CAS: 80226-00-2; (2R,3R)-2,3-Bis(3-Hydroxybenzyl)Butane-1,4-Diol

该化合物是一种自然产生的化合物,被归类为离子南,是一种在各种植物中发现的多酚化合物,特别是种子,整粒谷物和蔬菜中发现的多酚化合物,以其潜在的健康惠益而著称,包括抗氧化性特性和荷尔蒙调节中可能发挥的作用,特别是在雌激素代谢中; 肠道二醇通过饮食乳腺的新陈代谢(如在松树中发现的乳腺)在人体中产生; 其化学结构具有二苯并聚氨酯骨骼,有助于其生物活动; 研究表明,肠道二醇可能对癌症预防和心血管健康产生影响,尽管还需要进一步研究,以充分了解其机制和功效; 此外,肠道对营养学和功能食品领域很感兴趣,因为其潜在的健康保护性特性. 与许多植物化学一样,肠道生物利用率和作用可以因个别饮食习惯和肠道微生物组成而有所不同.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

ECHA物质C&L通报

上下游产品

Acetic acid 3-[(3S,4S)-4-(3-acetoxy-benzyl)-2,5-dioxo-tetrahydro-furan-3-ylmethyl]-phenyl ester trans-2,3-bis[(3-hydroxyphenyl)methyl]-γ-butyrolactone 3-benzyloxybenzaldehyde bis(phenylthio) acetal butyrolactone(+/-)-trans-2-(3-benzyloxybenzyl)-3-3-benzyloxy-α,α-bis(phenylthio)benzylbutyrolactone

合成工艺路线路线简述

  • 78473-71-9 = 80226-00-2
    反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran
    标题:Oxidative Metabolism Of The Mammalian Lignans Enterolactone And Enterodiol By Rat,Pig,And Human Liver Microsomes
    作者:Jacobs,Eric; Et Al
    参考文献:Journal Of Agricultural And Food Chemistry 日期:1999 卷标:47(3) 页码:1071-1077]

    77756-20-8 = 80226-00-2
    反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran
    标题:Enantioselective Synthesis Of Natural Dibenzylbutyrolactone Lignans (-)-Enterolactone,(-)-Hinokinin,(-)-Pluviatolide,(-)-Enterodiol,And Furofuran Lignan (-)-Eudesmin Via Tandem Conjugate Addition To γ-Alkoxybutenolides
    作者:Van Oeveren,Arjan; Et Al
    参考文献:Journal Of Organic Chemistry 日期:1994 卷标:59(20) 页码:5999-6007]

    77756-20-8 = 80226-00-2
    反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; 1 H,Rt; Rt -> 50 °C; 2 H,50 °C1.2 Reagents: Hydrochloric Acid Solvents: Water
    标题:Synthesis Of (-)-Matairesinol,(-)-Enterolactone,And (-)-Enterodiol From The Natural Lignan Hydroxymatairesinol
    作者:Eklund,Patrik; Et Al
    参考文献:Organic Letters 日期:2003 卷标:5(4) 页码:491-493]

    1700-31-8 + 497-23-4 = 80226-00-2
    反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane1.2 Solvents: Tetrahydrofuran1.3 Reagents: 1,3-Dimethyl-2-Imidazolidinone Solvents: Tetrahydrofuran1.4 Reagents: Water1.5 Reagents: Nickel Solvents: Ethanol2.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran
    标题:Oxidative Metabolism Of The Mammalian Lignans Enterolactone And Enterodiol By Rat,Pig,And Human Liver Microsomes
    作者:Jacobs,Eric; Et Al
    参考文献:Journal Of Agricultural And Food Chemistry 日期:1999 卷标:47(3) 页码:1071-1077]

    14874-70-5 + 26172-10-1 = 80226-00-2
    反应条件:1.1 Reagents: 2,6-Lutidine,Sodium Iodide Catalysts: 4-Imidazolidinone,2,2,3-Trimethyl-5-(Phenylmethyl)-,Hydrochloride (1:1),(5S)- Solvents: Dimethylacetamide,Water; 16 H,0 °C1.2 Reagents: Sodium Borohydride Solvents: Methanol,Dichloromethane; 15 Min,0 °C2.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; 1 H,0 °C2.2 Solvents: Water; 0 °C
    标题:Catalytic Photochemical Enantioselective α-Alkylation With Pyridinium Salts
    作者:Yetra,Santhivardhana Reddy; Et Al
    参考文献:Chemical Science 日期:2023 卷标:14(3) 页码:586-592]

    = 80226-00-2
    反应条件:1.1 Reagents: Nickel Dichloride Solvents: Methanol,Tetrahydrofuran1.2 Reagents: Sodium Borohydride1.3 Reagents: Potassium Hydroxide,Sodium Borohydride2.1 Reagents: Hydrogen,Palladium,Carbon Solvents: Ethyl Acetate3.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran
    标题:Enantioselective Synthesis Of Natural Dibenzylbutyrolactone Lignans (-)-Enterolactone,(-)-Hinokinin,(-)-Pluviatolide,(-)-Enterodiol,And Furofuran Lignan (-)-Eudesmin Via Tandem Conjugate Addition To γ-Alkoxybutenolides
    作者:Van Oeveren,Arjan; Et Al
    参考文献:Journal Of Organic Chemistry 日期:1994 卷标:59(20) 页码:5999-6007]

    1700-31-8 + 77934-87-3 = 80226-00-2
    反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane1.2 Solvents: Tetrahydrofuran1.3 Reagents: N,N,N′,N′-Tetramethylethylenediamine2.1 Reagents: Nickel Dichloride Solvents: Methanol,Tetrahydrofuran2.2 Reagents: Sodium Borohydride2.3 Reagents: Potassium Hydroxide,Sodium Borohydride3.1 Reagents: Hydrogen,Palladium,Carbon Solvents: Ethyl Acetate4.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran
    标题:Enantioselective Synthesis Of Natural Dibenzylbutyrolactone Lignans (-)-Enterolactone,(-)-Hinokinin,(-)-Pluviatolide,(-)-Enterodiol,And Furofuran Lignan (-)-Eudesmin Via Tandem Conjugate Addition To γ-Alkoxybutenolides
    作者:Van Oeveren,Arjan; Et Al
    参考文献:Journal Of Organic Chemistry 日期:1994 卷标:59(20) 页码:5999-6007]

    174732-96-8 = 80226-00-2
    反应条件:1.1 Reagents: 1-Ethyl-3-(3′-Dimethylaminopropyl)Carbodiimide Hydrochloride Catalysts: 4-(Dimethylamino)Pyridine Solvents: Dichloromethane; 4 H,0 - 23 °C1.2 Reagents: Hydrochloric Acid Solvents: 1,4-Dioxane,Water; 6 H,0 - 23 °C2.1 Reagents: Triethylamine Solvents: Dichloromethane; 30 Min,23 °C2.2 Reagents: Acetic Acid Solvents: Dichloromethane; 12 H,23 °C3.1 Reagents: 2,6-Lutidine,Sodium Iodide Catalysts: 4-Imidazolidinone,2,2,3-Trimethyl-5-(Phenylmethyl)-,Hydrochloride (1:1),(5S)- Solvents: Dimethylacetamide,Water; 16 H,0 °C3.2 Reagents: Sodium Borohydride Solvents: Methanol,Dichloromethane; 15 Min,0 °C4.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; 1 H,0 °C4.2 Solvents: Water; 0 °C
    标题:Catalytic Photochemical Enantioselective α-Alkylation With Pyridinium Salts
    作者:Yetra,Santhivardhana Reddy; Et Al
    参考文献:Chemical Science 日期:2023 卷标:14(3) 页码:586-592]

    580-72-3 = 80226-00-2
    反应条件:1.1 Reagents: 2,6-Lutidine Solvents: Dichloromethane; 48 H,0 °C2.1 Reagents: Triethylamine Catalysts: Formic Acid,1,3-Bis(Diphenylphosphino)Propane,Dichlorobis(Triphenylphosphine)Palladium Solvents: Dimethylformamide; 85 °C3.1 Reagents: Boron Tribromide Solvents: Dichloromethane; Rt -> -10 °C; 15 Min,-10 °C; 6 H,-10 °C; -10 °C -> Rt; 12 H,Rt4.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; 1 H,Rt; Rt -> 50 °C; 2 H,50 °C4.2 Reagents: Hydrochloric Acid Solvents: Water
    标题:Synthesis Of (-)-Matairesinol,(-)-Enterolactone,And (-)-Enterodiol From The Natural Lignan Hydroxymatairesinol
    作者:Eklund,Patrik; Et Al
    参考文献:Organic Letters 日期:2003 卷标:5(4) 页码:491-493]

    77756-20-8 = 80226-00-2
    反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; 1 H,0 °C1.2 Solvents: Water; 0 °C
    标题:Catalytic Photochemical Enantioselective α-Alkylation With Pyridinium Salts
    作者:Yetra,Santhivardhana Reddy; Et Al
    参考文献:Chemical Science 日期:2023 卷标:14(3) 页码:586-592]

    = 80226-00-2
    反应条件:1.1 Reagents: Hydrogen Solvents: Methanol,Water; 6 H,1 Atm,Rt
    标题:Remarkably Facile Borane-Promoted,Rhodium-Catalyzed Asymmetric Hydrogenation Of Tri- And Tetrasubstituted Alkenes
    作者:Shoba,Veronika M.; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2017 卷标:139(16) 页码:5740-5743]

    = 80226-00-2
    反应条件:1.1 Reagents: Hydrogen,Palladium,Carbon Solvents: Ethyl Acetate2.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran
    标题:Enantioselective Synthesis Of Natural Dibenzylbutyrolactone Lignans (-)-Enterolactone,(-)-Hinokinin,(-)-Pluviatolide,(-)-Enterodiol,And Furofuran Lignan (-)-Eudesmin Via Tandem Conjugate Addition To γ-Alkoxybutenolides
    作者:Van Oeveren,Arjan; Et Al
    参考文献:Journal Of Organic Chemistry 日期:1994 卷标:59(20) 页码:5999-6007]

    = 80226-00-2
    反应条件:1.1 Reagents: Tetrabutylammonium Iodide,Boron Trichloride Solvents: Dichloromethane; -78 °C; 5 Min,-78 °C; -78 °C -> Rt; Overnight,Rt1.2 Reagents: Water; 0 °C2.1 Reagents: Hydrogen Solvents: Methanol,Water; 6 H,1 Atm,Rt
    标题:Remarkably Facile Borane-Promoted,Rhodium-Catalyzed Asymmetric Hydrogenation Of Tri- And Tetrasubstituted Alkenes
    作者:Shoba,Veronika M.; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2017 卷标:139(16) 页码:5740-5743]

    = 80226-00-2
    反应条件:1.1 Reagents: Chlorotrimethylsilane,Lithium Bis(Trimethylsilyl)Amide Solvents: Tetrahydrofuran; 0 °C -> 23 °C; 16 H,23 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; 30 Min,23 °C2.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; 1 H,0 °C2.2 Solvents: Water; 0 °C
    标题:Catalytic Photochemical Enantioselective α-Alkylation With Pyridinium Salts
    作者:Yetra,Santhivardhana Reddy; Et Al
    参考文献:Chemical Science 日期:2023 卷标:14(3) 页码:586-592]

    80704-91-2 = 80226-00-2
    反应条件:1.1 Reagents: Boron Tribromide Solvents: Dichloromethane; Rt -> -10 °C; 15 Min,-10 °C; 6 H,-10 °C; -10 °C -> Rt; 12 H,Rt2.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; 1 H,Rt; Rt -> 50 °C; 2 H,50 °C2.2 Reagents: Hydrochloric Acid Solvents: Water
    标题:Synthesis Of (-)-Matairesinol,(-)-Enterolactone,And (-)-Enterodiol From The Natural Lignan Hydroxymatairesinol
    作者:Eklund,Patrik; Et Al
    参考文献:Organic Letters 日期:2003 卷标:5(4) 页码:491-493]

    = 80226-00-2
    反应条件:1.1 Catalysts: Rhodium(1+),Bis[(2,3,5,6-η)-Bicyclo[2.2.1]Hepta-2,5-Diene]-,Tetrafluoroborate(...,Dinaphtho[2,1-D:1′,2′-F][1,3,2]Dioxaphosphepin-4-Amine,2,6-Dimethyl-N-Phenyl-N-... Solvents: Tetrahydrofuran; 1 H,Rt1.2 Reagents: Methanol,Pinacolborane Solvents: Tetrahydrofuran; Rt; 12 H,Rt2.1 Reagents: Tetrabutylammonium Iodide,Boron Trichloride Solvents: Dichloromethane; -78 °C; 5 Min,-78 °C; -78 °C -> Rt; Overnight,Rt2.2 Reagents: Water; 0 °C3.1 Reagents: Hydrogen Solvents: Methanol,Water; 6 H,1 Atm,Rt
    标题:Remarkably Facile Borane-Promoted,Rhodium-Catalyzed Asymmetric Hydrogenation Of Tri- And Tetrasubstituted Alkenes
    作者:Shoba,Veronika M.; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2017 卷标:139(16) 页码:5740-5743]

    14874-70-5 + 15959-35-0 = 80226-00-2
    反应条件:1.1 Reagents: Triethylamine Solvents: Dichloromethane; 30 Min,23 °C1.2 Reagents: Acetic Acid Solvents: Dichloromethane; 12 H,23 °C2.1 Reagents: 2,6-Lutidine,Sodium Iodide Catalysts: 4-Imidazolidinone,2,2,3-Trimethyl-5-(Phenylmethyl)-,Hydrochloride (1:1),(5S)- Solvents: Dimethylacetamide,Water; 16 H,0 °C2.2 Reagents: Sodium Borohydride Solvents: Methanol,Dichloromethane; 15 Min,0 °C3.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; 1 H,0 °C3.2 Solvents: Water; 0 °C
    标题:Catalytic Photochemical Enantioselective α-Alkylation With Pyridinium Salts
    作者:Yetra,Santhivardhana Reddy; Et Al
    参考文献:Chemical Science 日期:2023 卷标:14(3) 页码:586-592]

    = 80226-00-2
    反应条件:1.1 Reagents: Triethylamine Catalysts: Formic Acid,1,3-Bis(Diphenylphosphino)Propane,Dichlorobis(Triphenylphosphine)Palladium Solvents: Dimethylformamide; 85 °C2.1 Reagents: Boron Tribromide Solvents: Dichloromethane; Rt -> -10 °C; 15 Min,-10 °C; 6 H,-10 °C; -10 °C -> Rt; 12 H,Rt3.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; 1 H,Rt; Rt -> 50 °C; 2 H,50 °C3.2 Reagents: Hydrochloric Acid Solvents: Water
    标题:Synthesis Of (-)-Matairesinol,(-)-Enterolactone,And (-)-Enterodiol From The Natural Lignan Hydroxymatairesinol
    作者:Eklund,Patrik; Et Al
    参考文献:Organic Letters 日期:2003 卷标:5(4) 页码:491-493]

    = 80226-00-2
    反应条件:1.1 Reagents: N-Hydroxyphthalimide,Triphenylphosphine,Diisopropyl Azodicarboxylate Solvents: Tetrahydrofuran; Rt; 3 H,Rt1.2 Reagents: Hydrazine Hydrate (1:1); Rt; 30 Min,Rt1.3 1 H,Rt2.1 Catalysts: Rhodium(1+),Bis[(2,3,5,6-η)-Bicyclo[2.2.1]Hepta-2,5-Diene]-,Tetrafluoroborate(...,Dinaphtho[2,1-D:1′,2′-F][1,3,2]Dioxaphosphepin-4-Amine,2,6-Dimethyl-N-Phenyl-N-... Solvents: Tetrahydrofuran; 1 H,Rt2.2 Reagents: Methanol,Pinacolborane Solvents: Tetrahydrofuran; Rt; 12 H,Rt3.1 Reagents: Tetrabutylammonium Iodide,Boron Trichloride Solvents: Dichloromethane; -78 °C; 5 Min,-78 °C; -78 °C -> Rt; Overnight,Rt3.2 Reagents: Water; 0 °C4.1 Reagents: Hydrogen Solvents: Methanol,Water; 6 H,1 Atm,Rt
    标题:Remarkably Facile Borane-Promoted,Rhodium-Catalyzed Asymmetric Hydrogenation Of Tri- And Tetrasubstituted Alkenes
    作者:Shoba,Veronika M.; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2017 卷标:139(16) 页码:5740-5743]

    1700-37-4 = 80226-00-2
    反应条件:1.1 Reagents: Aluminum Chloride Solvents: Dichloromethane2.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane2.2 Solvents: Tetrahydrofuran2.3 Reagents: N,N,N′,N′-Tetramethylethylenediamine3.1 Reagents: Nickel Dichloride Solvents: Methanol,Tetrahydrofuran3.2 Reagents: Sodium Borohydride3.3 Reagents: Potassium Hydroxide,Sodium Borohydride4.1 Reagents: Hydrogen,Palladium,Carbon Solvents: Ethyl Acetate5.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran
    标题:Enantioselective Synthesis Of Natural Dibenzylbutyrolactone Lignans (-)-Enterolactone,(-)-Hinokinin,(-)-Pluviatolide,(-)-Enterodiol,And Furofuran Lignan (-)-Eudesmin Via Tandem Conjugate Addition To γ-Alkoxybutenolides
    作者:Van Oeveren,Arjan; Et Al
    参考文献:Journal Of Organic Chemistry 日期:1994 卷标:59(20) 页码:5999-6007]

    1700-37-4 = 80226-00-2
    反应条件:1.1 Reagents: Sodium Borohydride Solvents: Methanol,Dichloromethane1.2 Reagents: Phosphorus Tribromide Solvents: Diethyl Ether2.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane2.2 Solvents: Tetrahydrofuran2.3 Reagents: N,N,N′,N′-Tetramethylethylenediamine3.1 Reagents: Nickel Dichloride Solvents: Methanol,Tetrahydrofuran3.2 Reagents: Sodium Borohydride3.3 Reagents: Potassium Hydroxide,Sodium Borohydride4.1 Reagents: Hydrogen,Palladium,Carbon Solvents: Ethyl Acetate5.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran
    标题:Enantioselective Synthesis Of Natural Dibenzylbutyrolactone Lignans (-)-Enterolactone,(-)-Hinokinin,(-)-Pluviatolide,(-)-Enterodiol,And Furofuran Lignan (-)-Eudesmin Via Tandem Conjugate Addition To γ-Alkoxybutenolides
    作者:Van Oeveren,Arjan; Et Al
    参考文献:Journal Of Organic Chemistry 日期:1994 卷标:59(20) 页码:5999-6007
📜Hydroxymatairesinol置于bis-Triphenylphosphine-Palladium(II) Chloride,Palladium On Activated Charcoal Lithium Aluminium Tetrahydride,甲酸,Lutidine,1,3-双(二苯基膦)丙烷,氢气,三溴化硼,三乙胺体系中,用 四氢呋喃,二氯甲烷,1,2-二氯乙烷,N,N-二甲基甲酰胺 作为反应溶剂,-10.0~85.0 °C,800.01 Kpa 条件下,反应 96.0H,反应生成 肠二醇
参考文献:Synthesis Of (−)-Matairesinol,(−)-Enterolactone,And (−)-Enterodiol From The Natural Lignan Hydroxymatairesinol
标题:Synthesis Of (−)-Matairesinol,(−)-Enterolactone,And (−)-Enterodiol From The Natural Lignan Hydroxymatairesinol
摘要:[graphics]We Describe Here A Four-Step Semisynthetic Method For The Preparation Of Enantiomerically Pure (-)-Enterolactone Starting From The Readily Available Lignan Hydroxymatairesinol From Norway Spruce (Picea Abies). Hydroxymatairesinol Was First Hydrogenated To Matairesinol. Matairesinol Was Esterified To Afford The Matairesinyl 4,4'-Bistriflate,Which Was Deoxygenated By Palladium-Catalyzed Reduction To 3,3'-Dimethylenterolactone. Demethylation Of 3,3'-Dimethylenterolactone And Reduction With Lialh4 Yielded (-)-Enterolactone And (-)-Enterodiol,Respectively.
DOI:10.1021/ol0273598

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专利信息


专利号:US-2012202778-A1
优先权日:2009-07-15
标题 :Use of at least one omega-3 fatty acid and of at least one polyphenol for the endogenous synthesis of eicosapentanoic acid and docosahexanoic acid

专利号:WO-2004069774-A2
优先权日:2003-02-04
标题 :Synthesis of 13c-labelled estrogen analogues

专利号:CN-106591390-B
优先权日:2016-12-15
标题 :A method for enzymatic cascade synthesis of pinoresin by self-scavenging H2O2

专利号:JP-2009240191-A
优先权日:2008-03-31
标题 :Enhanced expression of lignans and lignin synthesis genes by light irradiation

专利号:CN-106591390-A
优先权日:2016-12-15
标题:Pinoresinol enzyme-cascade synthesis method capable of automatically clearing H2O2

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主要参考文献


1: Kase BE, Liese AD, Zhang J, Murphy EA, Zhao L, Steck SE. The Development and Evaluation of a Literature-Based Dietary Index for Gut Microbiota. Nutrients. 2024 Apr 3;16(7):1045. doi: 10.3390/nu16071045.
2: Wang LQ. Mammalian phytoestrogens: enterodiol and enterolactone. J Chromatogr B Analyt Technol Biomed Life Sci. 2002 Sep 25;777(1-2):289-309. doi: 10.1016/s1570-0232(02)00281-7. 251(4):593-600. doi: 10.1007/s00232-018-0035-x. Epub 2018 May 4. 58(11):6678-84. doi: 10.1021/jf100471n. 99(5):2411-2419. doi: 10.1002/jsfa.9448. Epub 2018 Dec 18. 435(1):74-82. doi: 10.1016/j.abb.2004.12.015. 10(1):49. doi: 10.1186/s13048-017-0346-z.
8: Feng J, Shi Z, Ye Z. Effects of metabolites of the lignans enterolactone and enterodiol on osteoblastic differentiation of MG-63 cells. Biol Pharm Bull. 2008 Jun;31(6):1067-70. doi: 10.1248/bpb.31.1067. 89 Suppl

合成参考文献


参考文献:10.2478/v10102-011-0016-8
摘要:Zanwar AA, Hegde MV, Bodhankar SL. Cardioprotective activity of flax lignan concentrate extracted from seeds of Linum usitatissimum in isoprenalin induced myocardial necrosis in rats. Interdiscip Toxicol. 2011 Jun;4(2):90–7.
参考文献:10.1007/s11130-011-0245-1
摘要:Kosińska A, Penkacik K, Wiczkowski W, Amarowicz R. Presence of Caffeic Acid in Flaxseed Lignan Macromolecule. Plant Foods for Human Nutrition. 2011 Jul 16;66(3):270. doi: 10.1007/s11130-011-0245-1.
参考文献:10.4103/0974-8490.81958
摘要:El-Halawany AM, El Dine RS, Chung MH, Nishihara T, Hattori M. Screening for estrogenic and antiestrogenic activities of plants growing in Egypt and Thailand. Pharmacognosy Res. 2011 Apr;3(2):107–13.
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