CAS: 569-41-5; 1,8-Dimethylnaphthalene

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CAS号2025-95-8 1,8-双(溴甲基)萘 | CAS号81-84-5 1,8-萘二甲酸酐 | CAS号2026-08-6 1,8-萘二甲醇 | CAS号203-84-9 1H,3H-Naphtho[1... | CAS号77-78-1 硫酸二甲酯 | CAS号33295-37-3 1-溴-8-甲基萘 | CAS号50585-29-0 1,8-bis(chlorom... | CAS号36230-24-7 1,8-dimethyl-1,... | CAS号60-29-7 乙醚 | CAS号4044-58-0 1-溴-8-碘萘 | CAS号575-37-1 1,7-二甲基萘 | CAS号2025-95-8 1,8-双(溴甲基)萘 | CAS号120651-41-4 3,4,9,10-tetram... | CAS号2131-41-1 1,4,5-三甲基萘 | CAS号6549-57-1 8-甲基-1-萘醛 | CAS号24055-45-6 1,8-methyl-4-ni... | CAS号104306-74-3 (8-methylnaphth... | CAS号4523-47-1 4,5-Dimethyl-1-...

📜1,8-双(溴甲基)萘置于lithium Aluminium Tetrahydride体系中,化学反应生成 1,8-二甲基萘
参考文献:2-重氮-5,6-和-3,8-二取代的ena烯酮的光解,热,加成和环加成反应
标题:2-重氮-5,6-和-3,8-二取代的ena烯酮的光解,热,加成和环加成反应
摘要:报道了2-重氮5,6-(二取代)ac庚烯酮(11A-D)和2-重氮-3,8-二甲氧基ac庚烯(12)的制备以及各种热和光解反应.醇与11A-C发生热解和光解反应,损失n 2,反应生成2-烷氧基环庚酮(24A,B和47A,B)和烯酮(25和48A,B).苯胺和二苯胺在180oc下通过11A-C转化为[1,2-B]吲哚(29A,B和53A,B).在〜450oc(0.15 毫米汞柱)下加热11A-C分别得到还原产物25和48A,B.在上述实验中未观测到沃尔夫夫重排为1,8-亚萘基乙烯(15A-D)和/或其衍生物.氧气将11A-C热转化为苯醌(19A-C)和/或1,8-萘酐.插入,添加,取代和/或异构化反应是在环己烷,苯和四氢呋喃中辐照2-重氮ac环酮发生的.在o 2存在下,苯中11D的光解产生插入氧化产物2-羟基-5,6-二硝基-2-苯基ac庚酮(60).腈中11A-
DOI:10.1021/jo040175H

专利信息

专利号:US-2003162992-A1
优先权日:2001-12-14
标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides
发明人：WATANABE KYOICHI A; DU JINFA
摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.

专利号:US-7271231-B2
优先权日:1995-01-24
标 题 :Polymerization of olefins
发明人：BROOKHART MAURICE S; JOHNSON LYNDA KAYE; KILLIAN CHRISTOPHER MOORE
权利人:DU PONT
摘要:Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear α-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected α-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected α-diimine nickel complexes with ethylene.

专利号:US-7858808-B2
优先权日:2002-05-31
标 题:Multi-substituted imidazolines and method of use thereof
发明人：TEPE JETZE J; PEDDIBHOTLA SATYAMAHESHWAR
权利人:UNIV MICHIGAN STATE
摘要:A new class of imidazolines as 4-position acids or esters with very potent anti-inflammatory as well as antimicrobial activity is described. The synthesis of these imidazolines includes a multicomponent reaction applicable to a combinatorial synthetic approach. The combination of these two key characteristics provides an effective therapeutic drug in the treatment of septic shock as well as many other inflammatory (arthritis and asthma) and infectious disorders. The use of this novel class of non-steroidal agents as anti-inflammatory agents (for the treatment of asthma etc.), antibacterial agents and antiseptic agents is described. The compounds are also useful in the treatment of tumors (such as cancers). The imidazolines are potent inhibitors of the transcription factor NF-κB as well as potent activity against the Gram (+) bacterium B. subtillus and B. cereus with MIC values in the range of 50 μm/mL.

专利号:US-9884844-B2
优先权日:2012-12-31
标 题:Heterocyclic compounds and methods of use thereof
发明人：FANG QUN KEVIN; CAMPBELL UNA; SPEAR KERRY L
权利人:SUNOVION PHARMACEUTICALS INC; SUNOVION PHARMACEUTICALS INC
摘要:Provided herein are heterocyclyl compounds, methods of their synthesis, pharmaceutical compositions comprising the compounds, and methods of their use. The compounds provided herein are useful for the treatment, prevention, and/or management of various neurological disorders, including but not limited to, psychosis and schizophrenia.

专利号:US-2004035690-A1
优先权日:1998-02-11
标题 :Method and apparatus for chemical and biochemical reactions using photo-generated reagents
发明人：GULARI ERDOGAN
权利人:UNIV MICHIGAN
摘要:This invention provides method and apparatus for performing chemical and biochemical reactions in solution using in situ generated photo-products as reagent or co-reagent. Specifically, the method and apparatus of the present invention have applications in parallel synthesis of molecular sequence arrays on solid surfaces.

专利号:US-7345078-B2
优先权日:2002-05-31
标题 :NF-κB inhibitors and uses thereof
发明人：TEPE JETZE J; PEDDIBHOTLA SATYAMAHESHWAR
权利人:UNIV MICHIGAN STATE
摘要:A new class of imidazolines as 4-position acids or esters with very potent anti-inflammatory as well as antimicrobial activity is described. The synthesis of these imidazolines includes a multicomponent reaction applicable to a combinatorial synthetic approach. The combination of these two key characteristics provides an effective therapeutic drug in the treatment of septic shock as well as many other inflammatory (arthritis and asthma) and infectious disorders. The use of this novel class of non-steroidal agents as anti-inflammatory agents (for the treatment of asthma, etc.), antibacterial agents, and antiseptic agents is described. The compounds are also useful in the treatment of tumors (such as cancers). The imidazolines are potent inhibitors of the transcription factor NF-κB as well as potent activity against the Gram (+) bacterium. The compositions are also useful for treating autoimmune diseases and for inhibiting rejection of organ and tissue transplants.