CAS: 4020-99-9; Methoxydiphenylphosphine

该化合物是有机磷的化合物,其特征是磷的功能组,这种物质一般是无色的黄色液体,以其作为悬浮体和化学协调中的中间体和有机合成中的中间体而著称,在标准条件下具有中度稳定性,但对水分和空气具有敏感性,可能导致水解或氧化;该化合物在有机溶剂中溶解,在各种化学反应中有用;甲基P,P-二苯基硫化物由于存在磷原子,可以参与核细胞替代反应,与金属协调,加强其在催化过程中的效用;在处理该化合物时,有必要采取安全防范措施,因为吸入或摄入这种化合物可能会对健康造成危害,而且应当使用适当的个人防护设备.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

methanol chloro-diphenylphosphine trifluoroacetic acid-methyl ester (dimethylamino)(diphenyl)phosphinediphenyltrichloromethylphosphine oxide (α-diphenylphosphinoyl-benzyliden)-amidophosphoric acid diphenyl ester diphenyl(acetyl)phosphine oxide 5-benzo[1,3,2]thiazaphosphole3-(2,6-dimethyl-phenyl)-2-methoxy-2,2-diphenyl-2,3-dihydro-2λ5-benzo[1,3,2]thiazaphosphole

合成工艺路线路线简述

    📜二苯基磷酸乙酯置于碘,Magnesium体系中,用 二氯甲烷 作为反应溶剂,化学反应生成 二苯基甲氧基膦
    参考文献:Reduktion Der O-Alkylsalze Von Phosphinoxiden,Phosphonaten Und Phosphoniten
    标题:Reduktion Der O-Alkylsalze Von Phosphinoxiden,Phosphonaten Und Phosphoniten
    摘要:
    DOI:10.1007/bf00901104

    海关参考信息

    专利信息


    专利号:WO-2021014395-A1
    优先权日:2019-07-24
    标题:Process for the synthesis of deuterated capsaicin, capsaicinoids and synthetic capsaicin analogs
    发明人:ORUGANTI SRINIVAS; AMRUTAPU SRAVANTH KUMAR; SAMPATH MAGESH; SEN SAIKAT
    权利人:DR REDDY’S INST OF LIFE SCIENCES
    摘要:The present application provides novel processes for the synthesis of deuterated intermediates of capsaicinoids, particularly II, III, IV and V of capsaicinoids, relating to pharmaceutical applications. The invention also provides novel intermediates of compounds of formula IX, XIV, XV, XVI, XVII, XVIII, XX and XXI utilized in the process of making deuterated capsaicin II, III, IV and V.

    专利号:WO-2020255049-A1
    优先权日:2019-06-20
    标题:Process for the preparation and identification of deuterated eugenol
    发明人:ORUGANTI SRINIVAS; AMRUTAPU SRAVANTH KUMAR; SAMPATH MAGESH; SEN SAIKAT
    权利人:DR REDDY’S INST OF LIFE SCIENCES
    摘要:The present invention provides a novel, simple, unique and viable processes for the synthesis of deuterium incorporated eugenols, such as deuterated eugenol (II), regioisomeric deuterated eugenol (III), and deuterated variant of methyl eugenol (V).

    专利号:US-12291489-B2
    优先权日:2016-07-01
    标 题 :Synthesis of nanocomposites and their use in enhancing plant nutrition
    发明人:BISWAS PRATIM; RALIYA RAMESH
    权利人:BISWAS PRATIM; RALIYA RAMESH; WASHINGTON UNIVERSITY ST LOUIS
    摘要:The present disclosure is related to the development of improved fertilizer for precision and sustainable agriculture. A method was developed wherein efficient NPK nanocomposite for plant nutrition was synthesized in a single step using aerosol science and technology concepts. Further a formulation was prepared by addition of ZnO, TiO 2 and other nanoparticles to the NPK nanocomposite. Also, an aerosol based foliar application technique was developed for the precise delivery of nanoparticles to the plants.

    专利号:US-12049443-B2
    优先权日:2018-12-10
    标题 :Synthesis of conjugated diene pheromones and related compounds
    发明人:WAMPLER KEITH M; LEE CHOON WOO; ROZZELL DAVID
    权利人:PROVIVI INC
    摘要:Methods for preparing conjugated dienes are described. An α,β-unsaturated E olefin intermediate may be prepared via cross-metathesis using a catalyst comprising a transition metal (e.g., ruthenium), a first carbene ligand (e.g., a substituted indenylidene) and an N-heterocyclic carbene ligand (e.g., an imidazolidinylidene). The catalyst further includes a phenylphosphine ligand, a tri(isopropoxy)phosphine ligand, a dimethylsulfoxide ligand, an acetonitrile ligand, or a pyridine ligand. Following the cross metathesis-step, the α,β-unsaturated aldehyde intermediate may be converted to the conjugated diene product via reaction with a phosphonium ylide. Products obtained via the methods of the disclosure include (7E,9Z)-dodeca-7,9-dien-1-yl acetate, a pheromone produced by Lobesia botrana (European grapevine moth), and other insect pheromones.

    专利号:US-5342909-A
    优先权日:1992-04-03
    标题:Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization
    发明人:GRUBBS ROBERT H; JOHNSON LYNDA K; NGUYEN SONBINH T
    权利人:CALIFORNIA INST OF TECHN
    摘要:Processes for the synthesis of several new carbene compounds of ruthenium and osmium are provided. These novel complexes function as stable, well-defined catalysts for the metathesis polymerization of cyclic olefins.

    专利号:US-11173476-B2
    优先权日:2016-08-15
    标题 :Metathesis catalysts
    发明人:HERRON JESSICA R; PEDERSON RICHARD L; JOHNS ADAM M; GIARDELLO MICHAEL A
    权利人:UMICORE AG & CO KG
    摘要:This invention relates generally to olefin metathesis catalysts, to the preparation of such compounds, compositions comprising such compounds, methods of using such compounds, and the use of such compounds in the metathesis of olefins and in the synthesis of related olefin metathesis catalysts. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and in industrial applications such as oil and gas, fine chemicals and pharmaceuticals.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Ojima, I.; Vu, A. T.; Bonafoux, D., Science of Synthesis, (2001) 1, 561.
    摘要:Oshima, K., Science of Synthesis, (2003) 2, 62.
    摘要:Kündig, E. P.; Pache, S. H., Science of Synthesis, (2003) 2, 199.
    摘要:Gilchrist, T. L., Science of Synthesis, (2005) 18, 1122.
    摘要:Heydt, H., Science of Synthesis, (2006) 24, 455.
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