CAS: 3205-25-2; 1-(2-Nitrophenyl)Ethanol

该化合物是一种有机化合物,其特点是存在一个与乙醇协会附属的硝基联苯集团,该化合物具有氢氧基(-OH),有助于将其分类为酒精.硝基化合物组(-NO2)位于苯环的第二碳上,影响化合物的回动和极度.一般情况下,1-(2-硝基苯)乙醇是一种固体或液体,视具体情况而定,并因其在有机合成中的潜在应用和在各种化合物生产中的中间体而已知.氢氧基和硝基化合物的存在可产生独特的特性,例如极溶剂中的溶性增加,以及参与氢联结的能力.此外,该化合物可能表现出有趣的电子特性,因为硝基化合物的电吸附性质会影响其化学反应中的行为.在处理该物质时,应当采取安全防范措施,因为硝基化合物可能具有危险性.

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CAS号198756-82-0 (S)-a-甲基-2-硝基-苯甲胺 | CAS号1445-91-6 (S)-(-)-1-苯基乙醇

合成工艺路线路线简述

    📜邻硝基苯乙酮置于c40H37Cln2Prus(1+)*c24H20B(1-),异丙醇,Potassium Hydroxide体系中,化学反应 2.0H,以100%的收率获得1-(2-硝基苯基)乙醇
    参考文献:高效和可回收的钌(II)芳烃硫酰胺催化剂,用于酮的氢化转移:取代基对催化结果的影响
    标题:高效和可回收的钌(II)芳烃硫酰胺催化剂,用于酮的氢化转移:取代基对催化结果的影响
    摘要:六个阳离子钌(II)芳烃与分子通式的硫代酰胺络合物的[ru(η 6-P-Cymene)(pph 3)(l)] + [其中,L =吡啶-2-硫代酰胺和它的衍生物]已成功从的[ru(反应合成η 6-P氯-Cymene)2 ] 2与螯合配体的硫代酰胺和pph 3 2 M比分别为:在1在甲醇中.所有的复合物分离,为他们的bph 4-的盐,并通过分析和光谱(ft-Ir,Uv-Vis和被完全表征11 H-NMR)方法.复合物中的一个的固态结构,的[ru(η 6-P-Cymene)(pph 3)(l4)] Bph 4(4)(l4 = ñ-(2,4,6-三甲基苯基)吡啶已通过x射线单晶衍射建立了2-硫代羧酰胺),表明复合物中存在伪八面体(钢琴凳)配位几何.研发了钌(II)配合物对各种芳族,杂环和环状酮的转移氢化作用.氢化钌(II)的形成由1确认1 H-NMR被提出作为该反应中的
    Doi:10.1016/j.Jorganchem.2016.02.016

    海关参考信息

    专利信息


    专利号:US-7301049-B2
    优先权日:2001-06-21
    标 题:Photolabile esters and their uses
    发明人:SERAFINOWSKI PAWEL JERZY; GARLAND PETER BRYAN
    权利人:CANCER RES INST
    摘要:Compounds which are capable of generating acid on photolysis are disclosed, and the uses of these compounds, especially for deprotecting the termini of nucleic acid molecules or peptides during synthesis of arrays. The compounds described herein may be employed in the detritylation of 5′-O-dimethoxytrityl (DMT) protected nucleotides by photolysing the compounds to generate an acid capable of removing the DMT group allowing oligonucleotide arrays to be synthesised using readily available 5′-O-DMT-nucleoside-3′-O-phosphoramidite monomers conventionally used in solid phase nucleic acid synthesis. A method of avoiding the effects of stray light in projection lithography techniques is also disclosed.

    专利号:US-6384264-B1
    优先权日:1997-12-24
    标题:Photoactive materials applicable to imaging systems
    发明人:DOS SANTOS CRISTIANO MARIA DE; DAVIES JOHN KYNASTON; DOWD SHARON; JOHNSTONE ROBERT ALEXANDER WAL; PRATT MICHAEL JOHN; WADE JOHN ROBERT
    权利人:AGFA GEVAERT
    摘要:Organic photoprecursors of amines are provided for use in photosensitive imaging systems, finding particular application in the preparation of lithographic printing plates. Said photoprecursors generate free amines on exposure to long wavelength UV or visible radiation, have high solubility in organic solvents, and include photolabile 2-nitrobenzyl functional groups. Methods for the synthesis of the photoprecursors are described, and the use of the said photoprecursors for the production of printing plates using both positive working and negative working techniques are discussed.

    专利号:CN-104725247-A
    优先权日:2015-03-24
    标题:Device and method for continuous synthesis of anthranilol by microreactor method

    专利号:CN-104725247-B
    优先权日:2015-03-24
    标 题:Device and method for continuous synthesis of anthranilol by microreactor method

    专利号:CN-107417535-A
    优先权日:2017-05-17
    标题:A One-Pot Synthesis of Highly Selective (E)‑β‑Nitrostyrene Derivatives

    专利号:CN-204702683-U
    优先权日:2015-03-24
    标题 :A device for continuous synthesis of anthranilol by microreactor method

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Sharma, U.; Kumar, R.; Gupta, S. S.; Chandra, D., Science of Synthesis Knowledge Updates, (2022) 2, 346.
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