CAS: 1068-69-5; Tris(Trimethylsilyl)Methane

该化合物是一种高度多用途有机硅化合物,其特征是三甲基硅基(TMS)组,附在甲烷中央核心中,具有特殊的消毒体和电饱和特性,在合成化学中具有价值,特别是为保护反应中间体或修改分子结构而具有价值,其牢固的硅-碳结层能增强热和化学稳定性,而TMS组则能促进非极溶剂溶解性.该化合物经常用于有机金属反应,催化和作为高级硅基材料的前体.其可预测的反应性和易处理性使需要精确控制分子设计的研究人员更倾向于选择.

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相似化合物

2117-28-4

欧盟法规

ECHA物质C&L通报

上下游产品

tetrachloromethane chloro-trimethyl-silane chloroform Bromoform1,1-bis(trimethylsilyl)ethylene 1,1-diphenyl-2-trimethylsilylethene ((Z)-3,3-Dimethyl-2-phenyl-but-1-enyl)-trimethyl-silane [Chloro-(tris-trimethylsilanyl-methyl)-silanyl]-benzene

合成工艺路线路线简述

    📜Tribromo[tris(Trimethylsilyl)Methyl]Silane置于naphthalen-1-Yl-Lithium体系中,用 四氢呋喃 用作溶剂,化学反应 27.0H,反应生成三(三甲代甲硅烷基)甲烷
    参考文献:室温下在thf溶液中稳定的卤代亚甲硅烷基.
    标题:室温下在thf溶液中稳定的卤代亚甲硅烷基.
    摘要:
    Doi:10.1021/ja016309F

    专利信息


    专利号:US-2002034829-A1
    优先权日:2000-03-24
    标题 :Combinatorial synthesis and analysis of metal-ligand compositions using soluble metal precursors
    发明人:HALL KEITH; MURPHY VINCE; LAPOINTE ANNE M; VAN BEEK JOHANNES A M; DIAMOND GARY M
    摘要:The present invention relates to a process of conducting research using combinatorial techniques wherein metal-ligand compositions are synthesized and screened for reactivity in reactions of interest, particularly metal-ligand compounds which are suitable for use as catalysts. In the process, an array of different metal-ligand compositions is prepared by delivering a dissolved, soluble metal precursor and a metal-binding ligand to each reaction vessel or well in the array, where they may optionally be combined with an activator and/or other additives. The resulting metal-ligand composition in each vessel is then screened for reactivity in a chemical reaction of interest, particularly for catalytic activity in a polymerization reaction.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Oshima, K., Science of Synthesis, (2002) 4, 724.
    摘要:Streitwieser, A.; Xie, L., Science of Synthesis, (2006) 8, 1518.
    摘要:Lindenschmidt, A., Science of Synthesis, (2007) 25, 262.
    摘要:Drabowicz, J.; Kiełbasiński, P.; Łyżwa, P.; Mikołajczyk, M., Science of Synthesis, (2008) 39, 549.
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