CAS: 511-89-7; Methyl (1S,4As,7R,7As)-4'-((S)-1-Hydroxyethyl)-5'-Oxo-1-(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)-4A,7A-Dihydro-1H,5'H-Spiro[cyclopenta[c]Pyran-7,2'-Furan]-4-Carboxylate

上下游产品

protoplumericin S,7R)-1c-β-D-glucopyranosyloxy-4'-((S)-1-hydroxy-ethyl)-5'-oxo-(4ar,7ac)-4a,7a-dihydro-1H,5'H-spiro[cyclopenta[c]pyran-7,2'-furan]-4-carboxylic acid(4aS,7R)-1c-β-D-glucopyranosyloxy-4'-((S)-1-hydroxy-ethyl)-5'-oxo-(4ar,7ac)-4a,7a-dihydro-1H,5'H-spiro[cyclopenta[c]pyran-7,2'-furan]-4-carboxylic acid 48H56O24C48H56O24 4'-O-hydroxy-6'-O-benzylidene triacetate plumieride

📜Plumeride Coumarate Glucoside置于硫酸体系中,化学反应 4.0H,反应生成 鸡蛋花甙
参考文献:Iridoids With Algicidal Properties From Allamanda Cathartica
标题:Iridoids With Algicidal Properties From Allamanda Cathartica
摘要:
DOI:10.1016/s0031-9422(00)80083-7

专利信息

专利号:US-4410710-A
优先权日:1981-09-25
标题 :Conversion of iridoids to prostaglandins
发明人：BERKOWITZ WILLIAM F; CHOUDHRY SATISH C; HRABIE JOSEPH A
权利人:UNIV CITY
摘要:Naturally occurring iridoids provide the starting material for a unique synthesis sequence to produce prostaglandin intermediates. The iridoid lactone is hydrogenated, converted to an acetal, and rings opened to introduce the carbonyl octenyl side chain in six steps. The intermediate can be converted to prostaglandin as previously demonstrated.