CAS: 25059-80-7; Benazolin Ethyl Ester

该化合物是一种选择性的系统除草剂,属于丙氧基苯丙胺化学类,主要用于对谷类作物(如小麦和大麦)的大叶杂草进行出血后控制,主要用于小麦和大麦等大叶杂草;抑制乙酰-CoA carboxylase(ACCase)的复合行为,干扰易感染植物的脂肪酸合成;关键优点包括抗药性杂草人群的高效性,低施用率和土壤持久性最低的有利环境特征;Benazolin-乙基在目标杂草中迅速吸收和迁移,确保有效控制;其选择性确保作物安全性,在按指示使用时确保作物安全性;除草剂通常与安全剂一起配制,以提高与谷物的兼容性.

结构式图片

欧盟法规

统一分类与标签ECHA物质ECHA物质C&L通报REACH预注册废弃物危险特性清单

上下游产品

ethyl 2-((2-chlorophenyl)amino)acetate

合成工艺路线路线简述

    2-((2-氯苯基)氨基)乙酸乙酯置于硫酸,N,N-二甲基苯胺体系中,用 甲苯 用作溶剂,化学反应 6.5H,反应生成草除灵
    参考文献:An Improved Method For Preparation Ofn-Alkyl-2(3H)-Benzothiazolone Analogs
    标题:An Improved Method For Preparation Ofn-Alkyl-2(3H)-Benzothiazolone Analogs
    摘要:一些 N-烷基-2(3H)-苯并噻唑酮类似物可以从 N-单取代苯胺和氯甲酰亚磺酰氯中制备出来.新方法包括苯胺的氨基甲酰化,以及在适当的路易斯酸或质酸催化剂存在下,中间产物氨基甲酰磺酰氯的连续弗里德尔-卡夫斯型闭环反应.
    Doi:10.1246/bcsj.56.1255

    海关参考信息

    专利信息


    专利号:US-2010190794-A1
    优先权日:2007-06-12
    标 题:Herbicidally Active Composition
    发明人:HUPE EIKE; MOBERG WILLIAM KARL; REINHARD ROBERT; SIEVERNICH BERND; KIBLER ELMAR
    权利人:BASF SE
    摘要:The present invention relates to herbicidally active compositions comprising at least one piperazinedione compound of the formula I n n n n n n n n n n n n in which: n R x , R y are each hydrogen or together are a chemical bond; n R 1 is cyano or nitro; n R 2 is hydrogen, fluorine, chlorine, C 1 -C 2 -alkyl, ethenyl or C 1 -C 2 -alkoxy; n R 3 is fluorine or hydrogen; n R 4 is methyl; n R 5 is hydrogen, methyl or ethyl; n R 6 is hydrogen, methyl or ethyl; and n R 7 is hydrogen or halogen; n and at least one further active compound selected from the group consisting of n b1) lipid biosynthesis inhibitors; n b2) acetolactate synthase inhibitors (ALS inhibitors); n b3) photosynthesis inhibitors; n b4) protoporphyrinogen-IX oxidase inhibitors, n b5) bleacher herbicides; n b6) enolpyruvyl shikimate 3-phosphate synthase inhibitors (EPSP inhibitors); n b7) glutamine synthetase inhibitors; n b8) 7,8-dihydropteroate synthase inhibitors (DHP inhibitors); n b9) mitose inhibitors; n b10) inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors); n b11) cellulose biosynthesis inhibitors; n b12) decoupler herbicides; n b13) auxin herbicides; n b14) auxin transport inhibitors; n b15) other herbicides, and n C) safeners.

    专利号:WO-2020126584-A1
    优先权日:2018-12-18
    标 题 :Herbicidal combinations
    发明人:KRAUS HELMUT; ZAGAR CYRILL; SEISER TOBIAS; BESSAI JOHANNES; DIMITRIADI TATJANA; BLAKEN MATTHEW; LANDES ANDREAS; GRIVEAU YANNICK; REID DANIELLE; VAN THIELEN NOCHA; BROWN JEFFREY; PETERS JDAVID
    权利人:BASF AGROCHEMICAL PRODUCTS BV
    摘要:The present invention relates to herbicidally active combinations comprising a herbicide A and at least one herbicide B, wherein the herbicide A is R-imazamox, any non-racemic mixture of R- imazamox and S-imazamox, wherein the proportion of R-imazamox is at least 80% by weight, or an agriculturally acceptable salt or ester thereof; and the at least one herbicide B is selected from the groups b1) to b15): b1)lipid biosynthesis inhibitors; b2)acetolactate synthase inhibitors (ALS inhibitors); b3)photosynthesis inhibitors; b4)protoporphyrinogen-IX oxidase inhibitors; b5)bleacher herbicides; b6)enolpyruvyl shikimate 3-phosphate synthase inhibitors (EPSP inhibitors); b7)glutamine synthetase inhibitors; b8)7,8-dihydropteroate synthase inhibitors (DHP inhibitors); b9)mitosis inhibitors; b10)inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors); b11)cellulose biosynthesis inhibitors; b12)decoupler herbicides; b13)synthetic auxins; b14)auxin transport inhibitors; and b15)other herbicides.

    专利号:US-11213031-B2
    优先权日:2017-11-13
    标 题:Tetrazolylpropyl derivatives and their use as fungicides
    发明人:SUDAU ALEXANDER; HOFFMANN SEBASTIAN; DAHMEN PETER; WEBSTER ROBERT ALAN; MEISSNER RUTH; GOERTZ ANDREAS; MILLER RICARDA; COQUERON PIERRE-YVES; BERNIER DAVID; NICOLAS LIONEL; BRUNET STEPHANE; KENNEL PHILIPPE; TOQUIN VALERIE; GOURGUES MATHIEU; LOQUE DOMINIQUE; THOMAS VINCENT
    权利人:BAYER AG; BAYER CROPSCIENCE AG
    摘要:The present invention relates to tetrazolylpropyl derivatives of formula (I) n nwherein one of V 1 and V 2 represents CR 3 and the other one of V 1 and V 2 represents N, Q represents a 6-membered aromatic cycle as defined in the specification, and R 1 , R 2 , R 3 , R 4 , and R 5 are defined as disclosed in the specification, to compositions comprising such compounds, to the use of said compounds as fungicides, as well as to particular intermediates useful in the synthesis of said tetrazolylpropyl derivatives.

    专利号:BR-112019014061-A2
    优先权日:2017-01-23
    标 题 :compounds of formula i, intermediates b, intermediates c, intermediates ii and intermediates d, composition, use, method to combat phytopathogenic fungi, seed and process for the synthesis of the compounds of formula i

    专利号:EP-3650430-A1
    优先权日:2015-05-12
    标题 :Intermediates and processes for the synthesis of herbicides

    专利号:WO-2021069704-A1
    优先权日:2019-10-11
    标 题:Active compound combinations
    发明人:GÖRTZ ANDREAS; KLÜKEN MICHAEL; MONTAGNE CYRIL; ES-SAYED MAZEN
    权利人:BAYER AG
    摘要:The present invention relates to active compound combinations comprising N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylimidoformamide, at least one fungicide selected from specified inhibitors of the ergosterol synthesis or from specified compounds capable of having a multisite action, and at least one additional fungicide selected from inhibitors of the ergosterol synthesis or from compounds capable of having a multisite action, to compositions comprising such compound combination, and to the use thereof as biologically active agents, especially for control of harmful microorganisms in crop protection and in the protection of industrial materials.
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    主要参考文献

    [参考文献]: I D Kelly, Et Al. Chromatographic Purification And Identification Of Polar Metabolites Of Benazolin-Ethyl From Soybean. Int J Environ Anal Chem. 1986;25(1-3):135-49.
    [参考文献]: Ian J Senior, Et Al. Herbicide Sensitivity Of Transgenic Multiple Herbicide-Tolerant Oilseed Rape. Pest Manag Sci. 2002 Apr;58(4):405-12.
    [参考文献]: Tianming Cai, Et Al. Biodegradation Of Benazolin-Ethyl By Strain Methyloversatilis Sp. Cd-1 Isolated From Activated Sludge. Curr Microbiol. 2011 Feb;62(2):570-7.

    合成参考文献


    摘要:Farm Chemicals Handbook., -(C151), 1991
    摘要:Pesticide Manual., 9(52), 1991
    参考文献:10.1002/ps.471
    摘要:Senior IJ, Moyes C, Dale PJ. Herbicide sensitivity of transgenic multiple herbicide-tolerant oilseed rape. Pest Manag Sci. 2002 Apr;58(4):405–12. doi: 10.1002/ps.471.
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