📜环辛胺,N,N-二甲基甲酰胺置于叔丁基过氧化氢,Copper(Ll) Bromide体系中,用 癸烷 用作溶剂,化学反应 1.0H,以43%的收率获得环莠隆 参考文献:Copper Catalyzed Oxidative Coupling Of Amines With Formamides: A New Approach For The Synthesis Of Unsymmetrical Urea Derivatives 标题:Copper Catalyzed Oxidative Coupling Of Amines With Formamides: A New Approach For The Synthesis Of Unsymmetrical Urea Derivatives 摘要:已经开发了在室温下通过铜催化的c-h/n-h偶联反应,直接获得不对称尿素衍生物,反应对象是甲酰胺与胺.这一方法也适用于手性尿素衍生物的合成. Doi:10.1039/c3Cc42381F
专利号:WO-2024256370-A1 优先权日:2023-06-13 标 题 :Synthesis of glufosinate using an amidase-based process 发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN 权利人:BASF SE 摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.
专利号:US-2025120400-A1 优先权日:2021-12-10 标题:Synthesis of glufosinate using a hydantoinase-based process 发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN 权利人:BASF SE 摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.
专利号:US-2021386068-A1 优先权日:2018-11-07 标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides 发明人:KISTER JEREMY; SATCHIVI NORBERT M 权利人:CORTEVA AGRISCIENCE LLC 摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.
专利号:US-2021352899-A1 优先权日:2018-11-07 标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides 发明人:KISTER JEREMY; SATCHIVI NORBERT M 权利人:CORTEVA AGRISCIENCE LLC 摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.
专利号:ES-2717283-T3 优先权日:2012-07-24 标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids
专利号:TW-I655905-B 优先权日:2012-07-24 标题 :Contains 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid or a derivative thereof and very long chain fatty acid (VLCFA) Synthesis of herbicidal compositions with fatty acid/fat synthesis inhibiting herbicides
1: Gumiela M. Cyclotron production of 99mTc: Comparison of known separation technologies for isolation of 99mTc from molybdenum targets. Nucl Med Biol. 2018 Mar;58:33-41. doi: 10.1016/j.nucmedbio.2017.11.001. Epub 2017 Nov 10. 17(1):1-35. doi: 10.1002/(SICI)1098-2787(1998)17:1<1::AID-MAS1>3.0.CO;2-K. 11(2):92-99. doi: 10.2174/1874471011666180412170219. 38(2):143-148. doi: 10.1080/15368378.2019.1608234. Epub 2019 Apr 27. 24(3):444. doi: 10.3390/molecules24030444. 6: Pazur A. Calcium ion cyclotron resonance in dissipative water structures. Electromagn Biol Med. 2018;37(2):100-113. doi: 10.1080/15368378.2018.1434789. Epub 2018 Feb 8. 24(1):25. doi: 10.3390/molecules24010025. 8: Wagatsuma K, Ishiwata K, Nobuhara F, Koumura I, Kunugi M, Oda K, Miwa K, Toyohara J, Ishii K. Pre-discard estimation of radioactivated materials in positron emission tomography cyclotron systems and concrete walls of a cyclotron vault. Med Phys. 2019 May;46(5):2457-2467. doi: 10.1002/mp.13492. Epub 2019 Apr 8.
合成参考文献
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