CAS: 2197-57-1; 2,3-Dimethylnaphthalene-1,4-Dione

该化合物是一种替代环丙酮衍生物,在有机合成和材料科学中具有显著应用,其结构以二氢甲苯核心为特征,在2和3个位置有甲基替代成分,增强了稳定性,同时保留选择性变异的回动性.该化合物是合成多环芳烃系统和功能化五角星的多功能中间体,在染色化学,制药和光电子材料中很有价值.其硬性,同质框架有助于可预测的再活动模式,促进受控的功能化.该产品的特点通常是高纯度,确保研究和工业应用中的再生性.建议,由于对氧化的潜在敏感性,在惰性条件下进行适当处理.

结构式图片

欧盟法规

C&L通报

上下游产品

diazomethane 2-methyl-1,4-naphthohydroquinone methanol 1a,7a-dimethylnaphtho[2,3-b]oxirene-2,7(1aH,7aH)-dione 2-(2,2-diphenyl-ethyl)-3-methyl-[1,4]naphthoquinone H-naphthalen-1-one4-hydroxy-2,3-dimethyl-4-phenyl-4H-naphthalen-1-one 2,3-dimethyl-1,2-diphenyl-1,2-dihydro-naphthalene-1,4-diol 2,3-dimethyl-1,4-diphenyl-1,4-dihydro-naphthalene-1,4-diol

合成工艺路线路线简述

  • 合成目标产物 2,3-Dimethyl-1,4-Naphthoquinone 主要起始原料 Menadione And Dimethyl Sulfoxide
  • (文献来源)合成步骤主要原料 Menadione 和 Dimethyl Sulfoxide
📜甲基苯醌置于lead(Iv) Acetate,盐酸,溶剂黄146,苯体系中,化学反应生成2,3-二甲基萘-1,4-二酮
参考文献:Alkylation Of α-Naphthoquinones With Esters Of Tetravalent Lead
标题:Alkylation Of α-Naphthoquinones With Esters Of Tetravalent Lead
摘要:
Doi:10.1021/ja01261A013

海关参考信息

专利信息


专利号:US-7834215-B2
优先权日:2005-03-23
标题:Unsymmetrically substituted phospholane catalysts
发明人:HOLZ JENS; BOERNER ARMIN; ZAYAS VARGAS ODALYS ESPERANZA; ALMENA PEREA JUAN JOSE; MONSEES AXEL; KADYROV RENAT; RIERMEIER THOMAS
权利人:EVONIK DEGUSSA GMBH
摘要:The present invention is based on new ligand systems of the general formula (I). These ligand systems can be used advantageously in transition metal-catalyzed asymmetric syntheses. Likewise encompassed are the transition metal complexes thus prepared, a process for preparing the ligands and the use of the complexes in asymmetric synthesis.

专利号:CN-120607438-A
优先权日:2025-06-24
标题 :Synthesis method of 2, 3-dimethyl-1, 4-dihydronaphthalene-1, 4-dione

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


摘要:Hitomi, Y.; Arakawa, K., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 2, 297.
参考文献:10.1046/j.1432-1033.2002.02839.x|10.1046/j.1432-1327.2002.02839.x
摘要:Mander GJ, Duin EC, Linder D, Stetter KO, Hedderich R. Purification and characterization of a membrane‐bound enzyme complex from the sulfate‐reducing archaeon Archaeoglobus fulgidus related to heterodisulfide reductase from methanogenic archaea. European Journal of Biochemistry. 2002 Apr;269(7):1895–904. doi: 10.1046/j.1432-1033.2002.02839.x.
参考文献:10.1046/j.1432-1033.2002.02842.x|10.1046/j.1432-1327.2002.02842.x
摘要:Biel S, Simon J, Gross R, Ruiz T, Ruitenberg M, Kröger A. Reconstitution of coupled fumarate respiration in liposomes by incorporating the electron transport enzymes isolated from Wolinella succinogenes. European Journal of Biochemistry. 2002 Apr;269(7):1974–83. doi: 10.1046/j.1432-1033.2002.02842.x.
参考文献:10.1023/b:jobb.0000019600.36757.8c
摘要:Kletzin A, Urich T, Müller F, Bandeiras TM, Gomes CM. Dissimilatory Oxidation and Reduction of Elemental Sulfur in Thermophilic Archaea. Journal of Bioenergetics and Biomembranes. 2004 Feb;36(1):77–91. doi: 10.1023/b:jobb.0000019600.36757.8c.
参考文献:10.1073/pnas.83.7.2056
摘要:Weiner JH, Cammack R, Cole ST, Condon C, Honoré N, Lemire BD, Shaw G. A mutant of Escherichia coli fumarate reductase decoupled from electron transport. Proc. Natl. Acad. Sci. U.S.A. 1986 Apr;83(7):2056–60. doi: 10.1073/pnas.83.7.2056.
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