CAS: 1873-77-4; 1,1,1,3,3,3-Hexamethyl-2-(Trimethylsilyl)Trisilane

相似化合物

4098-98-0 2003-85-2 7428-60-6

上下游产品

chlorotris(trimethylsilyl)silane tris(trimethylsilyl)silyl bromide Tris(trimethylsilyl)iodsilan -2-phenylethane1--2-phenylethane propenal(Z)-3-phenyl-2-propenal propenal(E)-3-phenyl-2-propenal

📜Tris(Trimethylsilyl)Silyl Yttrium Diiodide Tris(Tetrahydrofuran)置于叔丁醇体系中,化学反应生成三(三甲基硅基)硅烷
参考文献:Synthesis,Characterization And Reactivity Of Yttrium And Gadolinium Silyl Complexes
标题:Synthesis,Characterization And Reactivity Of Yttrium And Gadolinium Silyl Complexes
摘要:The Syntheses Of Yttrium And Gadolinium-Silyl Complexes Of The Form R(Me3Si)(2)Simi2(Thf)(3) (M = Y,Gd; R = Et,Sime3) Through Reactions Of Potassium Silyl Reagents,Ksir(Sime3)(2)(Thf)(N) (R = Sime3,N = 2; R = Et,N = 0.5),With The Appropriate Metal Halide Precursors Are Described. The Complexes Are Shown To React With Protic Compounds,Hx (X = H,Oh,Otbu),In Protonolysis Reactions Releasing The Respective Silane. The Metal-Silyl Complexes Also React With 2,6-Dimethylphenyl Isocyanide To Yield The Metallazirine Products And With Carbodiimides To Generate Amidinate Complexes. Eleven Of The Twelve Complexes Have Been Characterized Using X-Ray Diffraction,With Three Exceedingly Rare Non-Cp Containing Rare Earth Metal-Silyl Structures Among Those Described. (C) 2014 Elsevier B.V. All Rights Reserved.
Doi:10.1016/j.Ica.2014.04.030

专利信息

专利号:US-7956011-B2
优先权日:2005-05-04
标题:Materials and methods for the photodirected synthesis of oligonucleotide arrays
发明人：SERAFINOWSKI PAWEL JERZY; GARLAND PETER BRYAN
权利人:CANCER RES INST ROYAL
摘要:Materials and methods for photodirected synthesis of oligonucleotide arrays on a solid substrate by photodirected synthesis are disclosed which employ a film formed from (i) a photoacid generator that on photolysis generates acid that is capable of directly removing the protecting group of the linker molecules or oligonucleotides and (ii) a polymer substantially lacking electronegative heteroatoms that are capable of hydrogen bonding with photogenerated acid. Methods of synthesizing an oligomer arrays are also described that use a film that restricts diffusion of reactants and products on the substrate during synthesis of the array and which includes a precursor of a deprotecting reagent. The method involves removing one or more of the non-required products of the deprotection reaction from the reactive array elements at which they are produced during the reaction, in order to displace the deprotection reaction towards completion.

专利号:US-11999757-B2
优先权日:2017-11-01
标 题:Synthesis of boronate ester derivatives and uses thereof
发明人：BOYER SERGE HENRI; HECKER SCOTT J; VERZIJL GERARDUS K M; HERMSEN PETRUS J
权利人:MELINTA SUBSIDIARY CORP
摘要:Disclosed herein are methods for the preparation of boronate derivatives in the synthesis of antimicrobial compounds and uses thereof. Disclosed herein includes method of making a compound of Formula (B) by reducing the ketone group of the keto-ester compound of Formula (A), and the reduction can be performed using a Ruthenium based catalyst system or using an alcohol dehydrogenase bioreduction system.

专利号:US-7094805-B2
优先权日:2001-12-14
标 题 :Total synthesis of merrilactone A
发明人：DANISHEFSKY SAMUEL J; BIRMAN VLADIMIR B
权利人:UNIV COLUMBIA
摘要:This invention provides a total synthesis of Merrillactone and Merrilactone analogues for use as neurotrophic agents in the treatment of neurodegenerative diseases. The invention also provides intermediates for use in the synthesis of Merrilactone and its analogues.

专利号:US-6998484-B2
优先权日:2000-10-04
标 题:Synthesis of purine locked nucleic acid analogues
发明人：KOCH TROELS; JENSEN FLEMMING REISSIG
权利人:SANTARIS PHARMA AS
摘要:The present invention relates to a new method for the synthesis of purine LNA (Locked Nucleic Acid) analogues which provides a higher overall yield. The method comprising a regioselective 9-N purine glycosylation reaction followed by a one-pot nucleophilic aromatic substitution reaction of the 6-substituent in the purine ring and simultaneous nucleophile-induced intramolecular ring closure of the C-branched carbohydrate to form novel purine LNA analogues. The novel strategy is illustrated by the synthesis of the novel compound (1S,3R,4R,7S)-7-benzyloxy-1-methanesulfonylmethyl-3-(guanin-9-yl)-2,5-dioxabicyclo[2.2.1]heptane which is easily converted into (1S,3R,4R,7S)-7-hydroxy-1-hydroxymethyl-3-((2-N-isobutyrylguanin-9-yl)-2,5-dioxabicyclo[2.2.1]heptane after isobutyryl protection of the 2-amino purine group and subsequent substitution of 1-methanesulfonyl with benzoate, debenzoylation and debenzylation.

专利号:US-10669292-B2
优先权日:2014-05-05
标 题 :Synthesis of boronate salts and uses thereof
发明人：HECKER SCOTT; BOYER SERGE
权利人:REMPEX PHARMACEUTICALS INC
摘要:Disclosed herein are boronate intermediates in the synthesis of antimicrobial compounds and the use and preparation thereof. Some embodiments relate to crystalline boronate salt derivatives and their use in the synthesis of therapeutic compounds.

专利号:US-10918627-B2
优先权日:2016-05-11
标 题:Convergent and enantioselective total synthesis of Communesin analogs
发明人：MOVASSAGHI MOHAMMAD; LATHROP STEPHEN PAUL; POMPEO MATTHEW W; CHANG WEN-TAU TIMOTHY
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:A highly convergent biomimetic synthesis of a complex polycyclic scaffold has been successfully implemented. From these efforts, compounds having a structure of Formula (I): n nor a pharmaceutically acceptable salt, tautomer or stereoisomer thereof, wherein R 1 -R 8 and m, n, r, s, t, and u are as defined herein, is provided. Methods of making such compounds are also disclosed as are methods for the treatment of cancer, various infectious diseases, and abnormal cardiovascular function.