CAS: 852458-12-9; 1-Butenylboronic Acid

该化合物是一种有机体,其特点是存在一个附于丁基链的碳酸功能组,通常视其形态和纯度而呈现为无色的黄色液体或固体色状,以其反应性而闻名,特别是在交叉反应中,使其在有机合成和药用化学中具有价值.二醇的碱酸味可形成稳定的复合体,这种复合体在各种应用中非常有用,包括传感器和药物运载系统的开发.此外,一丁基-米亚罗酸可参与铃木-米亚罗的配对反应,促进碳-碳联结的形成.其结构包括一种双联体,有助于其再活动性及聚合化学的潜在应用.与许多有机体化合物一样,处理需要谨慎,因为潜在的再活动以及需要适当的储存条件来保持稳定性.

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7547-97-9 42599-18-8 1301680-12-5

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but-1-yne acetaldehyde dimethylsulfide borane complex

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    专利号:US-8207337-B2
    优先权日:2007-01-29
    标 题:Reagent for organic synthesis reaction containing organic triol borate salt
    发明人:MIYAURA NORIO; YAMAMOTO YASUNORI
    权利人:MIYAURA NORIO; YAMAMOTO YASUNORI; WAKO PURE CHEM IND LTD
    摘要:[Problem] n To provide an organoboron compound-containing reagent for organic synthesis reactions which undergoes no trimerization with dehydration, does not necessitate activation with a base, and is stable and highly active. n [Means for Solving Problems] n The reagent for organic synthesis reactions contains an organic triol borate salt represented by any of the general formulae (I) to (III) and general formula (XVI): (wherein R 1 represents alkyl, alkenyl, etc.; R 2 represents optionally substituted alkyl, alkenyl, alkynyl, etc. or represents hydrogen; m + represents an alkaline metal ion, phosphonium ion, or given ammonium ion; M 2+ represents an alkaline earth metal; X represents halogen or alkoxide; Y represents an alkali metal ion, etc.; A represents optionally substituted methylene; and n represents an integer).

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    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Ruthenium-Catalysed Multicomponent Synthesis Of The 1,3-Dienyl-6-Oxy Polyketide Motif
    作者:Barry M. Trost,James J. Cregg,Christoph Hohn,Wen-Ju Bai,Guoting Zhang,Jacob S. Tracy |发布日期:2020.7
    摘要:Operation And Can Be Used To Generate Chiral Products. The Successful Development Of This Methodology Relies On The Remarkable Efficiency Of The Ruthenium-Catalysed Alkene-Alkyne Coupling Reaction Between Readily Available Vinyl Boronic Acids And Alkynes To Provide Unsymmetrical 3-Boryl-1,4-Diene Reagents. In The Presence Of Carbonyl Compounds, These Reagents Undergo Highly Diastereoselective Allylations To

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    参考DOI号:10.1016/j.bmc.2012.11.042
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