiden,Phosphonaten Und Phosphoniten 摘要: DOI:10.1007/bf00901104
专利号:WO-2021014395-A1 优先权日:2019-07-24 标题:Process for the synthesis of deuterated capsaicin, capsaicinoids and synthetic capsaicin analogs 发明人:ORUGANTI SRINIVAS; AMRUTAPU SRAVANTH KUMAR; SAMPATH MAGESH; SEN SAIKAT 权利人:DR REDDY’S INST OF LIFE SCIENCES 摘要:The present application provides novel processes for the synthesis of deuterated intermediates of capsaicinoids, particularly II, III, IV and V of capsaicinoids, relating to pharmaceutical applications. The invention also provides novel intermediates of compounds of formula IX, XIV, XV, XVI, XVII, XVIII, XX and XXI utilized in the process of making deuterated capsaicin II, III, IV and V.
专利号:WO-2020255049-A1 优先权日:2019-06-20 标题:Process for the preparation and identification of deuterated eugenol 发明人:ORUGANTI SRINIVAS; AMRUTAPU SRAVANTH KUMAR; SAMPATH MAGESH; SEN SAIKAT 权利人:DR REDDY’S INST OF LIFE SCIENCES 摘要:The present invention provides a novel, simple, unique and viable processes for the synthesis of deuterium incorporated eugenols, such as deuterated eugenol (II), regioisomeric deuterated eugenol (III), and deuterated variant of methyl eugenol (V).
专利号:US-12291489-B2 优先权日:2016-07-01 标 题 :Synthesis of nanocomposites and their use in enhancing plant nutrition 发明人:BISWAS PRATIM; RALIYA RAMESH 权利人:BISWAS PRATIM; RALIYA RAMESH; WASHINGTON UNIVERSITY ST LOUIS 摘要:The present disclosure is related to the development of improved fertilizer for precision and sustainable agriculture. A method was developed wherein efficient NPK nanocomposite for plant nutrition was synthesized in a single step using aerosol science and technology concepts. Further a formulation was prepared by addition of ZnO, TiO 2 and other nanoparticles to the NPK nanocomposite. Also, an aerosol based foliar application technique was developed for the precise delivery of nanoparticles to the plants.
专利号:US-12049443-B2 优先权日:2018-12-10 标题 :Synthesis of conjugated diene pheromones and related compounds 发明人:WAMPLER KEITH M; LEE CHOON WOO; ROZZELL DAVID 权利人:PROVIVI INC 摘要:Methods for preparing conjugated dienes are described. An α,β-unsaturated E olefin intermediate may be prepared via cross-metathesis using a catalyst comprising a transition metal (e.g., ruthenium), a first carbene ligand (e.g., a substituted indenylidene) and an N-heterocyclic carbene ligand (e.g., an imidazolidinylidene). The catalyst further includes a phenylphosphine ligand, a tri(isopropoxy)phosphine ligand, a dimethylsulfoxide ligand, an acetonitrile ligand, or a pyridine ligand. Following the cross metathesis-step, the α,β-unsaturated aldehyde intermediate may be converted to the conjugated diene product via reaction with a phosphonium ylide. Products obtained via the methods of the disclosure include (7E,9Z)-dodeca-7,9-dien-1-yl acetate, a pheromone produced by Lobesia botrana (European grapevine moth), and other insect pheromones.
专利号:US-5342909-A 优先权日:1992-04-03 标题:Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization 发明人:GRUBBS ROBERT H; JOHNSON LYNDA K; NGUYEN SONBINH T 权利人:CALIFORNIA INST OF TECHN 摘要:Processes for the synthesis of several new carbene compounds of ruthenium and osmium are provided. These novel complexes function as stable, well-defined catalysts for the metathesis polymerization of cyclic olefins.
专利号:US-11173476-B2 优先权日:2016-08-15 标题 :Metathesis catalysts 发明人:HERRON JESSICA R; PEDERSON RICHARD L; JOHNS ADAM M; GIARDELLO MICHAEL A 权利人:UMICORE AG & CO KG 摘要:This invention relates generally to olefin metathesis catalysts, to the preparation of such compounds, compositions comprising such compounds, methods of using such compounds, and the use of such compounds in the metathesis of olefins and in the synthesis of related olefin metathesis catalysts. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and in industrial applications such as oil and gas, fine chemicals and pharmaceuticals.
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