1H-Benzo[h]Quinolin-10-One 以 甲醇 用作溶剂,化学反应生成10-羟基苯并[h]喹啉 参考文献:Photophysical Model Of 10-Hydroxybenzo[h]Quinoline: Internal Conversion And Excited State Intramolecular Proton Transfer 标题:Photophysical Model Of 10-Hydroxybenzo[h]Quinoline: Internal Conversion And Excited State Intramolecular Proton Transfer 摘要:10-羟基苯并[h]喹啉(hbq)的光物理特性一直存在争议,特别是关于分子内质子转移(esipt)激发态之前和之后的电子态性质,尽管esipt的动力学和机理已经得到充分证实.我们报告了烯醇和酮异构体全发射频率区域的高度时间分辨荧光光谱以及时域各向异性,以确定酮异构体的精确衰减率,光谱弛豫和各向异性衰减.我们已经证明,在esipt动力学中经常观测到的约300飞秒的成分来自反应产物酮异构体的$s_2{\rightarrow}S_1$内部转换,并且esipt发生在烯醇异构体从$s_1$状态到酮异构体从$s_2$状态. Doi:10.5012/bkcs.2014.35.3.881
专利号:US-6977141-B2 优先权日:1998-02-10 标 题 :Direct adsorption scintillation assay for measuring enzyme activity and assaying biochemical processes 发明人:YUAN ZHENGYU; CHEN ZHONG-XIAO 权利人:VICURON PHARM INC 摘要:Methods and materials for scintillation assays are disclosed. The scintillation assays rely on differences in general molecular property-based binding interactions, such as charge or hydrophobicity, to localize a radioactive substance near a scintillating material, stimulating scintillation. They are thus described as a direct adsorption scintillation assay (DASA) to distinguish them from the scintillation proximity assay (SPA). The assays are more convenient and inexpensive to implement than SPAs, which rely on specific binding of ligand-receptor pairs, antibody-antigen pairs, or other binding partners which rely on the precise and specific structural complementarity of the partners. The assays can be employed for studying enzymatic reactions, such as those involved in the synthesis of Mur-pentapeptide. The assays are readily adaptable to high throughput screening for use in conjunction with combinatorial libraries of compounds.
专利号:CN-104672152-A 优先权日:2013-11-28 标 题 :Organic compounds and their applications in the synthesis of organometallic complexes
专利号:CN-104672152-B 优先权日:2013-11-28 标 题:Organic compounds and their applications in the synthesis of organometallic complexes
专利号:CN-111362977-A 优先权日:2018-11-29 标题:A kind of bimolecular polar compound and its synthesis and application
专利号:CN-109174200-A 优先权日:2018-09-04 标 题:A kind of catalyst, preparation method and synthesis method for synthesizing 1,1-diethoxyethane
专利号:CN-114436940-B 优先权日:2015-10-23 标 题 :Compounds and methods of synthesis
参考文献:10.1039/c6pp00377j 摘要:Huang J, Muliawan AP, Ma J, De Li M, Chiu HK, Lan X, Deodato D, Phillips DL, Dore TM. A spectroscopic study of the excited state proton transfer processes of (8-bromo-7-hydroxyquinolin-2-yl)methyl-protected phenol in aqueous solutions. Photochemical & Photobiological Sciences. 2017 Apr;16(4):575–84. doi: 10.1039/c6pp00377j.