Sodium Tungstate (Vi) Dihydrate置于硝酸体系中,用 水 用作溶剂,化学反应 49.0H,反应生成三氧化钨 参考文献:在可见光下可轻松 合成载有wo 3纳米颗粒的gc 3 N 4纳米片,并具有增强的光催化性能† 标题:在可见光下可轻松 合成载有wo 3纳米颗粒的gc 3 N 4纳米片,并具有增强的光催化性能† 摘要:石墨氮化碳(gc 3 ñ 4)纳米片装载有wo 3层制备的纳米颗粒通过gc的热处理3 ñ 4与wo一起x-Eda纳米带.热处理温度和wo X-Eda前体在增强wo 3纳米颗粒与gc 3 N 4纳米片之间的相互作用中起着关键作用,因为wo X-Eda的热分解温度(约400oc)接近于200oc. Gc 3 N 4的热剥离温度.对纳米复合材料在光催化性能上的结构演化和促进作用进行了很好的研究.发现wo 3纳米颗粒均匀地分散在gc 3 N 4纳米片的表面上,并且wo 3和gc 3 N 4的紧密结合导致在可见光照射下rhb的降解中具有高的光催化活性.同时,较大的比表面积和可见光吸收的增加也有利于加速有机染料的降解.此外,还研究了光催化反应的机理及其再利用性能. Doi:10.1039/c7Ra02297B
专利信息
专利号:WO-2025086012-A1 优先权日:2023-10-27 标题:Catalyst for the synthesis of methanol from methane and carbon dioxide 发明人:LI CHAO-JUN; SU HUI; HAN JINGTAN 权利人:THE ROYAL INSTITUTION FOR THE ADVANCEMENT OF LEARNING/MCGILL UNIV 摘要:There is provided a photocatalyst for the direct synthesis of methanol from methane and carbon dioxide. The photocatalyst comprises an AuPd alloy nanoparticles dispersed on a support comprising GaN, InN, AlN, BN, TlN, GaP, InP or a combination thereof. The AuPd alloy nanoparticles are uniformly dispersed on the support such that at least 90% of the AuPd alloy nanoparticles are positioned at a distance of from 1 nm to 15 nm from other AuPd alloy nanoparticles. There is also provided a method of synthesizing methanol from methane and carbon dioxide with a photocatalyst comprising a transition metal dispersed on a support comprising GaN, InN, AlN, BN, TlN, GaP, InP or a combination thereof.
专利号:US-2025281915-A1 优先权日:2023-06-06 标题 :Synthesis of Metallic Glass Nanoparticles by Flash Carbothermic Reactions and Compositions Thereof 发明人:TOUR JAMES M; DENG BING 权利人:UNIV RICE WILLIAM M 摘要:Synthesis of metallic glass nanoparticles and compositions thereof, including, particularly, the kinetically controlled synthesis of glass nanoparticles by flash carbothermic reactions and compositions thereof.
专利号:US-12139504-B2 优先权日:2022-08-09 标 题:Vanadium alkylidene complex, synthesis and use thereof 发明人:BUKHRYAKOV KONSTANTIN; BELOV DMITRY 权利人:BUKHRYAKOV KONSTANTIN; BELOV DMITRY; THE FLORIDA INTERNATIONAL UNIV BOARD OF TRUSTEES 摘要:The subject invention provides catalytical compounds/complexes, compositions comprising such compound/complex, synthesis of the compounds/complexes, and methods of using such compounds/complexes as catalysts in, for example, RCM reactions. Specifically, the subject invention provides the synthesis of the first catalytically active V oxo alkylidene, VO(CHSiMe 3 )(PEt 3 ) 2 Cl, which exhibits superior performance compared to other analogs.
专利号:US-2024263349-A1 优先权日:2023-02-02 标 题 :Phase-controllable synthesis of transition metal dichalcogenide monolayer crystals 发明人:ZHANG HUA; ZHAI WEI; WANG YONGJI 权利人:UNIV CITY HONG KONG 摘要:The present invention provides a general salt-assisted chemical vapour deposition method for phase-controllable synthesis of 1T′ and 2H-phase transition metal dichalcogenide (TMD) monolayer crystals. The method comprises: mixing a transition metal compound powder and a salt powder to form a precursor; placing a substrate on top of the precursor; placing the precursor and the substrate at a center position in a chemical vapour deposition (CVD) furnace; placing a chalcogen powder at an upstream position relative to the precursor along a gas-flow direction in the CVD furnace; heating up the CVD furnace to a growth temperature within the heat-up time; keeping the CVD furnace at the growth temperature for a growth time under a mixed gas flow of H2 and Ar. The optical and electrical characterizations reveal the phase-dependent in-plane isotropy and anisotropy of the as-synthesized 2H and 1T′-phase crystals. The 1T′-TMD monolayer crystals demonstrate much-improved phase transition temperatures.
专利号:US-11964879-B2 优先权日:2016-12-30 标 题 :Template-assisted synthesis of 2D nanosheets using nanoparticle templates 发明人:DANIELS STEVEN; PICKETT NIGEL L 权利人:NANOCO TECHNOLOGIES LTD; NANOCO 2D MAT LIMITED 摘要:A template-assisted method for the synthesis of 2D nanosheets comprises growing a 2D material on the surface of a nanoparticle substrate that acts as a template for nanosheet growth. The 2D nanosheets may then be released from the template surface, e.g. via chemical intercalation and exfoliation, purified, and the templates may be reused.
专利号:US-2014255328-A1 优先权日:2013-03-11 标 题:Hydrothermal Synthesis of Zinc Phlogopite 发明人:MCGUIRE MEAGHAN CLARK; BULL IVOR; JOHNSON GEOFFREY MARK 权利人:BASF SE 摘要:This invention relates to a synthetically derived zinc phlogopite platelets, of superior platelet diameter, effect pigments comprising such synthetically derived platelets and methods of forming said substrates. More specifically the disclosure describes an improved hydrothermal synthesis of zinc phlogopite suitable as a platelets for interference pigments, barrier and flame retardant applications.
摘要:Chiba, S.; Narasaka, K., Science of Synthesis Knowledge Updates, (2011) 4, 451. 摘要:Jiao, N.; Li, Z., Science of Synthesis: Catalytic Oxidation in Organic Synthesis, (2017) 1, 678. 摘要:International Labour Office. Encyclopedia of Occupational Health and Safety. Volumes I and II. New York: McGraw-Hill Book Co., 1971., p. 1444 摘要:Fire Protection Guide to Hazardous Materials. 12 ed. Quincy, MA: National Fire Protection Association, 1997., p. 491-203 摘要:American Conference of Governmental Industrial Hygienists TLVs and BEIs. Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices. Cincinnati, OH, 2008, p. 59