CAS: 10026-11-6; Zirconium(Iv) Chloride

该化合物是一种无机化合物,其特征是白色晶状表面,通常在室温时形成固体,在水和酒精等极地溶剂中高度溶解,在水解过程中可释放盐酸.ZrCl4以其湿度而著称,意思是它很容易吸收空气中的湿度,这可能导致形成一种水分状.该化合物具有高熔点,并显示出一种四角晶体结构.就再活性而言,氯化是一种刘易斯酸,在各种化学反应中有用,包括催化和有机金属化合物合成.它通常用于生产金属和其他化合物.在处理ZrCl4时,必须采取安全防范措施,因为它可能会对皮肤,眼睛和呼吸系统产生刺激.建议在一个冷却,干燥的地方适当储存,以防止降解和吸收水分.

结构式图片

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

tetrachloro-2,2'-bipyridylzirconium zirconium chlorine thionyl chloridezirconium(IV) oxide (2-butylcyclopenta-2,4-dienyl)zirconium(IV) chloride zirconium tetrachloride bis(tetrahydrofuran) complex

合成工艺路线路线简述

    Zirconium Sulfide置于cl2体系中,用 Neat (No Solvent) 用作溶剂,化学反应生成氯化锆(Iv)
    参考文献:Picon,M.,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1933,Vol. 197,P. 151-153
    标题:Picon,M.,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1933,Vol. 197,P. 151-153

    专利信息


    专利号:US-6479685-B2
    优先权日:1998-01-09
    标题 :Metallocene catalysts for synthesis of high-melting polyolefin copolymer elastomers
    发明人:WAYMOUTH ROBERT M; KRAVCHENKO RAISA L; MACIEJEWSKI PETOFF JENNIFER; HUNG JOYCE
    权利人:TRUSTEES OF THE LELAND STANDAR
    摘要:Metallocene catalysts having plural coordination geometries for synthesis of high melting polyolefin copolymers suitable as thermoplastic elastomers. The inventive catalysts comprise unbridged, substituted or unsubstituted cyclopentadienyl metallocene catalysts that are capable of inter-converting between states with different polymerization or copolymerization characteristics, which interconversion is controlled by selecting the substituents of the cyclopentadienyl ligands so that the rate of interconversion of the two states is within several orders of magnitude of the rate of formation of a single polymer chain. Where r i >r f the polymer can be characterized as multiblock; where r i
    专利号:US-2024075466-A1
    优先权日:2021-04-09
    标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites
    发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE
    权利人:UMICORE AG & CO KG
    摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.

    专利号:US-2022297083-A1
    优先权日:2019-08-27
    标 题 :Continuous Synthesis Of Porous Coordination Polymers In Supercritical Carbon Dioxide
    发明人:RASMUSSEN ELIZABETH G; KRAMLICH JOHN C; NOVOSSELOV IGOR V
    权利人:UNIV WASHINGTON
    摘要:This disclosure relates generally relates to methods and systems useful for continuous synthesis of materials in super-critical carbon dioxide (sCO 2 ). More particularly, this disclosure relates to methods and systems useful for continuous synthesis of coordination polymers, such as metal-organic frameworks (MOFs) and/or covalent organic frameworks (COFs), in sCO 2 .

    专利号:US-2008119665-A1
    优先权日:2004-09-07
    标 题:Process for the Synthesis of Zirconium Carboxylates
    发明人:FRITZ PETER; BOLT HEINZ; SCHERSCHLICHT KARL-HEINZ; MOSA FUAD; ALI TALAL K; AL-OTAIBI SULTAN
    权利人:FRITZ PETER; BOLT HEINZ; SCHERSCHLICHT KARL-HEINZ; MOSA FUAD; ALI TALAL K; AL-OTAIBI SULTAN
    摘要:A process for the synthesis of zirconium tetra carboxylates is disclosed. To overcome the disadvantageous characteristics of the currently used production process, which include highly corrosive starting substances and products, and complex removal of HCl, ZrCI 4 is suspended in an apolar solvent and reacted with the anhydride of an organic acid. The sole products of this reaction are slightly corrosive Zr tetra carboxylate and an organic acid chloride, which is a valuable basic chemical in the chemicals and pharmaceuticals industry. The reactors required for the synthesis need not necessarily consist of glass and/or enamel, but may instead be manufactured from stainless steel, which is cheaper. Apparatuses for the removal and treatment of hydrochloric acid are not necessary.

    专利号:US-11655264-B2
    优先权日:2015-11-25
    标题:Metallocene compounds, and preparation and use thereof for synthesis of poly-alpha-olefins as lubricating base oil
    发明人:WEI DONGCHU; LI BING
    权利人:APALENE TECH CO LTD JIAXING
    摘要:The present invention relates to a metallocene compound, and preparation and use thereof, and the compound can be used as a catalyst for synthesis of poly-α-olefin as lubricating base oil. The metallocene compound includes a substituted aryl group, a bridged atom, an optionally unsubstituted, 3-mono-substituted or 3,6-disubstituted 5H-indeno [1,2-b] pyridyl group or optionally unsubstituted, 3-mono-substituted or 3,6-disubstituted 5H-indeno [1,2-b] thiopyranyl group, and a metal coordination group. As a catalyst, the metallocene compound is shown to be structurally stable and high in catalytic efficiency, and the preparation of the catalyst is relatively easy in operation, high in yield, low in cost, low in pollution and easy to scale up for industrial production.

    专利号:US-6025492-A
    优先权日:1996-08-30
    标 题 :Synthesis of a hydrazone β-keto ester by the reaction with a diazo ester
    发明人:SHAH AJIT S; CLARK JERRY D; MA YINONG; PETERSON JAMES C; PATELIS LEFTERIS
    权利人:MONSANTO CO
    摘要:The present invention relates to the synthesis of a hydrazone β-keto ester by the reaction of an alkyl diazoester with a hydrazone aldehyde in the presence of a Lewis acid In a preferred embodiment, the hydrazone β-keto ester is then converted into a pyridazinone compound by the reaction with an alkyl acid chloride in the presence of a base, followed by acidification. A process for the production of a hydrazone aldehyde, which comprises contacting a hydrazine and glyoxal, is also described.
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    合成参考文献


    摘要:Merino, P., Science of Synthesis, (2010) 45, 306.
    摘要:Tchabanenko, K., Science of Synthesis Knowledge Updates, (2013) 1, 57.
    摘要:Hou, X.-L.; Peng, X.-S.; Yeung, K.-S.; Wong, H. N. C., Science of Synthesis Knowledge Updates, (2011) 2, 335.
    摘要:Cheng, B.; Wang, T., Science of Synthesis Knowledge Updates, (2020) 3, 177.
    摘要:Smith, L. H. S.; Coote, S. C.; Procter, D. J., Science of Synthesis Knowledge Updates, (2010) 3, 476.
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