CAS: 495-84-1; Salinazid

异烟酸甲酯置于一水合肼体系中,用 乙醇 作为反应溶剂,化学反应 14.0H,反应生成 2-异丙基硫杂蒽酮
参考文献:Synthesis And Luminescence Properties Of Salicylaldehyde Isonicotinoyl Hydrazone Derivatives And Their Europium Complexes
标题:Synthesis And Luminescence Properties Of Salicylaldehyde Isonicotinoyl Hydrazone Derivatives And Their Europium Complexes
摘要:Four Novel Salicylaldehyde Isonicotinoyl Hydrazone Derivatives And Their Corresponding Europium Ion Complexes Were Synthesized And Characterized,While The Luminescence Properties And The Fluorescence Quantum Yields Of The Target Complexes Were Investigated. The Results Indicated That The Ligands Favored Energy Transfers To The Emitting Energy Level Of Europium Ion,And Four Target Europium Complexes Showed The Characteristic Luminescence Of Central Europium Ion. Besides The Luminescence Intensity Of The Complex With Methoxy Group,Which Possessed The Highest Fluorescence Quantum Yield (0.522),Was Stronger Than That Of Other Complexes. Furthermore,The Electrochemical Properties Of The Target Complexes Were Further Investigated By Cyclic Voltammetry,The Results Indicated That The Highest occupied Molecular Orbital (Homo),Lowest Unoccupied Molecular Orbital (Lumo) Energy Levels And The Oxidation Potential Of The Complexes With Electron Donating Group Increased,However,That Of The Complexes With Accepting Electron Group Decreased. (C) 2015 Elsevier Inc. All Rights Reserved.
DOI:10.1016/j.Jinorgbio.2015.04.007