CAS: 2436-90-0; 3,7-Dimethylocta-1,6-Diene

该化合物是含有分子式C10H18的分链二极环.这种不饱和的碳氢化合物在1和6个位置以及3和7个位置的甲基替代成分中具有两个双键,有助于其独特的再活性和结构多功能.它作为有机合成中的宝贵中间体,特别是在生产梯子,芳香和特殊化学品方面.它的死环结构允许参与Diels-Alder反应和其他循环反应,而其分支则能增强稳定性和影响立体化学结果.该化合物作为单体或交叉连接剂在聚合化学中也很有用.其定义明确的结构确保了研究和工业应用的一贯性能.

结构式图片

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号41273-34-1 3,7-dimethyl°Ct... | CAS号105-87-3 乙酸香叶酯 | CAS号85217-72-7 (2E)-3,7-Dimeth... | CAS号141-12-8 乙酸橙花酯 | CAS号106-24-1 香叶醇; (E)-3,7-二甲... | CAS号85217-73-8 (Z)-3,7-dimethy... | CAS号106-25-2 橙花醇 | CAS号41144-01-8 3,7-dimethyl°Ct... | CAS号77085-97-3 (3,7-dimethyl°C... | CAS号53767-93-4 乙酸二氢月桂烯酯 | CAS号14576-08-0 4-(1-甲氧基-1-甲基乙基... | CAS号2492-22-0 2,6-二甲基-2-反式-6-辛二烯 | CAS号76343-94-7 红海海绵素 B | CAS号65733-16-6 S-(+)-甲基戊二烯 | CAS号58917-26-3 (S)-(+)-6-甲基-5-... | CAS号7540-51-4 (-)-beta-香茅醇 | CAS号18479-58-8 二氢月桂烯醇 | CAS号183202-73-5 Kendomycin | CAS号41890-92-0 甲氧基三甲基庚醇

合成工艺路线路线简述

  • 合成目标产物 Dihydromyrcene 主要起始原料 Geranyltriphenylphosphoniumbromide
  • (文献来源)合成步骤主要原料 Geranyltriphenylphosphoniumbromide
芳樟醇置于lithium Aluminium Tetrahydride,三氯化铝体系中,用 乙醚 用作溶剂,化学反应生成3,7-二甲基-1,6-辛二烯
参考文献:Hydrogenolyses With Chloroaluminum Hydrides. Iii. Allylic Alcohols
标题:Hydrogenolyses With Chloroaluminum Hydrides. Iii. Allylic Alcohols
摘要:
Doi:10.1021/jo01024A026

海关参考信息

专利信息


专利号:US-9126995-B2
优先权日:2011-11-08
标题:Method for catalytic asymmetric synthesis of optically active isoxazoline compound and optically active isoxazoline compound
发明人:TOYAMA KEN-ICHI; MORIYAMA YUJI; MATOBA KAZUTAKA; YAOSAKA MANABU; IKEDA EITATSU
权利人:NISSAN CHEMICAL IND LTD
摘要:There is provided a method for catalytic asymmetric synthesis of optically active isoxazoline compound and an optically active isoxazoline compound. A method for catalytic asymmetric synthesis of optically active isoxazoline compound of a formula (6) including reacting an α,β-unsaturated carbonyl compound of a formula (1) and a hydroxylamine in a solvent in the presence of a base by adding a chiral phase transfer catalyst. An optically active isoxazoline compound of a formula (13) that can be synthesized by the method.

专利号:US-2005130201-A1
优先权日:2003-10-14
标 题 :Splint-assisted enzymatic synthesis of polyribounucleotides
发明人:DERAS MICHAEL; PLEISS JEFFREY A; SCARINGE STEPHEN
权利人:DHARMACON INC
摘要:The present invention comprises methods and compositions for splint-assisted enzymatic synthesis of polyribonucleotides using an RNA polymerizing enzyme. The invention provides ligating ribonucleotides comprising ligating a donor RNA molecule to an acceptor RNA molecule in the presence of RNA ligase and a splint, wherein the donor RNA molecule is comprised of at least one nucleotide and a ligation linker moiety, the acceptor RNA molecule is comprised of at least one nucleotide and a ligation linker moiety and the splint is comprised of a polyribonucleotide. The invention also provides splints for use in splint-assisted enzymatic synthesis using an RNA polymerizing enzyme.

专利号:EP-1373548-B1
优先权日:2002-04-08
标 题 :Chemo-enzymatic synthesis of optically enriched rose-oxides
发明人:TANEJA SHUBASH CHANDRA; SETHI VIJAY KUMAR; KOUL SURRINDER; ANDOTRA SAMAR SINGH; QAZI GHULAM NABI
权利人:COUNCIL SCIENT IND RES
摘要:The present invention relates to a process for the synthesis of optically enriched dextro- and leavo-rotatory isomers of rose oxide from racemic citronellol.

专利号:US-7700654-B2
优先权日:2005-02-05
标 题:Isolation of N-butylbenzenesulfonamide, synthesis of benzenesulfonamide derivatives, and use of N-butylbenzenesulfonamide and benzenesulfonamide derivatives for treating benign prostatic hyperplasia and/or prostate carcinoma
发明人:HOFFMANN HANS-RAINER; MATUSCH RUDOLF; BANIAHMAD ARIA
权利人:LOHMANN THERAPIE SYST LTS
摘要:A process for isolating N-butylbenzenesulfonamide (NBBS) from biological material, the chemical synthesis of benzenesulfonamide derivatives, the use of NBBS and benzenesulfonamide derivatives for treating benign prostatic hyperplasia and/or prostate carcinoma, the production of medicaments for the treatment thereof, and the use of NBBS and benzenesulfonamide derivatives as a lead substance in the development of active substances for treating benign prostatic hyperplasia and/or prostate carcinoma are provided.

专利号:US-6734313-B2
优先权日:2000-10-20
标题 :Synthesis of spiro esters, spiro ortho carbonates, and intermediates
发明人:SEEMAYER ROBERT; LIANG JACK
权利人:BIOAVAILABILITY SYSTEMS LLC
摘要:Ortho esters and ortho carbonates can be produced by alkylating esters and carbonates with, for example, the hexafluorophosphate salt of a trialkyl oxonium ion. The spiro species are useful intermediates in the synthesis of complex organic molecules. Synthetic pathways for the production of medically active compounds incorporates spiro ortho esters. Anti-first-pass effect materials are produced in high yield utilizing a synthetic strategy incorporating cyclic ortho ester intermediates.

专利号:US-6613918-B1
优先权日:2000-10-20
标 题 :Synthesis of spiro ortho esters, spiro ortho carbonates, and intermediates
发明人:SEEMAYER ROBERT; LIANG JACK
权利人:BIOAVAILABILITY SYSTEMS LLC
摘要:Ortho esters and ortho carbonates can be produced by alkylating esters and carbonates with, for example, the hexafluorophosphate salt of a trialkyl oxonium ion. The spiro species are useful intermediates in the synthesis of complex organic molecules. Synthetic pathways for the production of medically active compounds incorporates spiro ortho esters. Anti-first-pass effect materials are produced in high yield utilizing a synthetic strategy incorporating cyclic ortho ester intermediates.
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主要参考文献

参考标题:A Novel Rhodium-Catalyzed Domino-Hydroformylation-Reaction For The Synthesis Of Sulphonamides
作者:Kaiwu Dong,Xianjie Fang,Ralf Jackstell,Matthias Beller
摘要:An Efficient And Highly Selective Domino Hydroformylation-Reductive Sulphonamidation Reaction Has Been Developed For The Synthesis Of Sulphonamides Using A Rhodium/phosphine Catalyst.

合成参考文献


参考文献:10.1016/j.plaphy.2011.06.008
摘要:Lawo NC, Weingart GJF, Schuhmacher R, Forneck A. The volatile metabolome of grapevine roots: First insights into the metabolic response upon phylloxera attack. Plant Physiology and Biochemistry. 2011 Sep;49(9):1059–63. doi: 10.1016/j.plaphy.2011.06.008.
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