2,3-Dichloro-6-Nitrotoluene置于盐酸,硫酸,氯,Tin(Ll) Chloride,Sodium Nitrite体系中,化学反应生成 2,3,6-三氯苯甲醛 参考文献:Brimelow Et Al.,Journal Of The Chemical Society,1951,P. 1208,1212 标题:Brimelow Et Al.,Journal Of The Chemical Society,1951,P. 1208,1212
专利号:US-6822092-B2 优先权日:2000-06-12 标 题:Expanded porphyrins and a method for synthesis thereof 发明人:OSUKA ATSUHIRO 权利人:JAPAN SCIENCE & TECH AGENCY 摘要:Novel meso-aryl substituted expanded porphyrins comprising of alternate arrangement of more than six of pyrrole units bridged by a methine group whose hydrogen is substituted with Ar-group; and their synthetic method. Ar-group is either a 2,6-substituted phenyl group which can possess a substituent at the other 3, 4, and 5 positions, or 9-anthryl group which can possess a substituent at the other positions of the anthracence, or a cyclohexyl group which can possess a substituent at the other positions of the cyclohexyl group. The substituents at the 2 and 6 positions mentioned above can be selected independently from halogen atom or lower alkyl group of carbon number 1 to 4, substituents at 3-5 positions, 9-anthryl group and cyclohexyl group can be selected independently from the group consisting of substituted or non-substituted alkyl of carbon number 5 or 6, substituted or non-substituted aryl group, besides above mentioned substituents at 2 and 6 positions. Each Ar-group can be different.
[参考文献]: M Keith Davis, Et Al. Assessing Intermittent Pesticide Exposure From Flea Control Collars Containing The Organophosphorus Insecticide Tetrachlorvinphos. J Expo Sci Environ Epidemiol. 2008 Nov;18(6):564-70.
合成参考文献
摘要:Weast, R.C. (ed.). Handbook of Chemistry and Physics. 60th ed. Boca Raton, Florida: CRC Press Inc., 1979., p. C-144 摘要:U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals., NX#07568