CAS: 610-29-7; 2-Nitroterephthalic Acid

该化合物是一种多用途有机化合物,具有不同的芳香特性,其1,4-三卡箱酸结构具有高度稳定性和反应性,使其适合聚合物合成和药物应用.该化合物的硝基子组增强了其适合分析用途的紫外线吸收能力.其纯度和一致性确保了各种化学反应的可靠性能.

结构式图片

相似化合物

153813-69-5 5292-45-5 10312-55-7

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号96-98-0 4-甲基-3-硝基苯甲酸 | CAS号939-79-7 4-甲基-3-硝基氰苯 | CAS号104-85-8 对甲苯腈 | CAS号5372-81-6 2-氨基对苯二甲酸二甲酯 | CAS号552-16-9 2-硝基苯甲酸 | CAS号100-21-0 对苯二甲酸(PTA) | CAS号89-58-7 2,5-二甲基硝基苯 | CAS号84540-59-0 4-甲基-3-硝基氯苄 | CAS号85062-97-1 4-methyl-2-nitr... | CAS号778-94-9 4-氰基-3-硝基三氟甲基苯 | CAS号35092-89-8 2-硝基对苯二酸单甲酯 | CAS号55737-66-1 3-硝基-4-羧基苯甲酸甲酯 | CAS号5292-45-5 2-硝基对苯二甲酸二甲酯 | CAS号98-95-3 硝基苯 | CAS号1829-22-7 2-碘对苯二甲酸 | CAS号27210-70-4 AKOS B007547 | CAS号6342-72-9 2-羟基对苯二甲酸二甲酯 | CAS号636-94-2 2-羟基对苯二甲酸 | CAS号10312-55-7 2-氨基对苯二甲酸 | CAS号137000-70-5 2,5-Diethynylaniline

合成工艺路线路线简述

  • 89-58-7 = 610-29-7 + 27329-27-7 + 96-98-0
    反应条件:1.1 Reagents: Oxygen Catalysts: Manganese Diacetate,Cobalt Dibromide Solvents: Acetic Acid; 40 Min,0.4 Mpa,138 °C1.2 Reagents: Nitric Acid Solvents: Water; 3 H,0.12 Mpa,112 °C
    标题:Green Preparation Of Monosubstituted Methylbenzoic Acid And Monosubstituted Phthalic Acid
    参考文献:China
2,5-二甲基硝基苯置于氢氧化钾,Potassium Hexacyanoferrate(Iii)体系中,化学反应生成 2-硝基对苯二甲酸
参考文献:Noyes,American Chemical Journal,1888,Vol. 10,P. 474,483
标题:Noyes,American Chemical Journal,1888,Vol. 10,P. 474,483

海关参考信息

专利信息


专利号:US-7880026-B2
优先权日:2006-04-14
标 题 :MOF synthesis method
发明人:NI ZHENG; MASEL RICHARD I
权利人:UNIV ILLINOIS
摘要:A rapid, simple and versatile metal organic framework molecule (MOF) synthesis method particularly adapted to make non-linear MOFs includes heating MOF precursors, such as a metal or metal oxide and an organic ligand, in a microwave oven for a period sufficient to achieve crystallization. Microwave-assisted MOF synthesis yields high quality MOF crystals in a reaction time ranging from about 5 seconds to about 2.5 minutes, compared to hours and days required in conventional solvothermal and hydrothermal methods. In addition, microwave assisted methods provide MOF materials with uniform crystal size and well-defined shape. Further, microwave synthesis of MOFs allows the size and shape of MOF crystals to be tailored for use in a wide range applications by manipulating reaction conditions. Secondary growth processes may also be employed to grow larger crystals using seeds obtained from microwave-assisted synthesis methods.

专利号:US-2022089618-A1
优先权日:2019-01-29
标题:Solid-State Synthesis Of Precursors Of Metal-Organic Frameworks
发明人:MAJANO GERARDO J; FALKOWSKI JOSEPH M
权利人:EXXONMOBIL RES & ENG CO
摘要:Metal-organic frameworks (MOFs) are highly porous entities comprising a multidentate ligand coordinated to multiple metal atoms, typically as a coordination polymer. MOFs are usually produced from a solvent in powder form under hydrothermal or solvothermal synthesis conditions. Alternately, powder-form precursors of MOFs may be formed by milling or mulling a substantially solid mixture of a metal salt and a multidentate organic ligand, optionally in the presence of a small amount of a solvent. The powder-form precursors may then undergo heating, typically in the absence of applied shear, to produce the corresponding MOF. Mulling may be differentiated from milling at least in that mulling applies to the substantially solid mixture at a non-constant pressure and milling applies a constant pressure while forming the powder-form precursor. In some cases, mulling may promote more effective formation of the powder-form precursor compared to milling.

专利号:US-10737239-B2
优先权日:2015-11-27
标题 :Ultrafast high space-time-yield synthesis of metal-organic frameworks
发明人:BURCKHART JULIA; MARX STEFAN; ARNOLD LENA; HOFMANN CLAUS; Müller Ulrich
权利人:BASF SE
摘要:The invention relates to a process for the preparation of metal-organic frameworks (MOFs) in form of a homogenous powder, and a process wherein the metal-organic framework is molded into shaped bodies.

专利号:US-11739112-B2
优先权日:2017-02-02
标 题:Low temperature process for the synthesis of MOF carboxylate nanoparticles
发明人:PANCHAL MONIK; NOUAR FARID; SERRE CHRISTIAN; BENZAQUI MARVIN; SENE SAAD; STEUNOU NATHALIE; GIMÉNEZ MARQUÉS MONICA
权利人:CENTRE NAT RECH SCIENT; UNIV DE VERSAILLES—SAINT QUENTIN EN YVELINES
摘要:The present invention relates to low temperature process for preparing nanoparticles of porous crystalline Fe-, Al- or Ti-based MOF carboxylate materials with low polydispersity index, and uses thereof, particularly as catalyst support for carrying out heterogeneously catalyzed chemical reactions, or as gas storage/separation/purification material, or as matrix for encapsulating active principles (medicine, cosmetics).

专利号:US-9951095-B2
优先权日:2014-05-16
标 题:Chromium metal organic frameworks and synthesis of metal organic frameworks
发明人:ZHOU HONG-CAI; Liu tian-fu; LIAN XIZHEN; ZOU LANFANG; FENG DAWEI
权利人:TEXAS A & M UNIV SYS
摘要:The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.

专利号:US-4002664-A
优先权日:1973-06-09
标题 :Manufacture of dimethylaminobenzenecarboxylic acid esters
发明人:QUADBECK-SEEGER HANS-JUERGEN; HOCH HELMUT
权利人:BASF AG
摘要:Dimethylaminobenzenecarboxylic acid esters are produced by reaction of nitrobenzenecarboxylic acid esters with formaldehyde and hydrogen under pressure in the presence of a hydrogenation catalyst containing metals of atomic numbers 24 to 29 and of a weak acid, at temperatures from 35° to 150° C. The products are starting materials for the synthesis of dyes, especially of crystal violets, and of reactive dyes and pesticides.
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主要参考文献

[参考文献]: Dennis Fiorini, Et Al. A Salting Out System For Improving The Efficiency Of The Headspace Solid-Phase Microextraction Of Short And Medium Chain Free Fatty Acids. J Chromatogr A. 2015 Aug 28:1409:282-7.
[参考文献]: Gina L Lonati, Et Al. Nitrogen Solubility In Odontocete Blubber And Mandibular Fats In Relation To Lipid Composition. J Exp Biol. 2015 Aug;218(Pt 16):2620-30.
[参考文献]: M Nurhasan, Et Al. Effect Of Storage Temperature In A Cambodian Field Setting On The Fatty Acid Composition In Whole Blood. Prostaglandins Leukot Essent Fatty Acids. 2015 May:96:57-61.
[参考文献]: Rubén Angeriz-Campoy, Et Al. Thermophilic Anaerobic Co-Digestion Of Organic Fraction Of Municipal Solid Waste (Ofmsw) With Food Waste (Fw): Enhancement Of Bio-Hydrogen Production. Bioresour Technol. 2015 Oct:194:291-6.
[参考文献]: Ryan M Bradley, Et Al. Acylglycerophosphate Acyltransferase 4 (Agpat4) Is A Mitochondrial Lysophosphatidic Acid Acyltransferase That Regulates Brain Phosphatidylcholine, Phosphatidylethanolamine, And Phosphatidylinositol Levels. Biochim Biophys Acta. 2015 Dec;1851(12):1566-76.

合成参考文献


摘要:Li, Y.; Fang, X.; Wang, Y., Science of Synthesis: DNA-Encoded Libraries, (2024) nan, 68.
参考文献:10.1107/s1600536810023615
摘要:Li H, Yuan H, Yang S, Huang R. Poly[[[aqua(2,2′-bipyridine-κ2N,N′)zinc(II)]-μ-2-nitroterephthalato-κ2O1:O4] monohydrate]. Acta Crystallogr E Struct Rep Online. 2010 Jul 21;66(8):m983–4. doi: 10.1107/s1600536810023615.
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