CAS: 27081-10-3; Tropyliumtetrafluoroborate
该化合物是一种以环己烷基化合物和四氟芳烃阴离子存在为特征的离子化合物.环己烷基烷基环(环己二烯基环)和四氟芳烷烷烷离子.环己二烯基烷基离子(环己二烯基)来自环己二烯基环己二烯基碳环,一种七人碳环,具有交替的双环双环双环,有助于其芳香类稳定性,尽管其独特的电子特性和再活动性,但这种化合物通常通过共振动而稳定.这种化合物通过对水分和空气的敏感度来处理,这可能会影响其稳定性和再活动.
- 英文名称Tropyliumtetrafluoroborate
- 中文名称四氟硼酸卓鎓
- IUPAC名称cyclohepta-1,3,5-triene tetrafluoroborate
- 其它别名tropylium fluoborate; tropylium tetrafluoroborate; cycloheptatrienylium,tetrafluoroborate(1-); tropyliumtetrafluoroborate,; tropylium fluoroborate; cycloheptatrienylium tetrafluoroborate.; tropylium tetrafluoroborate ; tropyliumtetrafluoroborate
- CAS编号27081-10-3
- MFCD编号:MFCD00013402
- EINECS号:248-214-5
- FDA UNII编号:DFS83J4CRL
- 分子式:C7H7BF4分子量:177.94
- 产品CID: 1250604
- 产品分类有机原料→催化剂与配体→催化剂→其它金属催化剂
- 相似结构搜索
- 产品信息参考
;;;; - InChIKey: SQVQHTIKOZVGLR-UHFFFAOYSA-N
- InChI=1S/C7H7.BF4/c1-2-4-6-7-5-3-1;2-1(3,4)5/h1-7H;/q+1;-1
- 计算化学: 氢键受体数*氢键供体数0.0可旋转键数0.0
相似化合物
29663-54-5物理性质
MSDS等安全信息
- GHS象形图
- GHS符号GHS05;
注释: Corrosion - 危险类别皮肤腐蚀 类别1B
急性毒性 类别4(经口)
皮肤腐蚀 类别1C
严重眼损伤 类别1 - 警示词Danger(危险)
- 危险描述H314 |造成严重皮肤灼伤和眼损伤.
H302 |吞咽有害.
H318 |造成严重眼损伤. - 防范说明P260-P264-P280-P301+P330+P331-P304+P340-P363-P405-P501
- 危险等级8
- UN编号UN 3261 8/PG 2
- 危险品标志Xi,C
- 风险等级Irritant/Keep Cold/Moisture Sensitive
- 包装等级III
- 安全声明22-28-45-36/37/39-26
- 危险类别码37/38-34
- WGK Germany3
欧盟法规
ECHA物质C&L通报REACH预注册上下游产品
CAS号544-25-2 环庚三烯 | CAS号698-84-0 2,4,6-cyclohept... | CAS号1714-38-1 1,3,5-Cyclohept... | CAS号4440-40-8 cyclohepta-2,4,... | CAS号19052-86-9 7-methylsulfany... | CAS号341-02-6 三苯基甲基四氟硼酸盐 | CAS号76044-18-3 tert-butyl(cycl... | CAS号39915-66-7 1,3-dithian-2-y... | CAS号86201-64-1 2-phenyl-1,3-di... | CAS号86201-65-2 2-(4-Chlorpheny... | CAS号106111-52-8 2-phenyl-1,8-di... | CAS号3376-24-7 N-叔丁基-α-苯基硝酮 | CAS号19052-86-9 7-methylsulfany... | CAS号779-02-2 9-甲基蒽 | CAS号87-85-4 六甲基苯 | CAS号29304-86-7 7-(4-chlorophen... | CAS号30366-75-7 4-cyclohepta-1,... | CAS号28673-74-7 1,3,5-Cyclohept... | CAS号18982-54-2 2-溴苄醇合成工艺路线路线简述
📜环庚三烯,五氯化磷,氟硼酸 反应生成四氟硼酸卓鎓
参考文献:Albeck,M.;Tamari,Tova;Sprecher,M.,J. Org. Chem.,1983,48,N 13,2276-2278
标题:Albeck,M.;Tamari,Tova;Sprecher,M.,J. Org. Chem.,1983,48,N 13,2276-2278
专利信息
专利号:US-4249025-A
优先权日:1978-04-28
标 题:Novel process for synthesis of a liquid irritant, 1-methoxycycloheptratriene
发明人：HYDRO WILLIAM R
权利人:US ARMY
摘要:An improved multi-step process for synthesizing the liquid irritant 1-metycycloheptatriene from tropylium tetrafluoborate the improvement comprising the step of using a polymerization/condensation inhibitor or retarder to minimize impurities and increase yield of the irritant product. Phenothiazine is the preferred polymerization inhibitor.
专利号:US-4978806-A
优先权日:1989-01-24
标题:Scale-up and synthesis of 1-methoxycyglohepta-1,3,5-triene
发明人：LANGFORD GORDON E
权利人:UNITED KINGDOM GOVERNMENT
摘要:A method for preparation of 1-methoxycyclohepta-1,3,5-triene in commercial quantities, which comprises the steps of heating 7,7-dichloro-1-methoxybicyclo[4.1.0]heptane in a refluxing reaction solvent comprising a lower boiling aromatic amine, at reflux, until suitable amounts of 1-methoxycyclohepta-1,3,5-triene have been produced, and recovering the 1-methoxycyclohepta-1,3,5-triene. Suitable reaction solvents include 2-picoline, pyridine and 2,6-lutidine. The method according to the present invention results in safer temperature control in the production of 1-methoxycyclohepta-1,3,5-triene, and increased yields.
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品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:Novel Process For Synthesis Of A Liquid Irritant,摘要:An Improved Multi-Step Process For Synthesizing The Liquid Irritant 1-Metycycloheptatriene From Tropylium Tetrafluoborate The Improvement Comprising The Step Of Using A Polymerization/condensation Inhibitor Or Retarder To Minimize Impurities And Increase Yield Of The Irritant Product. Phenothiazine Is The Preferred Polymerization Inhibitor.
合成参考文献
参考文献:10.1007/978-981-13-9144-6_3
摘要:Ortiz Villamizar MC, Galvis CEP, Kouznetsov VV. The C-1 Functionalization of Tetrahydroisoquinolines via Cross-Dehydrogenative Coupling Reactions. 2019. In: Heterocycles via Cross Dehydrogenative Coupling.
参考文献:10.1007/s10593-023-03157-3
摘要:Borodkin GI. Carbocation Catalysis in the Synthesis of Heterocyclic Compounds. Chem Heterocycl Comp. 2023 Feb;59(1-2):16–34. doi: 10.1007/s10593-023-03157-3.
参考文献:10.1134/s1070428023070187
摘要:Akent’eva TA, Zhakova SN. para-Substituted Anilines in Reactions with Tropylium Salts and Dibenzosuberenol. Russ J Org Chem. 2023 Jul;59(7):1251–4. doi: 10.1134/s1070428023070187.
参考文献:10.1134/s1070428023110209
摘要:Yunnikova LP, Akent’eva TA, Yunnikova EA. C- or N-Functionalization of a Tropylium Salt with 2-Amino-4-methylthiazole or 5-Aminotetrazole. Russ J Org Chem. 2023 Nov;59(11):1994–7. doi: 10.1134/s1070428023110209.
参考文献:10.1134/s1070428024060010
摘要:Yunnikova LP, Pshenitsyna OV. Nucleophilic Functionalization of Tropylium Salts with Heterocyclic Amines and Carboxylic Acid Amides and Hydrazides. Russ J Org Chem. 2024 Jun;60(6):971–83. doi: 10.1134/s1070428024060010.
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