CAS: 542-91-6; Diethylsilane

该化合物是一种有机硅化合物,其化学配方为C4H12Si,由硅原子结为两个乙基组和两个氢原子组成,这种无色,易燃液体的粘度较低,其沸点相对较低,导致其挥发性.二乙基硅在有机溶剂中溶解,但溶解性有限.主要用于合成含有硅的化合物,并用作生产硅基材料的前体.该化合物可经受各种化学反应,包括体液凝解和脱水,这在有机合成和材料科学中意义重大.鉴于其易燃性和潜在的健康危害,在处理二乙基硅烷时,应采取适当的安全防范措施,包括使用适当的个人防护设备,在通风良好的地区工作.

结构式图片

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ECHA物质C&L通报REACH预注册

上下游产品

CAS号1719-53-5 二氯二乙基硅烷 | CAS号811-49-4 乙基锂 | CAS号7440-21-3 硅 | CAS号16853-85-3 氢化铝锂 | CAS号925-90-6 乙基溴化镁 | CAS号4109-96-0 二氯硅烷 | CAS号617-86-7 三乙基硅烷 | CAS号1609-19-4 chloro(diethyl)... | CAS号54509-73-8 ethene | CAS号123-91-1 1,4-二氧六环 | CAS号606-87-1 N,N-二苯基苄胺 | CAS号1352009-17-6 N,N-diphenyldie... | CAS号108-88-3 甲苯 | CAS号5021-93-2 二乙基二乙氧基硅烷 | CAS号1722-26-5 三乙胺-硼烷 | CAS号18169-73-8 dibromo(diethyl... | CAS号18157-29-4 chloromethyl(di... | CAS号7440-21-3 硅 | CAS号2973-29-7 diethylsilyloxy... | CAS号2344-23-2 hexyl(dimethoxy...

合成工艺路线路线简述

    📜二乙基氯硅烷置于三氯化铝体系中,化学反应生成 二乙基硅烷
    参考文献:Dolgow Et Al.,Zhurnal Obshchei Khimii,1957,Vol. 27,P. 2062; Engl.Ausg.S. 2117
    标题:Dolgow Et Al.,Zhurnal Obshchei Khimii,1957,Vol. 27,P. 2062; Engl.Ausg.S. 2117

    海关参考信息

    专利信息


    专利号:US-7956011-B2
    优先权日:2005-05-04
    标题:Materials and methods for the photodirected synthesis of oligonucleotide arrays
    发明人:SERAFINOWSKI PAWEL JERZY; GARLAND PETER BRYAN
    权利人:CANCER RES INST ROYAL
    摘要:Materials and methods for photodirected synthesis of oligonucleotide arrays on a solid substrate by photodirected synthesis are disclosed which employ a film formed from (i) a photoacid generator that on photolysis generates acid that is capable of directly removing the protecting group of the linker molecules or oligonucleotides and (ii) a polymer substantially lacking electronegative heteroatoms that are capable of hydrogen bonding with photogenerated acid. Methods of synthesizing an oligomer arrays are also described that use a film that restricts diffusion of reactants and products on the substrate during synthesis of the array and which includes a precursor of a deprotecting reagent. The method involves removing one or more of the non-required products of the deprotection reaction from the reactive array elements at which they are produced during the reaction, in order to displace the deprotection reaction towards completion.

    专利号:US-10676481-B2
    优先权日:2016-02-12
    标 题 :Intermediates in the synthesis of eribulin and related methods of synthesis
    发明人:BARAN PHIL S; CHASE CHARLES E; FANG FRANCIS G
    权利人:EISAI R&D MAN CO LTD
    摘要:The invention relates to methods and intermediates useful in the synthesis of eribulin.

    专利号:US-2025179012-A1
    优先权日:2022-03-04
    标 题:Synthesis of sulfur(vi) compounds and reagents for same
    发明人:LOPCHUK JUSTIN MATTHEW; SHULTZ ZACHARY
    权利人:H LEE MOFFITT CANCER CT & RES
    摘要:This disclosure provides reagents and processes for the synthesis of organic compounds, more particularly reagents and processes for the asymmetric synthesis of sulfur (VI) containing organic compounds.

    专利号:US-2006183758-A1
    优先权日:2005-02-17
    标 题:Method for synthesis of AZA-annelated pyrroles, thiophenes, and furans
    发明人:BEARD CHARLES D; LEE VING J; WHITTLE C E
    权利人:CB RES AND DEV INC
    摘要:Methods of synthesis of intermediates that are useful as bioisosteres of the indole, benzofuran and benzothiophene scaffold are disclosed.

    专利号:US-2023192731-A1
    优先权日:2020-05-29
    标 题 :Process for the stepwise synthesis of silahydrocarbons
    发明人:AUNER NORBERT; STURM ALEXANDER G; SANTOWSKI TOBIAS; FELDER THORSTEN
    权利人:MOMENTIVE PERFORMANCE MAT INC
    摘要:The invention relates to a process for the stepwise synthesis of silahydrocarbons bearing up to four different organyl substituents at the silicon atom, wherein the process includes at least one step a) of producing a bifunctional hydridochlorosilane by a redistribution reaction, selective chlorination of hydridosilanes with an ether/HCl reagent, or by selective chlorination of hydridosilanes with SiCl 4 , at least one step b) of submitting a bifunctional hydridochloromonosilane to a hydrosilylation reaction, at least one step c) of hydrogenation of a chloromonosilane, and a step d) in which a silahydrocarbon compound is obtained in a hydrosilylation reaction.

    专利号:US-6479599-B1
    优先权日:1997-04-04
    标题:Catalyst system for high yield synthesis of polyolefins
    发明人:PEIL KEVIN P; WILSON DAVID R
    权利人:BP CHEM INT LTD
    摘要:This invention relates to a supported metallocene catalyst system for the high yield synthesis of polyolefins, to methods of preparation of the catalyst system, to polymerization processes which use the catalyst system and to polyolefin polymers produced by the polymerization processes.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Anderson, E. A.; Lim, D. S. W., Science of Synthesis Knowledge Updates, (2015) 1, 144.
    摘要:Szabó, K. J., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 2, 513.
    摘要:Ros, A.; Fernández, R.; Lassaletta, J. M., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 2, 436.
    摘要:Chen, P.; Liu, G., Science of Synthesis: Catalytic Oxidation in Organic Synthesis, (2017) 1, 235.
    摘要:van der Puyl, V.; Shenvi, R. A., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 648.
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