CAS: 4028-23-3; Allyldimethylchlorosilane

该化合物是有机硅化合物,其特点是存在一种硅原子结为两个甲基组(一个合金组)和氯原子.其分子结构具有一种类似乙烯的合金组,有助于其反应,特别是核生殖替代反应.该化合物一般是无色的,可粉黄液,有独特的气味.它溶于有机溶剂,但因其疏水性,在水中溶解性有限.甲状二甲基硅经常被用作有机合成的试剂,特别是用于制造硅基化合物和聚合化学中的联动剂.它的再活动使其得以参与各种化学变异,使其在硅素材料和其他功能化硅素的开发过程中具有价值.与许多有机硅化合物一样,它应谨慎处理,因为其氯化性质可能危害健康.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号2622-05-1 烯丙基氯化镁 | CAS号75-78-5 二甲基二氯硅烷 | CAS号106-95-6 烯丙基溴 | CAS号107-05-1 氯丙烯 | CAS号107-37-9 丙烯基三氯硅烷 | CAS号1730-25-2 烯丙基溴化镁 | CAS号75-16-1 甲基溴化镁 | CAS号1113-12-8 二烯丙基二甲基硅烷 | CAS号762-72-1 烯丙基三甲基硅烷 | CAS号1066-35-9 二甲基一氯硅烷 | CAS号4286-85-5 1,1'-(but-1-ene... | CAS号574-42-5 Bis(diphenylmet... | CAS号90-99-3 二苯基氯甲烷 | CAS号20083-13-0 1,1,3,3-tetrame... | CAS号17955-81-6 二烯丙基四甲基二硅氧烷 | CAS号220322-74-7 1-methyl-4-(1-p... | CAS号2295-06-9 1,3-双(氯二甲基甲硅烷基)丙烷 | CAS号200192-51-4 dimethyl-(1-phe... | CAS号768-56-9 4-苯基-1-丁烯 | CAS号2021-28-5 3-苯丙酸乙酯

合成工艺路线路线简述

    丙烯基三氯硅烷置于ch3Mgbr体系中,用 Not Given 作为反应溶剂,化学反应生成 烯丙基二甲基氯硅烷
    参考文献:The Preparation Of Vinyl And Allyl Chlorosilanes
    标题:The Preparation Of Vinyl And Allyl Chlorosilanes
    摘要:
    DOI:10.1021/ja01226A058

    海关参考信息

    专利信息


    专利号:US-7576169-B2
    优先权日:2003-10-23
    标 题:Facile synthesis of polyhedral silsesquioxane anions and use thereof
    发明人:HASEGAWA ISAO; LAINE RICHARD M; ASUNCION MICHAEL Z; TAKAMURA NORIHIRO
    权利人:UNIV MICHIGAN
    摘要:Polyhedral silsesquioxane anions are economically prepared by reaction of a silica source derived from combusted organic material with a quaternary ammonium hydroxide compound. Reaction of the resulting anions with chlorosilanes may be effected in near stoichiometric fashion in organic solvent containing reactive quantities of organic acids such as formic acid. The functional groups on the resulting functionalized silsesquioxanes may be substituted for other functional groups by reaction with di- or polysiloxanes in the presence of a synthetic ion exchange resin.

    专利号:US-2024010511-A1
    优先权日:2019-05-02
    标 题 :Methods and compositions for synthesis of phosphor and its incorporation in a polymer matrix for light conversion
    发明人:SAHI SUNIL
    权利人:SOLGO INC; SOLGRO INC
    摘要:The invention relates to methods and compositions for synthesizing a phosphor and preparing a surface-modified phosphor comprising a phosphor, a silica, and a silane, and articles comprising same. The invention also relates to a method of dispersion of the disclosed surface-modified phosphor with a blue emitting agent in a polymer matrix and uses thereof.

    专利号:US-7709672-B2
    优先权日:2001-09-21
    标 题:Method for obtaining halogenated monoorganoxysilanes useful in particular as synthesis intermediates
    发明人:GUENNOUNI NATHALIE; MIGNANI GERARD; PEVERE VIRGINIE
    权利人:RHODIA CHIMIE SA
    摘要:The invention concerns the preparation of halogenated monoorganoxysilanes, of formula (I), said compounds being useful as synthesis intermediate in organic chemistry. Said method for preparing monoorganoxysilanes consists in: using as starting product halogenoalkylsilanes of the (CH 3 ) 2 SiCl 2 type and in substituting the silicon with a radical bearing a divalent unit bound to an electrophilic reactive group capable of reacting with at least an appropriate nucleophilic agent to form a functionalised monoorganoxysilane of formula (II) with, for example: R<1>=C 1 -C 4 alkyl; R<2>, R<3>=C 1 -C 6 alkyl; B=C 1 -C 10 alkylene; m=1 or 2; Hal=halogen; W=amino, mercapto, (organosilyl)-organopolythio radical.

    专利号:US-10450331-B2
    优先权日:2015-07-23
    标 题:Functionalized cyanosilane and synthesis method and use thereof
    发明人:ZHOU JIAN; ZENG XINGPING
    权利人:UNIV EAST CHINA NORMAL
    摘要:The present teachings relate to a functionalized silyl cyanide and synthetic methods thereof. As an example, the method may include adding a raw material silane and a cyanide source MCN in an organic solvent to produce the functionalized silyl cyanide in the absence of catalyst or in the presence of a metal salt catalyst. The functionalized silyl cyanide may be used in the reactions that classic TMSCN participates in, to synthesize important intermediates (e.g., cyanohydrin, amino alcohols and α-amino nitrile compounds), with improved reactivity and selectivity. The cyanosilyl ether resulted from the nucleophilic addition of functionalized silyl cyanide to aldehyde or ketone may undergo intramolecular reaction under appropriate conditions to transfer the functional groups on silicon onto the other parts of the product linked to silicon. Such a functional group transfer process may increase the synthesis efficiency and atom economy, as well as afford products unobtainable using traditional TMSCN.

    专利号:US-6136926-A
    优先权日:1996-07-22
    标 题 :Cross-linkable, olefinic polymers and methods for their synthesis
    发明人:RAETZSCH MANFRED; HESSE ACHIM; BUCKA HARMUT; LEISTNER DIRK; IVANCHEV SERGEJ; HEIKIN SAUL; MESH ALLA; PUKSCHANSKI MOISEJ
    权利人:BOREALIS GMBH
    摘要:Cross-linkable, olefinic polymers synthesized from mixtures of olefinic polymers and ethylenically unsaturated organosilane compounds, which can be grafted, by a 2-step method using thermally decomposing free radical-forming agents by heating the mixtures to a temperature of 30 DEG to 110 DEG C. below the softening temperature or the crystallite melting point of the olefinic polymers used and subsequently heating the mixtures to a reaction temperature of 10 DEG to 60 DEG C. below the softening temperature or the crystallite melting point of the olefinic polymers used. In the alternative, they can be grafted by a method involving the action of ionizing radiation with simultaneous absorption of organosilane compounds and the action of radiation. The method is suitable for producing films, sheets, fibers, panels, coatings, pipes, hollow objects, foamed materials and molded articles.

    专利号:US-2005142054-A1
    优先权日:2003-10-23
    标 题 :Facile synthesis of polyhedral silsesquioxane anions and use thereof
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    合成参考文献


    摘要:Hlina, J. A., Science of Synthesis Knowledge Updates, (2021) 1, 115.
    摘要:Nahm Garrett, M.; Johnson, J. S., Science of Synthesis Knowledge Updates, (2012) 2, 10.
    摘要:Spitzner, D., Science of Synthesis Knowledge Updates, (2016) 1, 200.
    摘要:Cheng, Q.; Shen, X., Science of Synthesis: Knowledge Updates, (2025) 2.
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