专利号:US-2024075466-A1 优先权日:2021-04-09 标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites 发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE 权利人:UMICORE AG & CO KG 摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.
专利号:US-12221452-B2 优先权日:2017-10-04 标题:Synthesis of cantharidin 发明人:DAVIDSON MATTHEW GENE; EKLOV BRIAN MATTHEW; WUTS PETER; LOERTSCHER BRAD MELVIN; SCHOW STEVEN R 权利人:VERRICA PHARMACEUTICALS INC 摘要:The invention provides synthetic methods for the preparation of cantharidin and analogs thereof. In one aspect, the invention provides an improved Diels-Alder cycloaddition to generate a key intermediate en route to cantharidin and analogs thereof. In certain embodiments, the new Diels-Alder reaction involves reacting Compound (2) in the presence of furan, and in the absence of acid or increased pressure, in an aprotic polar solvent with slight warming, to yield Compound (1) in favorable yield and exo-endo ratio. In another aspect, the invention also provides a new Diels-Alder reaction between compounds of Formula (III) and furan to yield compounds of Formula (IV), which can then be transformed into cantharidin or analogs thereof. In yet another aspect, the invention describes a new palladium-mediated carbonylation providing another key intermediate en route to cantharidin and analogs thereof. In addition to synthetic methods, present invention also provides compounds (i.e., intermediates) useful in the synthesis of cantharidin and analogs thereof. Compounds provided herein may have biological activity, and therefore may be used in the treatment of diseases or conditions (e.g., infectious diseases and skin conditions).
专利号:US-9183993-B2 优先权日:2014-01-10 标 题 :One-pot synthesis of Nb2O5-doped TiO2 nanoparticles 发明人:FENG SHIEN-PING; SU HAIJUN; CHANG YA-HUEI; HUANG YU-TING; HAU NGA YU; ZHAI PENG 权利人:NANO & ADVANCED MATERIALS INST LTD 摘要:A one-pot synthesis of Nb 5+ -doped TiO 2 nanoparticles (NPs) with low cost and high efficiency for dye sensitized solar cells (DSSCs) is disclosed in the present invention. The Nb 5+ -doped TiO 2 NPs with Nb dopants of 0Ëœ5 mol % are prepared by directly mixing TiO 2 slurry with Nb 2 O 5 gel obtained by UV treatment of a mixture of NbCl 5 powder, ethanol and water in a certain ratio, following by heat treatment without using hydrothermal method. The as-prepared NPs exhibit well-crystallized pure anatase TiO 2 phase with uniform particle distribution. The incorporation of Nb 5+ leads to a stronger and broader light absorption in visible light range and a decrease of band gap with increasing Nb dopant content, which enhances the efficiencies of light-harvesting and electron injection and suppresses the charge recombination. The present method provides a simple and cost-effective mass-production route to synthesize n-type metallic ion doped TiO 2 nanoparticles as excellent photoanode materials.
专利号:US-9050776-B2 优先权日:2012-06-28 标 题 :Method of synthesis of high dispersed spherical Y or Nb doped lithium titanate oxide using titanium tetrachloride and lithium hydroxide 发明人:CHOI BYUNG HYUN; JI MI JUNG; KIM EUN KYUNG; KWON YOUNG JIN; JUNG SUNG HUN; AN YONG TAE 权利人:CHOI BYUNG HYUN; JI MI JUNG; KIM EUN KYUNG; KWON YOUNG JIN; JUNG SUNG HUN; AN YONG TAE; KOREA INST CERAMIC ENG & TECH 摘要:The present disclosure relates to a method of synthesis of Lithium Titanate Oxide used for a cathode of Lithium ion battery, the method comprising: (A) diluting TiCl 4 with TiOCl 2 ; (B) adding YCl 3 or NbCl 5 at the rate of 0.1Ëœ2 mol % to Ti(mol); (C) forming a complex salt by dissolving to put at least one selected from a group consisting of Hydroxy propyl cellulose or Polyethylene glycol in a solvent, the Hydroxy propyl cellulose being a complexing agent and being a dispersing agent as well, whereas the Polyethylene glycol being a dispersing agent; (D) synthesizing a titanium precursor by adding an aqueous ammonia solution; (E) preparing Y or Nb doped titanium dioxide(TiO 2 ) powder by heat-treating the synthetic product in a temperature of 500Ëœ700° C.; and (F) mixing the Y or Nb doped TiO 2 powder with LiOH.H 2 O and heat-treating the mixture in a temperature of 800Ëœ900° C.
专利号:US-8835661-B2 优先权日:2011-08-26 标 题:Process for the synthesis of C11 and C12 omega-aminoalkanoic acid esters comprising a nitrilation step 发明人:COUTURIER JEAN-LUC; DUBOIS JEAN-LUC 权利人:COUTURIER JEAN-LUC; DUBOIS JEAN-LUC; ARKEMA FRANCE 摘要:A process for the synthesis of C11 and C12 ω-amino-alkanoic acid esters including a step of continuous nitrilation in the gas phase or in a mixed gas-liquid phase, a step of metathesis and a step of reduction by hydrogenation, using, as raw material, C10 and C11 ω-alkenoic acid esters.
专利号:WO-2005085390-A1 优先权日:2004-03-09 标 题:Cobalt catalyst for the synthesis of fischer-tropsch, catalyst support, processes for the preparation of support and catalyst and the use of the catalyst 发明人:DOS SANTOS ANA CARLOTA BELIZAR; PEREIRA ANTONIO TELHADO; SOUSA-AGUIAR EDUARDO FALABELLA; MORAES JORGE LUIZ; DE OLIVEIRA KENSLEY ALVES; SUGAYA MARCOS DE FREITAS; SCHMAL MARTIN; MONTEIRO ROBSON DE SOUZA; VICENTINI VALERIA PERFEITO 权利人:CBMM SA; OXITENO SA IND E COMERCIO; PETROLEO BRASILEIRO SA; DOS SANTOS ANA CARLOTA BELIZAR; PEREIRA ANTONIO TELHADO; SOUSA-AGUIAR EDUARDO FALABELLA; MORAES JORGE LUIZ; DE OLIVEIRA KENSLEY ALVES; SUGAYA MARCOS DE FREITAS; SCHMAL MARTIN; MONTEIRO ROBSON DE SOUZA; VICENTINI VALERIA PERFEITO 摘要:The present invention is related to a cobalt catalyst supported on high-surface area niobium pentoxide for Fischer-Tropsch synthesis, the support of this catalyst which is a niobium pentoxide (Nb2O5) with a BET surface area in the range of 30 to 160 m2.g-1, the process for the preparation of the high-surface area support of niobium pentoxide by calcination of a hydrated niobium oxide or by synthesis from either organic or inorganic niobium precursors, a process for the preparation of said catalyst, and the use of the catalyst for the Fischer-Tropsch synthesis to obtain hydrocarbons with carbon atoms equal or higher than five containing specially linear paraffins in the diesel fuel range, and without a significant formation of light hydrocarbons, olefins, aromatics and oxygenated compounds.