CAS: 3405-88-7; 2-((4-Chlorophenyl)Thio)Acetic Acid

该化合物是一种有机化合物,其特点是存在硫醚功能组和一个碳酸组,其特征是附于硫磺原子的一个4-氯苯组,该组与乙酸类有进一步的联系.该化合物通常是一种固体或晶体物质,因其生物活动而有可能在制药和农用化学物质中应用.氯苯组的存在可能会加强其脂性,影响其与生物系统的互动.此外,箱酸功能可以参与各种化学反应,例如酯化和恐吓.它通常在极地溶剂中的溶性是中度的,并可能由于碳酸组而表现出酸性.应当参考安全数据,以便处理和储存,如同任何化学物质一样,确保采取适当的防范措施.

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n-butyllithium diethyl ether 4-chlorophenyl methyl sulfide sodium mon°Chloroacetic acid 2-(4-chloro-phenylsulfonyl)acetic acid 4-Chlorophenylsulfenylacetic acid (4-chloro-phenylsulfanyl)-acetic acid 2-morpholin-4-yl-ethyl ester 2,2-dichloro-2-(p-chlorophenylthio)acetyl chloride

合成工艺路线路线简述

    📜苯硫基乙酸置于磺酰氯,氯化锑(V)体系中,用 氯苯 用作溶剂,化学反应生成(4-氯苯基硫酚)乙酸
    参考文献:Electrophilic Substitution Of The Benzenethiols. I. Halobenzene-And Halotoluenethiols1
    标题:Electrophilic Substitution Of The Benzenethiols. I. Halobenzene-And Halotoluenethiols1
    摘要:
    Doi:10.1021/jo01059A081

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    专利信息


    专利号:US-9217012-B2
    优先权日:2009-04-08
    标题 :Inhibitors of protein tyrosine phosphatases
    发明人：ZHANG ZHONG-YIN; ZHANG SHENG
    权利人:ZHANG ZHONG-YIN; ZHANG SHENG; UNIV INDIANA RES & TECH CORP
    摘要:Disclosed herein are compounds that selectively inhibit members of the PTP family of enzymes. Synthesized compounds demonstrated selective inhibition of TC-PTP. Also provided are methods of using the compounds and formulations containing the compounds. Also described is a fluorescence-tagged combinatorial library synthesis and screening method. And methods of using these compounds to effect enzyme activity both in cells and in vitro as well as method of using these compounds to treat diseases in human and animals.

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    主要参考文献

    参考标题:Derivatives Of Phenyl Tribromomethyl Sulfone As Novel Compounds With Potential Pesticidal Activity
    作者:Krzysztof M Borys,Maciej D Korzyński,Zbigniew Ochal
    摘要:And Fungicides. The Synthesis Of Tribromomethyl Phenyl Sulfone Derivatives As Novel Potential Pesticides Is Reported. The Title Sulfone Was Obtained By Following Three Different Synthetic Routes, Starting From 4-Chlorothiophenol Or 4-Halogenphenyl Methyl Sulfone. Products Of Its Subsequent Nitration Were Subjected To The S(N)Ar Reactions With Ammonia, Amines, Hydrazines And Phenolates To Give 2-Nitroaniline

    合成参考文献


    摘要:D. J. Pasto, D. McMillan and T. Murphy, J. Org. Chem. 30, 2688 (1965).
    摘要:L. D. Pettit, A. Royston, C. Sherrington and R. J. Whewell, J. Chem. Soc. (B) 1968, 588.
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