专利号:WO-2024256370-A1 优先权日:2023-06-13 标 题 :Synthesis of glufosinate using an amidase-based process 发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN 权利人:BASF SE 摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.
专利号:US-12251401-B2 优先权日:2018-08-24 标 题 :Synthesis and antimicrobial uses of dinuclear silver(I) pyrazolates 发明人:RAPTIS RAPHAEL G; CHAKRABORTY INDRANIL; KANDEL SHAMBHU 权利人:RAPTIS RAPHAEL G; CHAKRABORTY INDRANIL; KANDEL SHAMBHU; THE FLORIDA INTERNATIONAL UNIV BOARD OF TRUSTEES 摘要:Novel dinuclear silver(I) pyrazolido complexes and methods of synthesizing them are provided. Advantageously, the novel silver(I) pyrazolido complexes have excellent antimicrobial activity and methods of using said complexes to treat bacterial, fungal, and viral infections are also provided.
专利号:US-11230562-B2 优先权日:2018-04-25 标题 :Synthesis of zinc MOF materials 发明人:TAYLOR JARED M; MAH ROGER K; SHIMIZU GEORGE K H 权利人:UTI LP 摘要:Method for making a Zn MOF of formula Zn 2 Ht 2 CL, where Ht is 1,2,4-triazolate or a combination of 1,2,4-triazolate and one or more other cycloazocarbyl compound, and CL is oxalate or a combination of oxalate and one or more chelating ligand other than oxalate. More specifically, the Zn MOF is Zn 2 Tz 2 Ox, where Tz is 1,2,4-triazolate and Ox is oxalate. The method includes reacting 2 molar equivalents of 1,2,4-triazole or the combination with cycloazocarbyl compound with 1 molar equivalent of oxalate or the combination with other chelating ligand and adding 2 molar equivalents of Zn 2+ to form the Zn MOF. The solvent used can be a lower alcohol or a miscible mixture of water and a lower alcohol. One or both reaction steps are conducted at a temperature less than or equal to 120° C. and can be conducted at room temperature and ambient pressure.
专利号:US-2025120400-A1 优先权日:2021-12-10 标题:Synthesis of glufosinate using a hydantoinase-based process 发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN 权利人:BASF SE 摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.
专利号:US-10326145-B2 优先权日:2012-04-11 标题 :Synthesis of electrocatalysts using metal-organic framework materials 发明人:LIU DI-JIA; ZHAO DAN 权利人:LIU DI JIA; ZHAO DAN; UCHICAGO ARGONNE LLC 摘要:Methods and compositions for use in the preparation of MOF-based non-PGM electrocatalysts including combining transition metal compounds with organic ligands and secondary building units to create a solid mixture, heating the solid mixture to form a MOF through a solid-state reaction, optionally heating the MOF to convert it to an electrocatalyst via pyrolysis, and optionally post-treating. The electrode catalysts may be used in various electrochemical systems, including a proton exchange membrane fuel cell.
专利号:US-9901901-B2 优先权日:2012-05-21 标 题 :Selective extraction of anions from solution 发明人:MEZEI GELLERT 权利人:WESTERN MICHIGAN UNIV RESEARCH FOUNDATION; THE BOARD OF TRUSTEES OF WESTERN MICHIGAN UNIV 摘要:A method of selectively extracting anions from an aqueous solution using an anion encapsulating aggregate formed upon the addition of a solvent, a copper contributor, a hydroxide contributor, a counterion contributor, and pyrazole to an aqueous solution containing the anions, or upon the addition of a solvent, a polymeric chain of [Cu II (μ-OH)(μ-pz)] ∞ and a counterion contributor to the aqueous solution. The aggregates include compounds of the formula cis Cu II x (OR 1 ) y (R 2 pz) z , where R 1 is H or an alkyl group, R 2 is H, or an alkyl group or a charged group, pz is pyrazolate and each of x, y, and z is an integer between about 1 and about 40. In addition, ligand-containing anion encapsulating aggregates can be formed by synthesis with a lig-and-bound pyrazole or by substituting the ligand-bound pyrazole for the pyrazole incorporated in the aggregate.
1: Kubo T, Ohno M, Nagasawa S, Kose T, Kawata K. Behavior of herbicide pyrazolynate and its hydrolysate in paddy fields after application. Bull Environ Contam Toxicol. 2012 Nov;89(5):985-9. doi: 10.1007/s00128-012-0793-6. Epub 2012 Aug 23.
合成参考文献
摘要:Sankyo Kenkyusho Nempo. Annual Report of Sankyo Research Laboratories., 36(44), 1984