CAS: 92-77-3; 3-Hydroxy-N-Phenyl-2-Naphthamide

• 英文名称3-Hydroxy-N-Phenyl-2-Naphthamide
• 中文名称萘酚AS
• IUPAC名称3-hydroxy-N-phenyl-2-naphthamide
• 其它别名冰染染料色酚as; 纳夫妥as; Naphthol As
• CAS编号92-77-3
• MFCD编号:MFCD00004096
• EINECS号:202-188-1
• 分子式:C17H13NO2
• 分子量:263.29
• 产品CID: 1966196
• 产品分类有机原料→分子砌块→芳环类化合物→萘类化合物

• 相似结构搜索
• InChIKey: JFGQHAHJWJBOPD-UHFFFAOYSA-N
• InChI=1S/C17H13NO2/c19-16-11-13-7-5-4-6-12(13)10-15(16)17(20)18-14-8-2-1-3-9-14/h1-11,19H,(H,18,20)…
• 计算化学: 氢键受体数2.0氢键供体数2.0可旋转键数2.0

相似化合物

物理性质

• 熔点246-248 °C
• 沸点406.53 °C at 760 mmHg
• 闪点190.738 °C
• 密度1.1138 (粗估)
• PH:Non& uorescence (8.2) to yellow/green & uorescence (10.3)
• pKa:9.70(at 25°C)
• PSA:49.33
• LogP:3.7977
• 折射率1.4500 (估算)
• 溶解性Insoluble In Water; Sparingly Soluble In Ethanol
• 外观形态米色粉末
• 储存条件冰箱
• 产品应用为染料色基,用于生产染料及棉粘胶纤维的染色和印花打底剂,制造快色素染料和有机颜料.
• 性质描述白色至米黄色或微红色均匀粉末,熔点243-250°C

MSDS等安全信息

• GHS象形图
• GHS符号GHS07 & GHS09;
  注释: Exclamation mark & Environment
• 危险类别皮肤致敏 类别1
  皮肤致敏 类别1A
  水生慢性毒性 类别2
  急性毒性 类别4(经口)
  严重眼损伤 类别1
  水生慢性毒性 类别3
  急性毒性 类别4(吸入)
  特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
• 警示词Warning(警告)
• 危险描述H317 |可能引起皮肤过敏反应.
  H411 |对水生生物有毒并具有长期持续影响.
  H302 |吞咽有害.
  H318 |造成严重眼损伤.
  H412 |对水生生物有害并具有长期持续影响.
  H332 |吸入有害.
  H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
• 防范说明P260-P261-P264-P270-P272-P273-P280-P302+P352-P362+P364-P391-P501
• 危险等级9
• UN编号3077.0
• 危险品标志Xi,N
• 包装等级Ⅲ
• 安全声明36/37-61
• 危险类别码43-51/53
• WGK Germany1

欧盟法规

上下游产品

合成工艺路线路线简述

• 92-70-6 = 92-77-3
  反应条件:1.1 Reagents: Phosphonic Acid Solvents: Xylene; 160 - 170 °C; 4 - 6 H,Reflux
  标题:Preparation Process Of Naphthol
  参考文献:China]
  
  92-70-6 = 92-77-3
  反应条件:1.1 Reagents: Phosphorus Trichloride Solvents: 1,2-Dichlorobenzene
  标题:Process For Preparing Naphthol As Products
  参考文献:China]
  
  92-70-6 = 92-77-3
  反应条件:1.1 Catalysts: Triethylamine,P,P′-Dipropyldiphosphonic Acid Solvents: Xylene
  标题:Preparation Of 3-Hydroxy-2-Naphthoic Anilides
  参考文献:Germany]
  
  92-70-6 = 92-77-3
  反应条件:1.1 Reagents: Phosphorus Trichloride Solvents: Chlorobenzene; 15 Min,Heated
  标题:Investigation Of Hydro-Lipophilic Properties Of N-Alkoxyphenylhydroxynaphthalenecarboxamides
  作者:Kapustikova,Iva; Bak,Andrzej; Gonec,Tomas; Kos,Jiri; Kozik,Violetta; Et Al
  参考文献:Molecules 日期:2018 卷标:23(7)]
  
  92-70-6 = 92-77-3 [标题:Reaction Conditions
  标题:Catalytic Aminolysis Of 3-Hydroxy-2-Naphthoic Acid
  作者:Kondratov,S. A.; Shteinberg,L. Ya.; Shein,S. M.; Udovichenko,L. V.; Boiko,V. D.
  参考文献:Zhurnal Organicheskoi Khimii 日期:1994 卷标:30(2) 页码:284-5]
  
  92-70-6 = 92-77-3
  反应条件:1.1 Reagents: Phosphorus Trichloride Solvents: Chlorobenzene; 5 Min,10 - 25 °C; 2.5 H,130 °C
  标题:Synthesis And Investigation Of The Steric Effect On Activity Of N-Substituted-3-Carbamoylnaphthalene-2-Yl α-Chlorocarboxylate In Human Leukocyte Esterase Staining Reaction
  作者:Tran,Van Tinh; Phan,Thi Trang; Nguyen,Anh Tri; Luu,Van Boi
  参考文献:Tap Chi Hoa Hoc 日期:2011 卷标:49(6) 页码:725-732]
  
  = 92-77-3 [标题:Reaction Conditions
  标题:High-Purity N-Aryl-3-Hydroxy-2-Naphthalenecarboxamides
  参考文献:Romania]
  
  92-70-6 = 92-77-3
  反应条件:1.1 Reagents: Thionyl Chloride Catalysts: Dimethylformamide Solvents: Dichloromethane; Rt1.2 Solvents: Tetrahydrofuran; 5 H,Rt -> 45 °C
  标题:Preparation Of Chromosol As
  参考文献:China]
  
  92-70-6 = 92-77-3
  反应条件:1.1 Reagents: Silicon Tetrachloride Solvents: Chlorobenzene
  标题:Production Of Azotol-A From A Mixed Anhydride Of Silicic And 2,3-Hydroxynaphthoic Acids
  作者:Kirsanov,A. V.; Levchenko,E. S.; Tret'Yakova,G. S.
  参考文献:Ukrains'Kii Khemichnii Zhurnal 日期:1953 卷标:19 页码:504-7]
  
  92-70-6 = 92-77-3
  反应条件:1.1 Reagents: Phosphorus Trichloride Solvents: Chlorobenzene; Rt -> 10 °C; 10 °C; 15 Min,135 °C
  标题:Synthesis Of Naphthol As-X Chloroacetates And Study On The Electron Effects On The Human Leukocyte Esterase Staining
  作者:Tran,Van Tinh; Pham,Hoai Thu; Nguyen,Anh Tri; Luu,Van Boi
  参考文献:Tap Chi Hoa Hoc 日期:2011 卷标:49(4) 页码:479-488]
  
  92-70-6 = 92-77-3
  反应条件:1.1 Catalysts: Titanium Tetrabutoxide Solvents: Aniline
  标题:Catalytic Synthesis Of 2,3-Hydroxynaphthoic Acid Anilide
  作者:Kondratov,S. A.; Shteinburg,L. Ya.; Shein,S. M.
  参考文献:Zhurnal Organicheskoi Khimii 日期:1993 卷标:29(9) 页码:1914-15]
  
  92-70-6 = 92-77-3
  反应条件:1.1 Reagents: Phosphorus Trichloride Solvents: Chlorobenzene; Rt; 10 Min,100 °C; 15 Min,120 °C; 20 Min,130 °C
  标题:Antibacterial And Herbicidal Activity Of Ring-Substituted 3-Hydroxynaphthalene-2-Carboxanilides
  作者:Kos,Jiri; Zadrazilova,Iveta; Pesko,Matus; Keltosova,Stanislava; Tengler,Jan; Et Al
  参考文献:Molecules 日期:2013 卷标:18 页码:7977-7997]
  
  92-70-6 = 92-77-3
  反应条件:1.1 Reagents: Phosphorus Oxychloride Solvents: Chlorobenzene; Rt; Rt -> 130 °C; 25 Min,130 °C
  标题:Preparation And Biological Properties Of Ring-Substituted 3-Hydroxynaphthalene-2-Carboxanilides
  作者:Kos,Jiri; Zadrazilova,Iveta; Pesko,Matus; Pavlica,Jiri; Gonec,Tomas; Et Al
  参考文献:International Electronic Conference On Synthetic Organic Chemistry 日期:2012]
  
  92-70-6 = 92-77-3
  反应条件:1.1 Reagents: Oxygen Catalysts: Phenylboronic Acid Solvents: Mesitylene; Rt; 30 H,Reflux
  标题:Preparation Method Of Naphthol As-Series Anilide Dye
  参考文献:China]
  
  1734-00-5 = 92-77-3
  反应条件:1.1 Reagents: Phosphonic Acid Solvents: Water; 75 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; Ph 2.5
  标题:Process For Synthesizing Naphthol
  参考文献:China]
  
  92-70-6 = 92-77-3
  反应条件:1.1 Reagents: Phosphorus Trichloride Solvents: Chlorobenzene; 50 °C -> 90 °C; 2 H,90 °C1.2 Reagents: Sodium Carbonate Solvents: Water; Ph 8.1
  标题:N-(3-Hydroxyl-2-Naphthoyl)Aniline Production Device
  参考文献:China]
  
  92-70-6 = 92-77-3
  反应条件:1.1 Reagents: Phosphorus Trichloride Solvents: Chlorobenzene; 10 Min,100 °C; 15 Min,120 °C; 20 Min,130 °C
  标题:3-Hydroxynaphthalene-2-Carboxanilides And Their Antitrypanosomal Activity
  作者:Kos,Jiri; Kapustikova,Iva; Clements,Carol; Gray,Alexander I.; Jampilek,Josef
  参考文献:Monatshefte Fuer Chemie 日期:2018 卷标:149(5) 页码:887-892]
  
  92-70-6 = 92-77-3
  反应条件:1.1 Reagents: Sodium Dodecyl Sulfate,Sodium Octadecyl Sulfate Solvents: 2-Chlorotoluene,Chlorobenzene; 5 Min1.2 Reagents: Phosphorus Trichloride; 65 °C; 90 °C; 90 °C -> 130 °C; 1 H,120 - 130 °C; 30 °C -> 105 °C; 95 - 105 °C
  标题:Process And Apparatus For Preparation Of Naphthol As
  参考文献:China]
  
  = 92-77-3 [标题:Reaction Conditions
  标题:Purification Of Bisazo Pigments Useful In Electrophotographic Photoconductors
  参考文献:Japan]
  
  = 92-77-3 [标题:Reaction Conditions
  标题:N-Substituted Amides Of 3-Hydroxy-2-Naphthalenecarboxylic Acid
  参考文献:Poland

海关参考信息

• 2902902000-精萘
  2912110000-甲醛
  2912210000-苯甲醛
  2907121100-间甲酚
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• ➥ 防范代码详解
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