CAS: 193410-84-3; Zeylenone

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物理性质

MSDS等安全信息

上下游产品

山椒子烯醇 (-)-Zeylenol 78804-17-8
(-)-Uvarigranol G 207971-83-3

合成工艺路线路线简述

  • 合成目标产物 (4R,5S,6S)-4-(Benzoyloxy)-6-[(Benzoyloxy)Methyl]-5,6-Dihydroxy-,2-Cyclohexen-1-One 主要起始原料 2,4-Methanoindeno[7,1-Bc]Furan-7-Methanol, 8-Bromo-2,2A,3,4,4A,5,7A,7B-Octahydro-5-Hydroxy-, (2R,2As,4R,4As,5R,7As,7Bs,8R)-
  • (文献来源)合成步骤主要原料 2,4-Methanoindeno[7,1-Bc]Furan-7-Methanol, 8-Bromo-2,2A,3,4,4A,5,7A,7B-Octahydro-5-Hydroxy-, (2R,2As,4R,4As,5R,7As,7Bs,8R)-
📜山椒子烯醇置于manganese(Iv) Oxide体系中,用 乙酸乙酯 用作溶剂,化学反应 4.0H,以82%的收率获得山椒子烯酮
参考文献:来自中国树紫tree的四种多氧化环己烯.
标题:来自中国树紫tree的四种多氧化环己烯.
摘要:从中国树紫心u的心木中分离出两种新型的多氧合环己烯,即6-甲氧基ze烯酚(3)和2-乙酰氧基ze烯酮(4),以及两种已知的化合物,Y烯酚(1)和ze烯酮(2).玉米油烯醇(1)和玉米油烯酮(2)均表现出对莴苣根生长的抑制活性.通过光谱和化学方法确定它们的结构.
Doi:10.1271/bbb.65.1395

海关参考信息

专利信息


专利号:CN-102675110-A
优先权日:2011-03-09
标题 :Novel production process for chemical synthesis of zeylenone

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主要参考文献

参考标题:Concise Total Synthesis Of (+)-Zeylenone With Antitumor Activity And The Structure-Activity Relationship Of Its Derivatives
作者:Zhonghao Sun,Shuxian Yang,Chengfang Xu,Fan Yi,Li Cao,Yu Tian,Jiahao Lin,Xudong Xu |发布日期:2021.11
摘要:Products--Polyoxygenated Cyclohexenes Exhibited Potent Anti-Tumor Activity, Such As Zeylenone, Which Is A Natural Product Isolated From Uvaria Grandiflora Roxb. This Article Will Attempt To Establish A Gram-Scale Synthesis Method Of (+)-Zeylenone And Explain The Structure-Activity Relationship Of This Kind Of Compound. Total Synthesis Of (+)-Zeylenone Was Completed In 13 Steps With Quinic Acid As The

合成参考文献


参考文献:10.1002/ps.6580
摘要:He J, Dou M, Xie J, Hou S, Liu Q, Hu Z, Zhang B, Zheng S, Yin F, Zhang M, Xie C, Lu D, Ding X, Zhu C, Sun R. Discovery of zeylenone from Uvaria grandiflora as a potential botanical fungicide. Pest Management Science. 2021 Aug 12;77(12):5407–17. doi: 10.1002/ps.6580.
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