丙烯基三氯硅烷置于ch3Mgbr体系中,用 Not Given 作为反应溶剂,化学反应生成 烯丙基二甲基氯硅烷 参考文献:The Preparation Of Vinyl And Allyl Chlorosilanes 标题:The Preparation Of Vinyl And Allyl Chlorosilanes 摘要: DOI:10.1021/ja01226A058
专利号:US-7576169-B2 优先权日:2003-10-23 标 题:Facile synthesis of polyhedral silsesquioxane anions and use thereof 发明人:HASEGAWA ISAO; LAINE RICHARD M; ASUNCION MICHAEL Z; TAKAMURA NORIHIRO 权利人:UNIV MICHIGAN 摘要:Polyhedral silsesquioxane anions are economically prepared by reaction of a silica source derived from combusted organic material with a quaternary ammonium hydroxide compound. Reaction of the resulting anions with chlorosilanes may be effected in near stoichiometric fashion in organic solvent containing reactive quantities of organic acids such as formic acid. The functional groups on the resulting functionalized silsesquioxanes may be substituted for other functional groups by reaction with di- or polysiloxanes in the presence of a synthetic ion exchange resin.
专利号:US-2024010511-A1 优先权日:2019-05-02 标 题 :Methods and compositions for synthesis of phosphor and its incorporation in a polymer matrix for light conversion 发明人:SAHI SUNIL 权利人:SOLGO INC; SOLGRO INC 摘要:The invention relates to methods and compositions for synthesizing a phosphor and preparing a surface-modified phosphor comprising a phosphor, a silica, and a silane, and articles comprising same. The invention also relates to a method of dispersion of the disclosed surface-modified phosphor with a blue emitting agent in a polymer matrix and uses thereof.
专利号:US-7709672-B2 优先权日:2001-09-21 标 题:Method for obtaining halogenated monoorganoxysilanes useful in particular as synthesis intermediates 发明人:GUENNOUNI NATHALIE; MIGNANI GERARD; PEVERE VIRGINIE 权利人:RHODIA CHIMIE SA 摘要:The invention concerns the preparation of halogenated monoorganoxysilanes, of formula (I), said compounds being useful as synthesis intermediate in organic chemistry. Said method for preparing monoorganoxysilanes consists in: using as starting product halogenoalkylsilanes of the (CH 3 ) 2 SiCl 2 type and in substituting the silicon with a radical bearing a divalent unit bound to an electrophilic reactive group capable of reacting with at least an appropriate nucleophilic agent to form a functionalised monoorganoxysilane of formula (II) with, for example: R<1>=C 1 -C 4 alkyl; R<2>, R<3>=C 1 -C 6 alkyl; B=C 1 -C 10 alkylene; m=1 or 2; Hal=halogen; W=amino, mercapto, (organosilyl)-organopolythio radical.
专利号:US-10450331-B2 优先权日:2015-07-23 标 题:Functionalized cyanosilane and synthesis method and use thereof 发明人:ZHOU JIAN; ZENG XINGPING 权利人:UNIV EAST CHINA NORMAL 摘要:The present teachings relate to a functionalized silyl cyanide and synthetic methods thereof. As an example, the method may include adding a raw material silane and a cyanide source MCN in an organic solvent to produce the functionalized silyl cyanide in the absence of catalyst or in the presence of a metal salt catalyst. The functionalized silyl cyanide may be used in the reactions that classic TMSCN participates in, to synthesize important intermediates (e.g., cyanohydrin, amino alcohols and α-amino nitrile compounds), with improved reactivity and selectivity. The cyanosilyl ether resulted from the nucleophilic addition of functionalized silyl cyanide to aldehyde or ketone may undergo intramolecular reaction under appropriate conditions to transfer the functional groups on silicon onto the other parts of the product linked to silicon. Such a functional group transfer process may increase the synthesis efficiency and atom economy, as well as afford products unobtainable using traditional TMSCN.
专利号:US-6136926-A 优先权日:1996-07-22 标 题 :Cross-linkable, olefinic polymers and methods for their synthesis 发明人:RAETZSCH MANFRED; HESSE ACHIM; BUCKA HARMUT; LEISTNER DIRK; IVANCHEV SERGEJ; HEIKIN SAUL; MESH ALLA; PUKSCHANSKI MOISEJ 权利人:BOREALIS GMBH 摘要:Cross-linkable, olefinic polymers synthesized from mixtures of olefinic polymers and ethylenically unsaturated organosilane compounds, which can be grafted, by a 2-step method using thermally decomposing free radical-forming agents by heating the mixtures to a temperature of 30 DEG to 110 DEG C. below the softening temperature or the crystallite melting point of the olefinic polymers used and subsequently heating the mixtures to a reaction temperature of 10 DEG to 60 DEG C. below the softening temperature or the crystallite melting point of the olefinic polymers used. In the alternative, they can be grafted by a method involving the action of ionizing radiation with simultaneous absorption of organosilane compounds and the action of radiation. The method is suitable for producing films, sheets, fibers, panels, coatings, pipes, hollow objects, foamed materials and molded articles.
专利号:US-2005142054-A1 优先权日:2003-10-23 标 题 :Facile synthesis of polyhedral silsesquioxane anions and use thereof