CAS: 22112-84-1; 5,10,15,20-Tetrakis(4-Aminophenyl)-21H,23H-Porphine

该化合物是一种合成激素化合物,其特点是其复杂的循环结构,其中包括一种与各种金属相协调的中央金属离子,可加强其在催化,光动疗法和染色方面的应用特性.附于porphyrin核心的四个4-momino苯基组的存在,大大提高了其极地溶剂的溶解性,并增强了其因氨基组而具有的再生化学改造作用.这种复合体在电磁频谱可见区域表现出强大的吸收力,使其在光学应用中有用.此外,它能够形成稳定的金属离子复合体,使其在协调化学中能够发挥多功能性悬殊作用.该化合物独特的电子特性源于其同质系统,有助于其在有机电子学和医疗应用中作为光敏化剂的潜在用途.

结构式图片

相似化合物

22843-73-8 67605-64-5 116206-75-8

欧盟法规

ECHA物质C&L通报

合成工艺路线路线简述

  • 合成目标产物 5,10,15,20-Tetrakis(4-Aminophenyl)-21H,23H-Porphine 主要起始原料 5,10,15,20-Tetrakis(4-Nitrophenyl)Porphyrin
  • 22112-84-1 + 1951-36-6 = 22112-84-1 + 1951-36-6
    反应条件:1.1 Reagents: Acetic Acid Solvents: 1-Butanol,1,2-Dichlorobenzene,Water; 6 D,120 °C
    标题:Synergistic Effect Of Covalent Bonding And Physical Encapsulation Of Sulfur In The Pores Of A Microporous Cof To Improve Cycling Performance In Li-S Batteries
    作者:Royuela,Sergio; Almarza,Joaquin; Mancheno,Maria J.; Perez-Flores,Juan C.; Michel,Enrique G.; Et Al
    参考文献:Chemistry - A European Journal 日期:2019 卷标:25(53) 页码:12394-12404

专利信息


专利号:US-2022325053-A1
优先权日:2019-08-13
标题:Method for the synthesis of a two-dimensional or quasi-two-dimensional polymer film, the two-dimensional or quasi-two-dimensional polymer film and the use

专利号:EP-3586956-A1
优先权日:2018-06-22
标 题:Nanoreactors for the synthesis of porous crystalline materials

专利号:US-9688686-B2
优先权日:2013-06-21
标题:Porphyrin containing covalent organic frameworks and process for the preparation thereof
发明人:BANERJEE RAHUL; KANDAMBETH SHARATH
权利人:COUNCIL OF SCIENT & IND RES (AN INDIAN REGISTERED BODY INCORPORATED UNDER THE REGISTRATION OF SOCIET; COUNCIL SCIENT IND RES
摘要:Disclosed herein is novel highly stable, crystalline porphyrin containing covalent organic frameworks and their synthesis using Schiff base reaction which are hydrophobic in nature having good selectivity towards alcohol uptake at low pressure over water. Particularly, present invention provides novel highly stable, porous covalent organic frameworks (COFs) comprising porphyrin linked hydroxyl aromatic compound by intramolecular O—H—Nâ•?C bonding; wherein porphyrin is tetra(p-amino-phenyl)porphyrin (Tph) and hydroxyl aromatic compound is selected from group consisting of Triformylphloroglucinol (Tp), 2, 5-dihydroxyterephthalaldehyde (Da).

专利号:EP-3810320-B1
优先权日:2018-06-22
标 题:Nanoreactors for the synthesis of porous crystalline materials

专利号:EP-2832767-A1
优先权日:2013-07-31
标 题 :Method for the Synthesis of Covalent Organic Frameworks

专利号:CN-119372498-B
优先权日:2024-12-27
标 题 :Synthesis of crown ether-based covalent organic framework adsorption materials and their targeted adsorption and extraction methods for indium
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主要参考文献

1.) Bifunctional covalent organic frameworks with two dimensional organocatalytic micropores, Shinde, Digambar Balaji; Kandambeth, Sharath; Pachfule, Pradip; Kumar, Raya Rahul; Banerjee, Rahul, Chemical Communications (Cambridge, United Kingdom) (2015), 51(2), 310-313. 2.) Manganese porphyrin derivatives as ionophores for thiocyanate-selective electrodes: the influence of porphyrin substituents and additives on the response properties Khorasani, Jafar H.; Amini, Mohammad K.; Motaghi, Hasan; Tangestaninejad, Shahram; Moghadam, Majid, Sensors and Actuators, B: Chemical (2002), 87(3), 448-456. 3.) Positional effects of second-sphere amide pendants on electrochemical CO2 reduction catalyzed by iron porphyrins, Nichols, Eva M.; Derrick, Jeffrey S.; Nistanaki, Sepand K.; Smith, Peter T.; Chang, Christopher J., Chemical Science (2018), 9(11), 2952-2960. 4.) The optical gas-sensing properties of an asymmetrically substituted porphyrin, Pedrosa, Jose Ma; Dooling, Colin M.; Richardson, Tim H.; Hyde, Robert K.; Hunter, Chris A.; Martin, Ma Teresa; Camacho, Luis, Journal of Materials Chemistry (2002), 12(9), 2659-2664. 5.) Micellar Cobaltporphyrin Nanorods in Alcohols, Yuasa, Makoto; Oyaizu, Kenichi; Yamaguchi, Aritomo; Kuwakado, Michi, Journal of the American Chemical Society (2004), 126(36), 11128-11129. 6.) Influence of Molecular Organization of Asymmetrically Substituted Porphyrins on Their Response to NO2 Gas, Pedrosa, Jose M.; Dooling, Colin M.; Richardson, Tim H.; Hyde, Robert K.; Hunter, Chris A.; Martin, Maria T.; Camacho, Luis, Langmuir (2002), 18(20), 7594-7601. 7.) State-of-the-art catechol porphyrin COF catalyst for chemical fixation of carbon dioxide via cyclic carbonates and oxazolidinones, Saptal, Vitthal; Shinde, Digambar Balaji; Banerjee, Rahul; Bhanage, Bhalchandra M., Catalysis Science & Technology (2016), 6(15), 6152-6158. 8.) Spin effects on decay dynamics of charge-separated states generated by photoinduced electron transfer in zinc porphyrin-naphthalenediimide dyads, Mori, Yukie; Sakaguchi, Yoshio; Hayashi, Hisaharu , Journal of Physical Chemistry A (2002), 106(18), 4453-4467. 9.) Stable Binding of Isothiocyanoporphyrin Molecules to Au(111): An STM Study, Han, Wenhai; Li, Shumin; Lindsay, S. M.; Gust, Devens; Moore, Thomas A.; Moore, Ana L., Langmuir (1996), 12(23), 5742-5744. 10.) A porous porphyrin organic polymer (PPOP) for visible light triggered hydrogen production, Mukherjee, Gargi; Thote, Jayshri; Aiyappa, Harshitha Barike; Kandambeth, Sharath; Banerjee, Subhrashis; Vanka, Kumar; Banerjee, Rahul, Chemical Communications (Cambridge, United Kingdom) (2017), 53(32), 4461-4464. 11.) Efficient ternary organic photovoltaics incorporating a graphene-based porphyrin molecule as a universal electron cascade materials, Stylianakis, M. M.; Konios, D.; Kakavelakis, G.; Charalambidis, G.; Stratakis, E.; Coutsolelos, A. G.; Kymakis, E.; Anastasiadis, S. H., Nanoscale (2015), 7(42), 17827-17835.

合成参考文献


参考文献:10.1007/s11172-023-3907-x
摘要:Mamardashvili GM, Mamardashvili NZ. Design and binding ability of organometallic Zn porphyrin films toward imidazole derivatives. Russ Chem Bull. 2023 Jun;72(6):1322–33. doi: 10.1007/s11172-023-3907-x.
参考文献:10.1007/s12274-022-5307-1
摘要:Zhao R, Wang T, Li J, Shi Y, Hou M, Yang Y, Zhang Z, Lei S. Two-dimensional covalent organic frameworks for electrocatalysis: Achievements, challenges, and opportunities. Nano Res. 2023 May 06;16(7):8570–95. doi: 10.1007/s12274-022-5307-1.
参考文献:10.1007/s40242-023-3127-9
摘要:Wang M, Huang G, You Z, Jia R, Zhong Y, Bai F. Progress of Porphyrin-based Nanoassemblies for Cancer Theranostics. Chem. Res. Chin. Univ. 2023 Jul 14;39(4):612–23. doi: 10.1007/s40242-023-3127-9.
参考文献:10.1007/s12393-023-09355-1
摘要:Lena A, Marino M, Manzano M, Comuzzi C, Maifreni M. An Overview of the Application of Blue Light-Emitting Diodes as a Non-Thermic Green Technology for Microbial Inactivation in the Food Sector. Food Eng Rev. 2023 Aug 19;16(1):59–84. doi: 10.1007/s12393-023-09355-1.
参考文献:10.1007/s11664-023-10711-4
摘要:Khune AS, Padghan V, Bongane R, Narwade VN, Dole BN, Ingle NN, Tsai M, Hianik T, Shirsat MD. Highly Selective Chemiresistive SO2 Sensor Based on a Reduced Graphene Oxide/Porphyrin (rGO/TAPP) Composite. J. Electron. Mater. 2023 Sep 29;52(12):8108–23. doi: 10.1007/s11664-023-10711-4.
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